Aqueous compositions containing 6-undecanol-esters are useful in cosmetic aplications. Methods for producing 6-undecanol-esters are also provided.

A method is used to prepare silver nanoparticles in the form of a silver nanoparticle cellulosic polymeric composite. A cellulosic polymer, organic solvent having a boiling point at atmospheric pressure of 100 C. to 500 C. and a Hansen parameter (.sub.T.sup.Polymer) equal to or greater than that of the cellulosic polymer, and a nitrogenous base are mixed to form a premix solution. Upon heating the premix solution to a temperature of at least 75 C., a solution of reducible silver ions is added that is equimolar or less in relation to the nitrogenous base. The weight ratio of reducible silver ions to the cellulosic polymer is 5:1 to 50:1. The resulting silver nanoparticle composite is cooled, isolated, and re-dispersed in an organic solvent, providing a non-aqueous silver-containing dispersion comprising the silver nanoparticle cellulosic polymeric composite.

Disclosed herein are reaction compositions comprising an oxidation catalyst, a solvent, and a substrate that is dissolved in the solvent. The oxidation catalyst comprises a metal ion complexed with an -keto acid and a tridentate N,N,O-ligand. Also disclosed herein are methods for oxidizing a CH bond of a molecule, the methods comprising contacting the molecule with a metal complex comprising a metal ion complexed with a tridentate N,N,O-ligand in the presence of an -keto acid and a solvent. In some embodiments, the oxidation catalyst or metal complex is linked to a solid support.

Disclosed herein are reaction compositions comprising an oxidation catalyst, a solvent, and a substrate that is dissolved in the solvent. The oxidation catalyst comprises a metal ion complexed with an -keto acid and a tridentate N,N,O-ligand. Also disclosed herein are methods for oxidizing a CH bond of a molecule, the methods comprising contacting the molecule with a metal complex comprising a metal ion complexed with a tridentate N,N,O-ligand in the presence of an -keto acid and a solvent. In some embodiments, the oxidation catalyst or metal complex is linked to a solid support.

To provide a method for producing a Guerbet alcohol without necessity of the use of a solvent, capable of enhancing the conversion and the yield. A method for producing a Guerbet alcohol, including the following steps 1 to 3 in this order: step 1: preparing a liquid composition containing an aliphatic alcohol and a base; step 2: holding the liquid composition at 100 C. or more and 180 C. or less to thereby adjust a water amount in the liquid composition to less than 0.28% by mass; and step 3: setting the liquid composition to be more than 180 C.

To provide a method for producing a Guerbet alcohol without necessity of the use of a solvent, capable of enhancing the conversion and the yield. A method for producing a Guerbet alcohol, including the following steps 1 to 3 in this order: step 1: preparing a liquid composition containing an aliphatic alcohol and a base; step 2: holding the liquid composition at 100 C. or more and 180 C. or less to thereby adjust a water amount in the liquid composition to less than 0.28% by mass; and step 3: setting the liquid composition to be more than 180 C.

A chemoselective process for producing alcohols from ,-unsaturated aldehydes and ketones is described.

A chemoselective process for producing alcohols from ,-unsaturated aldehydes and ketones is described.

The present disclosure provides an apparatus and method for producing a policosanol having a specific chromatographic fingerprint. The apparatus of the present disclosure has a feed tank and receiving tanks which are connected to a vacuum system. The method of the present disclosure is carried out by a high vacuum rectification process and includes: firstly, feeding a saponified crude alkanol into a melting tank in which the material is melted and then flows into the feed tank, and then injecting the material into a rectifying still using a delivery pump, followed by first rectification under vacuum condition and sequential collection of fractions at different phases from the tower top and stillage residue from the tower bottom; and after the completion of the rectification of the first batch crude product, carrying out second feeding on the basis of consistent vacuum in the feed tank and the rectifying tower.

The present disclosure provides an apparatus and method for producing a policosanol having a specific chromatographic fingerprint. The apparatus of the present disclosure has a feed tank and receiving tanks which are connected to a vacuum system. The method of the present disclosure is carried out by a high vacuum rectification process and includes: firstly, feeding a saponified crude alkanol into a melting tank in which the material is melted and then flows into the feed tank, and then injecting the material into a rectifying still using a delivery pump, followed by first rectification under vacuum condition and sequential collection of fractions at different phases from the tower top and stillage residue from the tower bottom; and after the completion of the rectification of the first batch crude product, carrying out second feeding on the basis of consistent vacuum in the feed tank and the rectifying tower.