A new crystalline zinc (silico)aluminophosphate molecular sieve designated SSZ-90 is disclosed. SSZ-90 is isostructural with the DFO framework type and is synthesized using an ionic liquid as both the solvent and the structure directing agent. The ionic liquid [Q.sup.+A.sup.] comprises a cation (Q.sup.+) selected from the group consisting of 1,3-diisopropylimidazolium, 1,3-diisobutylimidazolium, and 1-isopropyl-3-isobutylimidazolium and an anion (A.sup.) which is not detrimental to the formation of the molecular sieve.

A new crystalline zinc (silico)aluminophosphate molecular sieve designated SSZ-90 is disclosed. SSZ-90 is isostructural with the DFO framework type and is synthesized using an ionic liquid as both the solvent and the structure directing agent. The ionic liquid [Q.sup.+A.sup.] comprises a cation (Q.sup.+) selected from the group consisting of 1,3-diisopropylimidazolium, 1,3-diisobutylimidazolium, and 1-isopropyl-3-isobutylimidazolium and an anion (A.sup.) which is not detrimental to the formation of the molecular sieve.

A new crystalline zinc (silico)aluminophosphate molecular sieve designated SSZ-90 is disclosed. SSZ-90 is isostructural with the DFO framework type and is synthesized using an ionic liquid as both the solvent and the structure directing agent. The ionic liquid [Q.sup.+A.sup.] comprises a cation (Q.sup.+) selected from the group consisting of 1,3-diisopropylimidazolium, 1,3-diisobutylimidazolium, and 1-isopropyl-3-isobutylimidazolium and an anion (A.sup.) which is not detrimental to the formation of the molecular sieve.

A method for upgrading a naphtha feed includes passing the naphtha feed to an adsorption unit to produce at least a paraffin stream and an isoparaffin stream, wherein the isoparaffin stream comprises isoparaffins and aromatics. Passing the isoparaffin stream to an isoparaffin aromatization catalytic unit that contacts the isoparaffin stream with at least one aromatization catalyst produces aromatics from the isoparaffins thereby yielding an aromatization effluent. The at least one aromatization catalyst may comprise ZSM-5 zeolite. Benzene, toluene, and/or xylene (BTX) may be separated from the aromatization effluent by separating the aromatics effluent into a gas stream and a liquid stream in a gas/liquid separator, wherein the liquid stream contains BTX. Passing the liquid stream to a BTX-separation unit may produce a BTX stream and a recycle stream, wherein the BTX stream contains benzene, toluene, and/or xylene.

A method for upgrading a naphtha feed includes passing the naphtha feed to an adsorption unit to produce at least a paraffin stream and an isoparaffin stream, wherein the isoparaffin stream comprises isoparaffins and aromatics. Passing the isoparaffin stream to an isoparaffin aromatization catalytic unit that contacts the isoparaffin stream with at least one aromatization catalyst produces aromatics from the isoparaffins thereby yielding an aromatization effluent. The at least one aromatization catalyst may comprise ZSM-5 zeolite. Benzene, toluene, and/or xylene (BTX) may be separated from the aromatization effluent by separating the aromatics effluent into a gas stream and a liquid stream in a gas/liquid separator, wherein the liquid stream contains BTX. Passing the liquid stream to a BTX-separation unit may produce a BTX stream and a recycle stream, wherein the BTX stream contains benzene, toluene, and/or xylene.

A flexible process for gasoline refineries is described. The process can vary depending on the available feedstock and the desired products. At one time, the process can involve disproportionating pentanes to a product mixture including isobutane and isohexane. At other times, by switching the feedstock and operating conditions, the process can convert a mixture of C.sub.4 and C.sub.7 paraffins to a low aromatic blendstock with suitable octane and a vapor pressure lower than butanes. The process can be performed in separate stand-alone units operated at different times, or a single unit can be operated according to one process at one time and according to the other process at another time.

A flexible process for gasoline refineries is described. The process can vary depending on the available feedstock and the desired products. At one time, the process can involve disproportionating pentanes to a product mixture including isobutane and isohexane. At other times, by switching the feedstock and operating conditions, the process can convert a mixture of C.sub.4 and C.sub.7 paraffins to a low aromatic blendstock with suitable octane and a vapor pressure lower than butanes. The process can be performed in separate stand-alone units operated at different times, or a single unit can be operated according to one process at one time and according to the other process at another time.

A process for preparing C.sub.2 to C.sub.4 hydrocarbons includes introducing a feed stream into a reaction zone of a reactor, the feed stream comprising hydrogen gas and carbon monoxide. An additional stream is introduced into the reaction zone of the reactor, the additional stream comprising carbon dioxide. A combined stream that includes the feed stream and the additional stream is converted into a product stream comprising C.sub.2 to C.sub.4 hydrocarbons in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst includes a mixed metal oxide catalyst component, and a microporous catalyst component. The process operates at a gas hourly space velocity in excess of 2500 hr.sup.1 and effectively yields a net carbon dioxide selectivity of less than 5.0% and a productivity of C.sub.2-C.sub.4 hydrocarbons greater than 75 g hydrocarbons per kilogram of catalyst per hour.

A process for preparing C.sub.2 to C.sub.4 hydrocarbons includes introducing a feed stream into a reaction zone of a reactor, the feed stream comprising hydrogen gas and carbon monoxide. An additional stream is introduced into the reaction zone of the reactor, the additional stream comprising carbon dioxide. A combined stream that includes the feed stream and the additional stream is converted into a product stream comprising C.sub.2 to C.sub.4 hydrocarbons in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst includes a mixed metal oxide catalyst component, and a microporous catalyst component. The process operates at a gas hourly space velocity in excess of 2500 hr.sup.1 and effectively yields a net carbon dioxide selectivity of less than 5.0% and a productivity of C.sub.2-C.sub.4 hydrocarbons greater than 75 g hydrocarbons per kilogram of catalyst per hour.