Proposed is a process for producing methanol from synthesis gas by means of multi-stage, for example 2-stage, heterogeneously catalyzed methanol synthesis, wherein the product stream of a synthesis stage is applied to the downstream synthesis stage as a feed stream or after removal of a purge stream recycled to the first synthesis stage as a recycle stream. According to the invention a substream is removed from the synthesis gas fresh gas and introduced into the second methanol synthesis reactor as a bypass stream.

Proposed is a process for producing methanol from synthesis gas by means of multi-stage, for example 2-stage, heterogeneously catalyzed methanol synthesis, wherein the product stream of a synthesis stage is applied to the downstream synthesis stage as a feed stream or after removal of a purge stream recycled to the first synthesis stage as a recycle stream. According to the invention a substream is removed from the synthesis gas fresh gas and introduced into the second methanol synthesis reactor as a bypass stream.

Compositions and methods of use related to metal organic frameworks (MOFs) and/or nanoparticles are generally described. In some embodiments, methods and compositions for the catalytic upgrading of alcohols using MOFs and/or nanoparticles associated with MOFs are generally described. In some embodiments, a catalytic MOF composition is provided, wherein the MOF composition comprises a MOF compound and a plurality of metal catalytic compounds. In some embodiments, an alcohol may be exposed to the MOF composition and/or a plurality of nanoparticles associated with the MOF composition such that the alcohol is converted to a higher order alcohol. Advantageously, in some embodiments, the alcohol conversion occurs at a relatively high turnover frequency and/or with a relatively high selectivity as compared to traditional methods for converting alcohols.

The present invention relates generally to methods for producing renewable detergent compounds. More specifically, the invention relates to methods for producing detergent intermediates, including bio-linear alkylbenzene (LAB), bio-alcohols, and long chain bio-paraffins, from natural oils.

The present invention relates generally to methods for producing renewable detergent compounds. More specifically, the invention relates to methods for producing detergent intermediates, including bio-linear alkylbenzene (LAB), bio-alcohols, and long chain bio-paraffins, from natural oils.

The present invention relates generally to methods for producing renewable detergent compounds. More specifically, the invention relates to methods for producing detergent intermediates, including bio-linear alkylbenzene (LAB), bio-alcohols, and long chain bio-paraffins, from natural oils.

A method of recovering 2-ethyl hexanol (2-EH) from crude alcohol that includes the 2-ethyl hexanol, 2-ethyl, 3-propyl acrolein (EPA), and 2-ethylhexanal (EHA) is disclosed. The crude alcohol stream is first separated into a first stream of primarily 2-EH, a second stream of primarily EPA and 2-EH collectively, and a third stream of primarily 2-EH and EHA collectively. The second stream and the third stream are combined to form a combined stream. The combined stream is processed further to form a first product stream comprising primarily 2-EH and a second product stream comprising primarily, 2-EH, EHA, and EPA collectively.

A method of recovering 2-ethyl hexanol (2-EH) from crude alcohol that includes the 2-ethyl hexanol, 2-ethyl, 3-propyl acrolein (EPA), and 2-ethylhexanal (EHA) is disclosed. The crude alcohol stream is first separated into a first stream of primarily 2-EH, a second stream of primarily EPA and 2-EH collectively, and a third stream of primarily 2-EH and EHA collectively. The second stream and the third stream are combined to form a combined stream. The combined stream is processed further to form a first product stream comprising primarily 2-EH and a second product stream comprising primarily, 2-EH, EHA, and EPA collectively.

The present invention relates to a method for producing an aldehyde by a hydroformylation reaction of reacting an olefin with hydrogen and carbon monoxide in the presence of a Group 8 to 10 metal-phosphine complex catalyst, including the following steps (1) and (2): (1) a step of oxidizing by withdrawing a reaction solution having accumulated therein a high-boiling-point byproduct from a reaction zone and bringing the withdrawn reaction solution into contact with an oxygen-containing gas, and (2) a step of, after the step (1), mixing a poor solvent and hydrogen with the reaction solution, then crystallizing the Group 8 to 10 metal-phosphine complex catalyst by crystallization, and recovering the crystallized complex catalyst from the reaction solution.

The present invention relates generally to methods for producing renewable detergent compounds. More specifically, the invention relates to methods for producing detergent intermediates, including bio-linear alkylbenzene (LAB), bio-alcohols, and long chain bio-paraffins, from natural oils.