Patent classifications
C07C9/22
Even carbon number paraffin composition and method of manufacturing same
Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.
Even carbon number paraffin composition and method of manufacturing same
Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.
Process for preparing a 3,7-dimethylalkane compound
The present invention relates to a process for preparing a 3,7-dimethylalkane compound (3): wherein n is 5 or 6, the process comprising: subjecting a nucleophilic reagent, 2,6-dimethyloctyl compound (1): wherein M.sup.1 represents Li, Mg Z.sup.1, CuZ.sup.1, or CuLiZ.sup.1, wherein Z.sup.1 represents a halogen atom or a 2,6-dimethyloctyl group, to a coupling reaction with an electrophilic alkyl reagent (2): wherein X.sup.1 represents a halogen atom or a p-toluenesulfonate group, and “n” is as defined above, to form the 3,7-dimethylalkane compound (3). ##STR00001##
Process for preparing a 3,7-dimethylalkane compound
The present invention relates to a process for preparing a 3,7-dimethylalkane compound (3): wherein n is 5 or 6, the process comprising: subjecting a nucleophilic reagent, 2,6-dimethyloctyl compound (1): wherein M.sup.1 represents Li, Mg Z.sup.1, CuZ.sup.1, or CuLiZ.sup.1, wherein Z.sup.1 represents a halogen atom or a 2,6-dimethyloctyl group, to a coupling reaction with an electrophilic alkyl reagent (2): wherein X.sup.1 represents a halogen atom or a p-toluenesulfonate group, and “n” is as defined above, to form the 3,7-dimethylalkane compound (3). ##STR00001##
Diesel and turbine fuels from ethanol
A three step method for the conversion of ethanol into fuels that can be utilized as full-performance military jet or diesel fuels. Embodiments of the invention further describe methods for the selective conversion of ethanol to full performance saturated hydrocarbon fuels that are suitable for both jet and diesel propulsion.
Diesel and turbine fuels from ethanol
A three step method for the conversion of ethanol into fuels that can be utilized as full-performance military jet or diesel fuels. Embodiments of the invention further describe methods for the selective conversion of ethanol to full performance saturated hydrocarbon fuels that are suitable for both jet and diesel propulsion.
ALKYLATION OF METALLOCENE-OLIGOMER WITH ISOALKANE TO MAKE HEAVY BASE OIL
A process to make an isoalkane alkylate base oil, comprising: a. oligomerizing an olefin feed having a carbon number from 3 to 6 using a metallocene catalyst to make an unsaturated olefin oligomer; and b. alkylating an isoalkane feed with the unsaturated olefin oligomer in the presence of an acidic alkylation catalyst, and without any addition of hydrogen, to make an alkylate product comprising the isoalkane alkylate base oil having a kinematic viscosity at 100° C. greater than 10 mm.sup.2/s, a VI higher than 80, and a bromine index less than 1000 mg Br/100 g.
ALKYLATION OF METALLOCENE-OLIGOMER WITH ISOALKANE TO MAKE HEAVY BASE OIL
A process to make an isoalkane alkylate base oil, comprising: a. oligomerizing an olefin feed having a carbon number from 3 to 6 using a metallocene catalyst to make an unsaturated olefin oligomer; and b. alkylating an isoalkane feed with the unsaturated olefin oligomer in the presence of an acidic alkylation catalyst, and without any addition of hydrogen, to make an alkylate product comprising the isoalkane alkylate base oil having a kinematic viscosity at 100° C. greater than 10 mm.sup.2/s, a VI higher than 80, and a bromine index less than 1000 mg Br/100 g.
BASE OIL HAVING HIGH VISCOSITY INDEX FROM ALKYLATION OF DIMER KETONE-DERIVED OLEFIN
A process to make an alkylate base oil having a viscosity index greater than or equal to 90, comprising: a. converting an at least one dimeric ketone to an at least one alcohol; b. dehydrating the at least one alcohol to make one or more corresponding olefins; and c. alkylating at least one isoalkane with the one or more corresponding olefins to form the alkylate base oil.
BASE OIL HAVING HIGH VISCOSITY INDEX FROM ALKYLATION OF DIMER KETONE-DERIVED OLEFIN
A process to make an alkylate base oil having a viscosity index greater than or equal to 90, comprising: a. converting an at least one dimeric ketone to an at least one alcohol; b. dehydrating the at least one alcohol to make one or more corresponding olefins; and c. alkylating at least one isoalkane with the one or more corresponding olefins to form the alkylate base oil.