Patent classifications
C07C29/56
CATALYST SYSTEM
Proposed is a catalyst system specifically for the rearrangement of epoxides into allyl alcohols comprising or consisting of (a) a salt of formula (I) XY (I) in which X represents Zn.sup.2+ and/or Co.sup.2+ and Y represents an anion selected from the group formed from laurate, palmitate, stearate, picolinate, glycinate, gluconate, naphthenate, 2-hexyldecanoate, 2-octyldodecanoate, cyclohexane butyrate and mixtures thereof, and (b) at least one aminophenol.
Homogeneous Catalysts That Are Recoverable By Host Guest Interactions
A method for separating a homogeneous catalyst from a solution includes forming a host-guest compound between a first isomer of the catalyst and inclusion compound in the solution and isolating the host-guest compound from the solution. The catalyst may be released from the inclusion compound by converting the first isomer of the catalyst to a second isomer of the catalyst.
Homogeneous Catalysts That Are Recoverable By Host Guest Interactions
A method for separating a homogeneous catalyst from a solution includes forming a host-guest compound between a first isomer of the catalyst and inclusion compound in the solution and isolating the host-guest compound from the solution. The catalyst may be released from the inclusion compound by converting the first isomer of the catalyst to a second isomer of the catalyst.
COMPOSITIONS AND METHODS FOR MEALYBUG MONITORING AND CONTROL
A preparation comprising gamma-necrodyl isobutyrate and an agriculturally acceptable carrier is disclosed for the monitoring and control of mealybugs. Methods of synthesizing the preparation and other mealybug pheromones that feature a necrodane structure are also disclosed.
COMPOSITIONS AND METHODS FOR MEALYBUG MONITORING AND CONTROL
A preparation comprising gamma-necrodyl isobutyrate and an agriculturally acceptable carrier is disclosed for the monitoring and control of mealybugs. Methods of synthesizing the preparation and other mealybug pheromones that feature a necrodane structure are also disclosed.
Process for producing prenol and prenal from isoprenol
The present invention relates to a process for preparing 3-methyl-2-butenol (prenol) and 3-methyl-2-butenal (prenal) from 3-methyl-3-butenol (isoprenol), in which 3-methyl-3-butenol is subjected to a catalytic isomerization over a carbon-supported Pd catalyst in the presence of a gas mixture comprising 1% to 15% by volume of oxygen to obtain a first product mixture, and the first product mixture is subjected to an oxidative dehydrogenation over a Pd catalyst comprising SiO.sub.2 and/or Al.sub.2O.sub.3 as support material, or over a carbon-supported Pd/Au catalyst in the presence of a gas mixture comprising 5% to 25% by volume of oxygen.
Process for producing prenol and prenal from isoprenol
The present invention relates to a process for preparing 3-methyl-2-butenol (prenol) and 3-methyl-2-butenal (prenal) from 3-methyl-3-butenol (isoprenol), in which 3-methyl-3-butenol is subjected to a catalytic isomerization over a carbon-supported Pd catalyst in the presence of a gas mixture comprising 1% to 15% by volume of oxygen to obtain a first product mixture, and the first product mixture is subjected to an oxidative dehydrogenation over a Pd catalyst comprising SiO.sub.2 and/or Al.sub.2O.sub.3 as support material, or over a carbon-supported Pd/Au catalyst in the presence of a gas mixture comprising 5% to 25% by volume of oxygen.
Process for producing prenol and prenal from isoprenol
The present invention relates to a process for preparing 3-methyl-2-butenol (prenol) and 3-methyl-2-butenal (prenal) from 3-methyl-3-butenol (isoprenol), in which 3-methyl-3-butenol is subjected to a catalytic isomerization over a carbon-supported Pd catalyst in the presence of a gas mixture comprising 1% to 15% by volume of oxygen to obtain a first product mixture, and the first product mixture is subjected to an oxidative dehydrogenation over a Pd catalyst comprising SiO.sub.2 and/or Al.sub.2O.sub.3 as support material, or over a carbon-supported Pd/Au catalyst in the presence of a gas mixture comprising 5% to 25% by volume of oxygen.
Water Soluble Homogeneous Catalysts That Are Recoverable By Phase Selectivity And Host-Guest Interactions
A chemical reaction is catalyzed in an organic solvent using a water soluble N-heterocyclic carbene homogeneous catalyst to form a reaction mixture. An aqueous phase in the reaction mixture. A solvent in which the catalyst is insoluble is added to the reaction mixture, causing the catalyst to migrate to the aqueous phase to form a catalyst-laden aqueous phase. The catalyst is extracted from the catalyst-laden aqueous phase.
Water Soluble Homogeneous Catalysts That Are Recoverable By Phase Selectivity And Host-Guest Interactions
A chemical reaction is catalyzed in an organic solvent using a water soluble N-heterocyclic carbene homogeneous catalyst to form a reaction mixture. An aqueous phase in the reaction mixture. A solvent in which the catalyst is insoluble is added to the reaction mixture, causing the catalyst to migrate to the aqueous phase to form a catalyst-laden aqueous phase. The catalyst is extracted from the catalyst-laden aqueous phase.