A process for adsorbing impurities from hydrocarbon gas streams is disclosed. The process involves passing a hydrocarbon gas stream and a solid dry adsorbent under inert environment to a scrubbing chamber for adsorbing impurities from the hydrocarbon gas streams within the scrubbing chamber. The process adsorption of impurities in scrubbing chamber is carried under non-oxidative conditions to generate a clean product gas.

A process for adsorbing impurities from hydrocarbon gas streams is disclosed. The process involves passing a hydrocarbon gas stream and a solid dry adsorbent under inert environment to a scrubbing chamber for adsorbing impurities from the hydrocarbon gas streams within the scrubbing chamber. The process adsorption of impurities in scrubbing chamber is carried under non-oxidative conditions to generate a clean product gas.

A process for adsorbing impurities from hydrocarbon gas streams is disclosed. The process involves passing a hydrocarbon gas stream and a solid dry adsorbent under inert environment to a scrubbing chamber for adsorbing impurities from the hydrocarbon gas streams within the scrubbing chamber. The process adsorption of impurities in scrubbing chamber is carried under non-oxidative conditions to generate a clean product gas.

Device and process for the conversion of a feedstock of aromatic compounds, in which the feedstock is treated notably by means of a fractionation train (4-7), a xylene separation unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO.sub.2 and H.sub.2; a reverse water gas shift RWGS reaction section (50) treats the pyrolysis gas and produces an RWGS gas enriched in CO and in water; a fermentation reaction section (52) treats the RWGS gas enriched in CO and in water, to produce ethanol and recycle the ethanol to the inlet of the pyrolysis unit.

Device and process for the conversion of a feedstock of aromatic compounds, in which the feedstock is treated notably by means of a fractionation train (4-7), a xylene separation unit (10) and an isomerization unit (11), and in which a pyrolysis unit (13) treats a second hydrocarbon feedstock, produces a pyrolysis effluent feeding the feedstock, and produces a pyrolysis gas comprising CO, CO.sub.2 and H.sub.2; a reverse water gas shift RWGS reaction section (50) treats the pyrolysis gas and produces an RWGS gas enriched in CO and in water; a fermentation reaction section (52) treats the RWGS gas enriched in CO and in water, to produce ethanol and recycle the ethanol to the inlet of the pyrolysis unit.

Process for producing biomethane from a biogas stream including methane, carbon dioxide and at least one impurity chosen from ammonia, volatile organic compounds, water, sulfur-based impurities (H.sub.2S) and siloxanes. A biogas stream is dried, the at least one impurity is at least partially removed by solidification and removal of the impurity. The methane and the carbon dioxide contained in the biogas obtained from the second step are separated so as to produce a biomethane stream and a CO.sub.2 stream.

Process for producing biomethane from a biogas stream including methane, carbon dioxide and at least one impurity chosen from ammonia, volatile organic compounds, water, sulfur-based impurities (H.sub.2S) and siloxanes. A biogas stream is dried, the at least one impurity is at least partially removed by solidification and removal of the impurity. The methane and the carbon dioxide contained in the biogas obtained from the second step are separated so as to produce a biomethane stream and a CO.sub.2 stream.

Disclosed are air-stable small-molecule adsorbents trimeric [Cu—Br].sub.3 and [Cu—H].sub.3 that undergo a reversible solid-state molecular rearrangements to [Cu—Br.(alkene)].sub.2 and [Cu—H.(alkene)].sub.2 dimers. The reversible solid-state rearrangement allows one to break adsorbent design trade-offs and achieve low heat of adsorption while retaining high selectivity and uptake.

Disclosed are air-stable small-molecule adsorbents trimeric [Cu—Br].sub.3 and [Cu—H].sub.3 that undergo a reversible solid-state molecular rearrangements to [Cu—Br.(alkene)].sub.2 and [Cu—H.(alkene)].sub.2 dimers. The reversible solid-state rearrangement allows one to break adsorbent design trade-offs and achieve low heat of adsorption while retaining high selectivity and uptake.

A composition comprising a compound of formula I:

##STR00001##

wherein n is 5, and R is methyl; and
the composition is in an essentially guest-free solid form.