A process and related electrode composition are disclosed for the electrocatalytic hydrogenation and/or hydrodeoxygenation of biomass-derived bio-oil components by the production of hydrogen atoms on a catalyst surface followed by the reaction of the hydrogen atoms with the organic compounds in bio-oil. The catalyst is a metal supported on a monolithic high surface area material such as activated carbon cloth. Electrocatalytic hydrogenation and/or hydrodeoxygenation stabilizes the bio-oil under mild conditions to reduce coke formation and catalyst deactivation. The process converts oxygen-containing functionalities and unsaturated bonds into chemically reduced forms with an increased hydrogen content. The process is operated at mild conditions, which enables it to be a good means for stabilizing bio-oil to a form that can be stored and transported using metal containers and pipes.

A process and related electrode composition are disclosed for the electrocatalytic hydrogenation and/or hydrodeoxygenation of biomass-derived bio-oil components by the production of hydrogen atoms on a catalyst surface followed by the reaction of the hydrogen atoms with the organic compounds in bio-oil. The catalyst is a metal supported on a monolithic high surface area material such as activated carbon cloth. Electrocatalytic hydrogenation and/or hydrodeoxygenation stabilizes the bio-oil under mild conditions to reduce coke formation and catalyst deactivation. The process converts oxygen-containing functionalities and unsaturated bonds into chemically reduced forms with an increased hydrogen content. The process is operated at mild conditions, which enables it to be a good means for stabilizing bio-oil to a form that can be stored and transported using metal containers and pipes.

The present invention relates to a transition metal complex having a PNNP4 ligand, which is easy to manufacture and handle and is relatively inexpensively available, and a method for manufacturing the same, as well as a method using this transition metal complex as a catalyst for hydrogenation reduction of ketones, esters and amides to manufacture corresponding alcohols, aldehydes, hemiacetals and hemiaminals, a method using this transition metal complex as a catalyst for oxidation of alcohols, hemiacetals and hemiaminals to manufacture corresponding carbonyl compounds, and a method using this transition metal complex as a catalyst for dehydrogenation condensation between alcohols and amines to manufacture alkylamines.

The present invention relates to a transition metal complex having a PNNP4 ligand, which is easy to manufacture and handle and is relatively inexpensively available, and a method for manufacturing the same, as well as a method using this transition metal complex as a catalyst for hydrogenation reduction of ketones, esters and amides to manufacture corresponding alcohols, aldehydes, hemiacetals and hemiaminals, a method using this transition metal complex as a catalyst for oxidation of alcohols, hemiacetals and hemiaminals to manufacture corresponding carbonyl compounds, and a method using this transition metal complex as a catalyst for dehydrogenation condensation between alcohols and amines to manufacture alkylamines.

A process for producing fuel-range organic oxygen-containing compounds is provided. The process includes converting glycerol in the presence of a metal oxide catalyst. The fuel-range organic oxygen-containing compounds can be deoxygenated to produce gasoline and jet fuels or fuel blending components.

A process for preparing alkylene glycol from particulate matter comprising hemicellulose, cellulose and lignin, which process comprises the steps of subjecting a reactor comprising such particulate matter to a two-stage hydrolysis in the presence of hydrochloric acid to hydrolase the hemicellulose and cellulose in the particulate matter to saccharides, followed by subjecting the obtained hydrolysates to a catalytic conversion with hydrogen and in the presence of a catalyst system to a product comprising one or more alkylene glycols.

A process for preparing alkylene glycol from particulate matter comprising hemicellulose, cellulose and lignin, which process comprises the steps of subjecting a reactor comprising such particulate matter to a two-stage hydrolysis in the presence of hydrochloric acid to hydrolase the hemicellulose and cellulose in the particulate matter to saccharides, followed by subjecting the obtained hydrolysates to a catalytic conversion with hydrogen and in the presence of a catalyst system to a product comprising one or more alkylene glycols.

A process for preparing alkylene glycol from particulate matter comprising hemicellulose, cellulose and lignin, which process comprises the steps of subjecting a reactor comprising such particulate matter to a two-stage hydrolysis in the presence of hydrochloric acid to hydrolase the hemicellulose and cellulose in the particulate matter to saccharides, followed by subjecting the obtained hydrolysates to a catalytic conversion with hydrogen and in the presence of a catalyst system to a product comprising one or more alkylene glycols.

The invention concerns a method for preparing a mixture containing cyclohexanol and cyclohexanone, comprising the step of hydrogenating cyclohexyl hydroperoxide in cyclohexane in the presence of a Raney nickel catalyst to give cyclohexanol and cyclohexanone.

The invention concerns a method for preparing a mixture containing cyclohexanol and cyclohexanone, comprising the step of hydrogenating cyclohexyl hydroperoxide in cyclohexane in the presence of a Raney nickel catalyst to give cyclohexanol and cyclohexanone.