C07C7/12

Oxygenates-free C8-C12 aromatic hydrocarbon stream and a process for preparing the same

The present disclosure provides a process for separating oxygenates present in an aromatic hydrocarbon stream to obtain an oxygenates-free aromatic hydrocarbon stream. The process involves selectively removing oxygenates from the aromatic hydrocarbon stream by passing said stream through at least one zeolite based adsorbing material.

Oxygenates-free C8-C12 aromatic hydrocarbon stream and a process for preparing the same

The present disclosure provides a process for separating oxygenates present in an aromatic hydrocarbon stream to obtain an oxygenates-free aromatic hydrocarbon stream. The process involves selectively removing oxygenates from the aromatic hydrocarbon stream by passing said stream through at least one zeolite based adsorbing material.

Oxygenates-free C8-C12 aromatic hydrocarbon stream and a process for preparing the same

The present disclosure provides a process for separating oxygenates present in an aromatic hydrocarbon stream to obtain an oxygenates-free aromatic hydrocarbon stream. The process involves selectively removing oxygenates from the aromatic hydrocarbon stream by passing said stream through at least one zeolite based adsorbing material.

Paraxylene separation process

The invention relates to a p-xylene separation process wherein at least a portion of ethylbenzene present in an aromatics-containing feed is removed prior to isomerization. Aspects of the invention provide a process for producing p-xylene. The process includes providing a first mixture comprising ≧5.0 wt. % of aromatic C.sub.8 isomers, the C.sub.8 isomers comprising p-xylene and ethylbenzene. A p-xylene-containing portion and an ethylbenzene-containing portion are separated from the first mixture in a first separation stage to form a p-xylene-depleted raffinate. The first separation stage can include at least one simulated moving-bed adsorptive separation stage. At least a portion the p-xylene-depleted raffinate in the liquid phase is reacted to produce a reactor effluent comprising aromatic C.sub.8 isomers. The first mixture can be combined with ≧50.0 wt. % of the reactor effluent's aromatic C.sub.8 isomers. The combining can be carried out before and/or during the separating of the p-xylene and ethylbenzene portions.

Paraxylene separation process

The invention relates to a p-xylene separation process wherein at least a portion of ethylbenzene present in an aromatics-containing feed is removed prior to isomerization. Aspects of the invention provide a process for producing p-xylene. The process includes providing a first mixture comprising ≧5.0 wt. % of aromatic C.sub.8 isomers, the C.sub.8 isomers comprising p-xylene and ethylbenzene. A p-xylene-containing portion and an ethylbenzene-containing portion are separated from the first mixture in a first separation stage to form a p-xylene-depleted raffinate. The first separation stage can include at least one simulated moving-bed adsorptive separation stage. At least a portion the p-xylene-depleted raffinate in the liquid phase is reacted to produce a reactor effluent comprising aromatic C.sub.8 isomers. The first mixture can be combined with ≧50.0 wt. % of the reactor effluent's aromatic C.sub.8 isomers. The combining can be carried out before and/or during the separating of the p-xylene and ethylbenzene portions.

Paraxylene separation process

The invention relates to a p-xylene separation process wherein at least a portion of ethylbenzene present in an aromatics-containing feed is removed prior to isomerization. Aspects of the invention provide a process for producing p-xylene. The process includes providing a first mixture comprising ≧5.0 wt. % of aromatic C.sub.8 isomers, the C.sub.8 isomers comprising p-xylene and ethylbenzene. A p-xylene-containing portion and an ethylbenzene-containing portion are separated from the first mixture in a first separation stage to form a p-xylene-depleted raffinate. The first separation stage can include at least one simulated moving-bed adsorptive separation stage. At least a portion the p-xylene-depleted raffinate in the liquid phase is reacted to produce a reactor effluent comprising aromatic C.sub.8 isomers. The first mixture can be combined with ≧50.0 wt. % of the reactor effluent's aromatic C.sub.8 isomers. The combining can be carried out before and/or during the separating of the p-xylene and ethylbenzene portions.

PROCESS FOR CARBON DIOXIDE RECOVERY FROM A GAS STREAM CONTAINING CARBON DIOXIDE AND HYDROCARBONS

The present invention relates to a process for purification of a carbon dioxide feedstock, for example from a production well, which comprises carbon dioxide and gaseous and liquid C.sub.1+ hydrocarbons. Specifically, a carbon dioxide feedstream is passed through one or more separation unit wherein each separation unit removes one or more C.sub.1+ hydrocarbon from the carbon dioxide feedstream to provide a richer carbon dioxide gas stream. The process comprises one or more separation unit which employs an adsorption media and has an adsorption step and a media regeneration step wherein the regeneration step may be operated as a batch process, a semi-continuous process, or a continuous process. One embodiment of this method provides for the use of a different regenerable adsorbent media in two or more separation units.

PROCESS FOR CARBON DIOXIDE RECOVERY FROM A GAS STREAM CONTAINING CARBON DIOXIDE AND HYDROCARBONS

The present invention relates to a process for purification of a carbon dioxide feedstock, for example from a production well, which comprises carbon dioxide and gaseous and liquid C.sub.1+ hydrocarbons. Specifically, a carbon dioxide feedstream is passed through one or more separation unit wherein each separation unit removes one or more C.sub.1+ hydrocarbon from the carbon dioxide feedstream to provide a richer carbon dioxide gas stream. The process comprises one or more separation unit which employs an adsorption media and has an adsorption step and a media regeneration step wherein the regeneration step may be operated as a batch process, a semi-continuous process, or a continuous process. One embodiment of this method provides for the use of a different regenerable adsorbent media in two or more separation units.

Pretreatment process for improving the filling of a chamber with solid particles

The invention relates to a pretreatment process for improving the filling of a chamber with solid particles, in which said solid particles are mixed before loading of said solid particles into the chamber with at least one lubricant that is solid at ambient temperature chosen from saturated fatty acids having 14 or more carbon atoms, metal salts of saturated fatty acids having 14 or more carbon atoms, esters of fatty acids having 14 or more carbon atoms, fatty alcohols having 14 or more carbon atoms, linear N-alkanes having 16 or more carbon atoms in solid form, fumaric acid, talc, sodium stearoyl fumarate, the lubricant being introduced at a content of between 0.01% and 1% relative to the total weight of the mixture of solid particles and lubricant. The invention also relates to the use of the process for the pretreatment of particles of adsorbents for the separation of xylenes.

Pretreatment process for improving the filling of a chamber with solid particles

The invention relates to a pretreatment process for improving the filling of a chamber with solid particles, in which said solid particles are mixed before loading of said solid particles into the chamber with at least one lubricant that is solid at ambient temperature chosen from saturated fatty acids having 14 or more carbon atoms, metal salts of saturated fatty acids having 14 or more carbon atoms, esters of fatty acids having 14 or more carbon atoms, fatty alcohols having 14 or more carbon atoms, linear N-alkanes having 16 or more carbon atoms in solid form, fumaric acid, talc, sodium stearoyl fumarate, the lubricant being introduced at a content of between 0.01% and 1% relative to the total weight of the mixture of solid particles and lubricant. The invention also relates to the use of the process for the pretreatment of particles of adsorbents for the separation of xylenes.