The present invention relates to a process for producing a diene, preferably a conjugated diene, more preferably 1,3-butadiene, comprising the dehydration of at least one alkenol having a number of carbon atoms greater than or equal to 4, in the presence of a catalytic material comprising at least one crystalline metalosilicate in acid form, preferably a macroporous zeolite, more preferably a zeolite with a FAU, BEA or MTW structure. Preferably, said alkenol having a number of carbon atoms greater than or equal to 4 may be obbtained directly through biosynthetic processes, or through catalytic dehydration processes of at least one diol. When said alkenol is a butenol, said diol is preferably a butanediol, more preferably 1,3-butanediol, even more preferably bio-1,3-butanediol, i.e. 1,3-butanediol deriving from biosynthetic processes. When said alkenol is 1,3-butanediol, or bio-1,3-butanediol, the diene obtained with the process according to the present invention is, respectively, 1,3-butadiene, or bio-1,3-butadiene.

The present invention relates to a process for producing a diene, preferably a conjugated diene, more preferably 1,3-butadiene, comprising the dehydration of at least one alkenol having a number of carbon atoms greater than or equal to 4, in the presence of a catalytic material comprising at least one crystalline metalosilicate in acid form, preferably a macroporous zeolite, more preferably a zeolite with a FAU, BEA or MTW structure. Preferably, said alkenol having a number of carbon atoms greater than or equal to 4 may be obbtained directly through biosynthetic processes, or through catalytic dehydration processes of at least one diol. When said alkenol is a butenol, said diol is preferably a butanediol, more preferably 1,3-butanediol, even more preferably bio-1,3-butanediol, i.e. 1,3-butanediol deriving from biosynthetic processes. When said alkenol is 1,3-butanediol, or bio-1,3-butanediol, the diene obtained with the process according to the present invention is, respectively, 1,3-butadiene, or bio-1,3-butadiene.

The present invention relates to a process for producing a diene, preferably a conjugated diene, more preferably 1,3-butadiene, comprising the dehydration of at least one alkenol having a number of carbon atoms greater than or equal to 4, in the presence of a catalytic material comprising at least one crystalline metalosilicate in acid form, preferably a macroporous zeolite, more preferably a zeolite with a FAU, BEA or MTW structure. Preferably, said alkenol having a number of carbon atoms greater than or equal to 4 may be obbtained directly through biosynthetic processes, or through catalytic dehydration processes of at least one diol. When said alkenol is a butenol, said diol is preferably a butanediol, more preferably 1,3-butanediol, even more preferably bio-1,3-butanediol, i.e. 1,3-butanediol deriving from biosynthetic processes. When said alkenol is 1,3-butanediol, or bio-1,3-butanediol, the diene obtained with the process according to the present invention is, respectively, 1,3-butadiene, or bio-1,3-butadiene.

A process for preparing alkylene glycol from particulate matter comprising hemicellulose, cellulose and lignin, which process comprises the steps of subjecting a reactor comprising such particulate matter to a two-stage hydrolysis in the presence of hydrochloric acid to hydrolase the hemicellulose and cellulose in the particulate matter to saccharides, followed by subjecting the obtained hydrolysates to a catalytic conversion with hydrogen and in the presence of a catalyst system to a product comprising one or more alkylene glycols.

A process for preparing alkylene glycol from particulate matter comprising hemicellulose, cellulose and lignin, which process comprises the steps of subjecting a reactor comprising such particulate matter to a two-stage hydrolysis in the presence of hydrochloric acid to hydrolase the hemicellulose and cellulose in the particulate matter to saccharides, followed by subjecting the obtained hydrolysates to a catalytic conversion with hydrogen and in the presence of a catalyst system to a product comprising one or more alkylene glycols.

A process for preparing alkylene glycol from particulate matter comprising hemicellulose, cellulose and lignin, which process comprises the steps of subjecting a reactor comprising such particulate matter to a two-stage hydrolysis in the presence of hydrochloric acid to hydrolase the hemicellulose and cellulose in the particulate matter to saccharides, followed by subjecting the obtained hydrolysates to a catalytic conversion with hydrogen and in the presence of a catalyst system to a product comprising one or more alkylene glycols.

Provided is a method capable of manufacturing high-purity 1,3-butylene glycol having a high potassium permanganate test value, a very low content of low boiling point components, and a high initial boiling point with a high recovery rate.

The method for manufacturing 1,3-butylene is a method for obtaining purified 1,3-butylene glycol from a crude reaction liquid containing 1,3-butylene glycol. In a dehydration column used in a dehydration step, a liquid feed containing 1,3-butylene glycol and water with an acetaldehyde content of 1000 ppm or lower and a crotonaldehyde content of 400 ppm or lower is distilled under a condition of a reflux ratio of higher than 0.3, and a liquid concentrated with a low boiling point component containing water is distilled off from above a feed tray. In a product column used in a product distillation step, a 1,3-butylene glycol liquid feed with an acetaldehyde content of 500 ppm or lower and a crotonaldehyde content of 200 ppm or lower is distilled under a condition of a reflux ratio of higher than 0.1.

An integrated production plant system includes, at one production site at least two plants of different kinds selected from a renewable paraffinic fuel plant to produce renewable paraffinic fuel in a renewable paraffinic fuel process, a renewable fatty acid alkyl ester (FAAE) fuel plant to produce renewable FAAE fuel in a renewable FAAE process, a renewable base oil plant to produce renewable base oil in a renewable base oil process, and a renewable chemical plant to produce renewable chemical in a renewable chemical process. Each of the processes is provided with a respective renewable feed, where the feed of each of the processes originates from a common renewable system feed, and the feed to at least one of the processes is altered for example by directing at least part of the feed of at least one of the processes to another of the processes.

An integrated production plant system includes, at one production site at least two plants of different kinds selected from a renewable paraffinic fuel plant to produce renewable paraffinic fuel in a renewable paraffinic fuel process, a renewable fatty acid alkyl ester (FAAE) fuel plant to produce renewable FAAE fuel in a renewable FAAE process, a renewable base oil plant to produce renewable base oil in a renewable base oil process, and a renewable chemical plant to produce renewable chemical in a renewable chemical process. Each of the processes is provided with a respective renewable feed, where the feed of each of the processes originates from a common renewable system feed, and the feed to at least one of the processes is altered for example by directing at least part of the feed of at least one of the processes to another of the processes.

Provided is a method capable of yielding high-purity 1,3-butylene glycol having a very low content of a low boiling point component and a high initial boiling point, with a high recovery ratio. A reaction crude liquid containing 1,3-butylene glycol is subjected to product distillation to yield purified 1,3-butylene glycol, through dehydration including removing water by distillation and performing high boiling point component removal including removing a high boiling point component by distillation. A method for producing 1,3 butylene glycol, the method including: distilling a charged liquid having a water content of 1.2 wt.% or less in a product column for use in the product distillation under a condition of a reflux ratio of greater than 0.1; distilling off a liquid in which a low boiling point component is concentrated from above a charging plate; and extracting 1,3-butylene glycol from below the charging plate.