Retro-aldol processes are disclosed that use very low concentrations of retro-aldol catalyst in combination with hydrogenation catalyst of certain activities, sizes and spatial dispersions to obtain the high selectivities to ethylene glycol.

Disclosed is a liquid production method and device for producing a liquid containing water-soluble components. The liquid production method includes extracting water-soluble components from a biological tissue, using a liquefied gas, to yield an extraction liquid, and vaporizing the liquefied gas from the extraction liquid obtained in the extracting to concentrate the extraction liquid.

Disclosed is a liquid production method and device for producing a liquid containing water-soluble components. The liquid production method includes extracting water-soluble components from a biological tissue, using a liquefied gas, to yield an extraction liquid, and vaporizing the liquefied gas from the extraction liquid obtained in the extracting to concentrate the extraction liquid.

Retro-aldol processes are disclosed that use very low concentrations of retro-aldol catalyst in combination with hydrogenation catalyst of certain activities, sizes and spatial dispersions to obtain the high selectivities to ethylene glycol.

Retro-aldol processes are disclosed that use very low concentrations of retro-aldol catalyst in combination with hydrogenation catalyst of certain activities, sizes and spatial dispersions to obtain the high selectivities to ethylene glycol.

Retro-aldol processes are disclosed that use very low concentrations of retro-aldol catalyst in combination with hydrogenation catalyst of certain activities, sizes and spatial dispersions to obtain the high selectivities to ethylene glycol.

An integrated facility for the co-production of ethanol and the pretreatment of impure vegetable oils, waxes and (animal) fats is provided. A by-product from the ethanol plant, such as distillers corn oil or distillers sorghum oil, can be directly refined on site to remove contaminants such as metals, phospholipids and inorganic anions, to enable use as ready feedstocks for a renewable diesel hydrotreatment plant. The utility of the ethanol plant infrastructure can be directly harnessed to pretreat and purify a variety of impure feedstock materials. The pretreatment reduces catalytic poisoning in the reduction process at refining facilities during the synthesis of renewable diesel. By-products of the pretreatment process are recycled to various parts of the ethanol plant for incorporation into the animal feed(s) produced by the ethanol plant or incorporated into the existing wastewater treatment and disposal system within the ethanol plant.

An integrated facility for the co-production of ethanol and the pretreatment of impure vegetable oils, waxes and (animal) fats is provided. A by-product from the ethanol plant, such as distillers corn oil or distillers sorghum oil, can be directly refined on site to remove contaminants such as metals, phospholipids and inorganic anions, to enable use as ready feedstocks for a renewable diesel hydrotreatment plant. The utility of the ethanol plant infrastructure can be directly harnessed to pretreat and purify a variety of impure feedstock materials. The pretreatment reduces catalytic poisoning in the reduction process at refining facilities during the synthesis of renewable diesel. By-products of the pretreatment process are recycled to various parts of the ethanol plant for incorporation into the animal feed(s) produced by the ethanol plant or incorporated into the existing wastewater treatment and disposal system within the ethanol plant.

A method for preparing 1,2-propanediol and dipropylene glycol involves continuously reacting propene with hydrogen peroxide in the presence of a catalyst mixture, containing a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase, to obtain 1,2-propanediol and dipropylene glycol. The method then involves separating the reaction mixture into an aqueous phase (P.sub.a) containing 1,2-propanediol and dipropylene glycol and an organic phase (P.sub.o); recycling at least part of the separated organic phase (P.sub.o) to the reaction; and recovering 1,2-propanediol and dipropylene glycol from the separated aqueous phase (P.sub.a), The reaction heat generated is at least partially removed, and the ratio of 1,2 propanediol to dipropylene glycol is controlled by adjusting the weight ratio of hydrogen peroxide to water fed to the reaction.

A method for preparing 1,2-propanediol and dipropylene glycol involves continuously reacting propene with hydrogen peroxide in the presence of a catalyst mixture, containing a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase, to obtain 1,2-propanediol and dipropylene glycol. The method then involves separating the reaction mixture into an aqueous phase (P.sub.a) containing 1,2-propanediol and dipropylene glycol and an organic phase (P.sub.o); recycling at least part of the separated organic phase (P.sub.o) to the reaction; and recovering 1,2-propanediol and dipropylene glycol from the separated aqueous phase (P.sub.a), The reaction heat generated is at least partially removed, and the ratio of 1,2 propanediol to dipropylene glycol is controlled by adjusting the weight ratio of hydrogen peroxide to water fed to the reaction.