Patent classifications
C07C29/32
CYCLOPROPANATION OF SUBSTITUTED ALKENES
Disclosed is a cyclopropanation process comprising the step of reacting an alkene compound having at least one carbon-carbon double bond with at least one dihaloalkane. The reaction is carried out in the presence of (i) particulate metal Zn, (ii) catalytically effective amount of particulate metal Cu or a salt thereof, (iii) at least one haloalkylsilane, and (iv) at least one solvent.
Process for preparing perhydrofluorene or alkyl-substituted perhydrofluorene
The present invention discloses a process for preparing perhydrofluorene or alkyl-substituted perhydrofluorene, comprising the steps of: (1) reacting a phenolic compound or an aromatic hydrocarbon compound or an aromatic ketone compound or an aromatic ether compound with a benzyl compound to carry out an alkylation reaction in the presence of a first catalyst, thereby to produce substituted or unsubstituted diphenyl methane, wherein the first catalyst is an acidic catalyst; and (2) reacting the substituted or unsubstituted diphenyl methane with hydrogen gas to carry out an hydrogenation reaction or a hydrodeoxygenation reaction, thereby to produce perhydrofluorene or alkyl-substituted perhydrofluorene, wherein the second catalyst is a physical mixture of a metal catalyst and an acidic catalyst or a metal catalyst loaded on an acidic catalyst.
Process for preparing perhydrofluorene or alkyl-substituted perhydrofluorene
The present invention discloses a process for preparing perhydrofluorene or alkyl-substituted perhydrofluorene, comprising the steps of: (1) reacting a phenolic compound or an aromatic hydrocarbon compound or an aromatic ketone compound or an aromatic ether compound with a benzyl compound to carry out an alkylation reaction in the presence of a first catalyst, thereby to produce substituted or unsubstituted diphenyl methane, wherein the first catalyst is an acidic catalyst; and (2) reacting the substituted or unsubstituted diphenyl methane with hydrogen gas to carry out an hydrogenation reaction or a hydrodeoxygenation reaction, thereby to produce perhydrofluorene or alkyl-substituted perhydrofluorene, wherein the second catalyst is a physical mixture of a metal catalyst and an acidic catalyst or a metal catalyst loaded on an acidic catalyst.
Cyclopropanation of substituted alkenes
Disclosed is a cyclopropanation process comprising the step of reacting an alkene compound having at least one carbon-carbon double bond with at least one dihaloalkane. The reaction is carried out in the presence of (i) particulate metal Zn, (ii) catalytically effective amount of particulate metal Cu or a salt thereof, (iii) at least one haloalkylsilane, and (iv) at least one solvent.
Cyclopropanation of substituted alkenes
Disclosed is a cyclopropanation process comprising the step of reacting an alkene compound having at least one carbon-carbon double bond with at least one dihaloalkane. The reaction is carried out in the presence of (i) particulate metal Zn, (ii) catalytically effective amount of particulate metal Cu or a salt thereof, (iii) at least one haloalkylsilane, and (iv) at least one solvent.
Cyclopropanation of substituted alkenes
Disclosed is a cyclopropanation process comprising the step of reacting an alkene compound having at least one carbon-carbon double bond with at least one dihaloalkane. The reaction is carried out in the presence of (i) particulate metal Zn, (ii) catalytically effective amount of particulate metal Cu or a salt thereof, (iii) at least one haloalkylsilane, and (iv) at least one solvent.
Methods and system for decreasing gas emissions from landfills
A method of diverting municipal solid waste (MSW) from a landfill that includes receiving, at a MSW processing system, a quantity of MSW, gasifying the quantity of MSW in a gasification unit to yield a syngas stream and biochar stream, converting at least a portion of the syngas to mixed alcohols in an alcohol synthesis unit, separating the mixed alcohols into one or more alcohol products, and determining a carbon offset for diverting the MSW from the landfill to the MSW processing system.
Methods and system for decreasing gas emissions from landfills
A method of diverting municipal solid waste (MSW) from a landfill that includes receiving, at a MSW processing system, a quantity of MSW, gasifying the quantity of MSW in a gasification unit to yield a syngas stream and biochar stream, converting at least a portion of the syngas to mixed alcohols in an alcohol synthesis unit, separating the mixed alcohols into one or more alcohol products, and determining a carbon offset for diverting the MSW from the landfill to the MSW processing system.
Methods and system for decreasing gas emissions from landfills
A method of diverting municipal solid waste (MSW) from a landfill that includes receiving, at a MSW processing system, a quantity of MSW, gasifying the quantity of MSW in a gasification unit to yield a syngas stream and biochar stream, converting at least a portion of the syngas to mixed alcohols in an alcohol synthesis unit, separating the mixed alcohols into one or more alcohol products, and determining a carbon offset for diverting the MSW from the landfill to the MSW processing system.
CYCLOPROPANE COMPOUND
Provided are a compound and a fragrance composition that are excellent in harmony with various other fragrance materials and can be blended to impart a natural and fresh floral feeling. The present invention provides a cyclopropane compound represented by Formula (I) and a fragrance composition containing a cyclopropane compound represented by Formula (I):
##STR00001##
where R.sup.1 is a methyl group and R.sup.2 is a methyl group, or R.sup.1 is a hydrogen atom and R.sup.2 is an ethyl group.