Patent classifications
C07C7/148
Method for catalyst regeneration
The various embodiments relate to a system and method for regenerating a direct oxidation catalyst that coverts H.sub.2S to elemental S. One embodiment of the method comprises regenerating a direct oxidation catalyst by contacting the direct oxidation catalyst with steam.
Method for Purifying Linear Alpha Olefins
The disclosure provides a method of purifying a linear alpha olefin product, the method including feeding a linear alpha olefin feed stream comprising the linear alpha olefin product and at least one impurity into a distillation column, the distillation column having a plurality of stacked stages; withdrawing a side stream from at least one of said plurality of stacked stages; feeding the side stream into a reactor containing an isomerization catalyst to convert at least a portion of the at least one impurity from a first isomer to a second isomer, producing a reactor product stream having a reduced content of the first isomer; returning the reactor product stream to a stage of the distillation column; and withdrawing an overhead stream from the distillation column comprising the linear alpha olefin product and having a reduced content of the at least one impurity.
Method for Purifying Linear Alpha Olefins
The disclosure provides a method of purifying a linear alpha olefin product, the method including feeding a linear alpha olefin feed stream comprising the linear alpha olefin product and at least one impurity into a distillation column, the distillation column having a plurality of stacked stages; withdrawing a side stream from at least one of said plurality of stacked stages; feeding the side stream into a reactor containing an isomerization catalyst to convert at least a portion of the at least one impurity from a first isomer to a second isomer, producing a reactor product stream having a reduced content of the first isomer; returning the reactor product stream to a stage of the distillation column; and withdrawing an overhead stream from the distillation column comprising the linear alpha olefin product and having a reduced content of the at least one impurity.
Method for Purifying Linear Alpha Olefins
The disclosure provides a method of purifying a linear alpha olefin product, the method including feeding a linear alpha olefin feed stream comprising the linear alpha olefin product and at least one impurity into a distillation column, the distillation column having a plurality of stacked stages; withdrawing a side stream from at least one of said plurality of stacked stages; feeding the side stream into a reactor containing an isomerization catalyst to convert at least a portion of the at least one impurity from a first isomer to a second isomer, producing a reactor product stream having a reduced content of the first isomer; returning the reactor product stream to a stage of the distillation column; and withdrawing an overhead stream from the distillation column comprising the linear alpha olefin product and having a reduced content of the at least one impurity.
REMOVAL OF CARBONYLS FROM GASEOUS HYDROCARBON STREAMS
Disclosed are methods and systems for removing a highly reactive polymer precursor such as acetaldehyde and acetone from a hydrocarbon gas stream. Embodiments may disclose a method for removal of carbonyls comprising providing a hydrocarbon gas stream comprising a carbonyl, providing a liquid bisulfite stream, and contacting the hydrocarbon gas stream and liquid bisulfite stream in a mass transfer device wherein at least a portion of the carbonyl reacts with the bisulfite to form a solid adduct that is soluble in the liquid bisulfite stream.
REMOVAL OF CARBONYLS FROM GASEOUS HYDROCARBON STREAMS
Disclosed are methods and systems for removing a highly reactive polymer precursor such as acetaldehyde and acetone from a hydrocarbon gas stream. Embodiments may disclose a method for removal of carbonyls comprising providing a hydrocarbon gas stream comprising a carbonyl, providing a liquid bisulfite stream, and contacting the hydrocarbon gas stream and liquid bisulfite stream in a mass transfer device wherein at least a portion of the carbonyl reacts with the bisulfite to form a solid adduct that is soluble in the liquid bisulfite stream.
METHOD FOR REDUCING RISK OF BURNING AND EXPLOSION IN DEOXYGENATION PROCESS OF OXYGEN-CONTAINING GAS
A method for reducing the risk of burning and explosion in a deoxygenation process of an oxygen-containing gas includes multiple steps. According to this method, in the presence of a gaseous alkane, hydrogen reacts with an oxygen-containing gas from which an unsaturated hydrocarbon has been removed. The oxygen-containing gas contains the oxygen and the unsaturated hydrocarbon, and the content of the oxygen in the oxygen-containing gas is greater than 0.5% by volume. A gaseous alkane is introduced to reduce the risk of burning and explosion of a mixed gas. A hydrocatalytic reaction is carried out to promote oxygen in the mixed gas to react with hydrogen to produce water, which removes oxygen from the oxygen-containing gas and also effectively inhibits carbon deposition on the surface of a catalyst and the production of a carbon oxide, which enhances the toleration for fluctuation of the oxygen content in a raw gas.
Hydrocarbon Conversion Process
The invention relates to processes for converting a mixture of hydrocarbon and sulfur-containing molecules such as mercaptan into products comprising acetylene, ethylene, and hydrogen sulfide, to processes utilizing the acetylene and ethylene resulting from the conversion, and to equipment useful for such processes.
Hydrocarbon Conversion Process
The invention relates to processes for converting a mixture of hydrocarbon and sulfur-containing molecules such as mercaptan into products comprising acetylene, ethylene, and hydrogen sulfide, to processes utilizing the acetylene and ethylene resulting from the conversion, and to equipment useful for such processes.
Process for oxidative desulfurization with integrated sulfone decomposition
The process provided herein is concerned with disposal of oxidized sulfur compounds formed by oxidative desulfurization. The process uses solid base catalyst in the presence of a caustic solution or solid base catalyst pretreated with a base and eliminates the need to separate the sulfones from the hydrocarbon streams and recover the hydrocarbons.