C07C31/28

OLEFIN POLYMERIZATION CATALYST CARRIER, SOLID CATALYST COMPONENT AND USE THEREOF

A method of making an olefin polymerization catalyst carrier with a general structure formula of Mg(OR.sup.I).sub.n(OR.sup.II).sub.2-n, wherein: 0n2, and R.sup.I and R.sup.II can be the same or different and are each independently selected from a C.sub.1-C.sub.20 hydrocarbon group by reacting an alcohol with a metal magnesium powder under the protection of nitrogen in the presence of a halogen or a halogen-containing compound to obtain a first product, and subjecting the product to a treatment pressure of from 0.2 to 5.0 MPa at a treatment temperature of from 80 to 200 C. for a duration of between 2 minutes and 6 hours. Also provided is a method of making an olefin polymerization solid catalyst component which includes the catalyst carrier, a titanium compound, and at least one electron donor compound.

OLEFIN POLYMERIZATION CATALYST CARRIER, SOLID CATALYST COMPONENT AND USE THEREOF

A method of making an olefin polymerization catalyst carrier with a general structure formula of Mg(OR.sup.I).sub.n(OR.sup.II).sub.2-n, wherein: 0n2, and R.sup.I and R.sup.II can be the same or different and are each independently selected from a C.sub.1-C.sub.20 hydrocarbon group by reacting an alcohol with a metal magnesium powder under the protection of nitrogen in the presence of a halogen or a halogen-containing compound to obtain a first product, and subjecting the product to a treatment pressure of from 0.2 to 5.0 MPa at a treatment temperature of from 80 to 200 C. for a duration of between 2 minutes and 6 hours. Also provided is a method of making an olefin polymerization solid catalyst component which includes the catalyst carrier, a titanium compound, and at least one electron donor compound.

Metal alkoxide complex, catalyst composition, and production method of polycaprolactone or polylactide

The invention provides a metal alkoxide complex of Formula (I), wherein X, M, R1, R2, R3, m, n, y and z are as defined in the Description. The invention also provides a catalyst composition comprising the metal alkoxide complex and a hydroxy-containing compound, wherein the molar ratio of the metal alkoxide complex to the hydroxy-containing compound is 1:0.1-1000. The invention also provides a production method of poly--caprolactone or polyactide, wherein an -caprolactone monomer or a lactide monomer is reacted in the presence of the metal alkoxide complex or catalyst composition to obtain poly--caprolactone or polylactide. The metal alkoxide complex and the catalyst composition thereof can be used to catalyze the synthesis of poly--caprolactone or polylactide with a high efficiency. The molecular weight of polycaprolactone or polylactide can be controlled by the molar ratio of the metal alkoxide complex and the hydroxy-containing compound, and is adjustable in the range of 1000-600,000, and wherein the molecular weight distribution is from 1.03 to 1.50.
[X.sub.n-mM(OCR.sub.1R.sub.2R.sub.3).sub.m].sub.y.(organic solvent).sub.z (I)

Metal alkoxide complex, catalyst composition, and production method of polycaprolactone or polylactide

The invention provides a metal alkoxide complex of Formula (I), wherein X, M, R1, R2, R3, m, n, y and z are as defined in the Description. The invention also provides a catalyst composition comprising the metal alkoxide complex and a hydroxy-containing compound, wherein the molar ratio of the metal alkoxide complex to the hydroxy-containing compound is 1:0.1-1000. The invention also provides a production method of poly--caprolactone or polyactide, wherein an -caprolactone monomer or a lactide monomer is reacted in the presence of the metal alkoxide complex or catalyst composition to obtain poly--caprolactone or polylactide. The metal alkoxide complex and the catalyst composition thereof can be used to catalyze the synthesis of poly--caprolactone or polylactide with a high efficiency. The molecular weight of polycaprolactone or polylactide can be controlled by the molar ratio of the metal alkoxide complex and the hydroxy-containing compound, and is adjustable in the range of 1000-600,000, and wherein the molecular weight distribution is from 1.03 to 1.50.
[X.sub.n-mM(OCR.sub.1R.sub.2R.sub.3).sub.m].sub.y.(organic solvent).sub.z (I)

Metal alkoxide complex, catalyst composition, and production method of polycaprolactone or polylactide

The invention provides a metal alkoxide complex of Formula (I), wherein X, M, R1, R2, R3, m, n, y and z are as defined in the Description. The invention also provides a catalyst composition comprising the metal alkoxide complex and a hydroxy-containing compound, wherein the molar ratio of the metal alkoxide complex to the hydroxy-containing compound is 1:0.1-1000. The invention also provides a production method of poly--caprolactone or polyactide, wherein an -caprolactone monomer or a lactide monomer is reacted in the presence of the metal alkoxide complex or catalyst composition to obtain poly--caprolactone or polylactide. The metal alkoxide complex and the catalyst composition thereof can be used to catalyze the synthesis of poly--caprolactone or polylactide with a high efficiency. The molecular weight of polycaprolactone or polylactide can be controlled by the molar ratio of the metal alkoxide complex and the hydroxy-containing compound, and is adjustable in the range of 1000-600,000, and wherein the molecular weight distribution is from 1.03 to 1.50.
[X.sub.n-mM(OCR.sub.1R.sub.2R.sub.3).sub.m].sub.y.(organic solvent).sub.z (I)

Group 5 metal oxo-alkoxo complex, method for producing same, and method for manufacturing group 5 metal oxide film

A compound useful for the manufacture of a Group 5 metal oxide film is provided. The compound is a Group 5 metal oxo-alkoxo complex represented by the following formula (A), and after preparing a film-forming material solution containing the compound and an organic solvent, a Group 5 metal oxide film can be manufactured using the film-forming material solution:
M.sub.(.sub.4-O).sub.(.sub.3-O).sub.(-O).sub.(-OR.sup.A).sub.(OR.sup.A).sub.(R.sup.AOH).sub.X.sub.Y.sub..Math.(A)
(wherein M represents a niobium atom, etc.; R.sup.A represents an alkyl group; X represents an alkylenedioxy group; Y represents a carboxy group, etc.; represents an integer of 3 to 10; represents 0 or 1; represents an integer of 0 to 8; represents an integer of 2 to 9; represents an integer of 0 to 6; represents an integer of 6 to 16; represents an integer of 0 to 4; represents an integer of 0 to 2; and .Math. represents an integer of 0 to 6).

Group 5 metal oxo-alkoxo complex, method for producing same, and method for manufacturing group 5 metal oxide film

A compound useful for the manufacture of a Group 5 metal oxide film is provided. The compound is a Group 5 metal oxo-alkoxo complex represented by the following formula (A), and after preparing a film-forming material solution containing the compound and an organic solvent, a Group 5 metal oxide film can be manufactured using the film-forming material solution:
M.sub.(.sub.4-O).sub.(.sub.3-O).sub.(-O).sub.(-OR.sup.A).sub.(OR.sup.A).sub.(R.sup.AOH).sub.X.sub.Y.sub..Math.(A)
(wherein M represents a niobium atom, etc.; R.sup.A represents an alkyl group; X represents an alkylenedioxy group; Y represents a carboxy group, etc.; represents an integer of 3 to 10; represents 0 or 1; represents an integer of 0 to 8; represents an integer of 2 to 9; represents an integer of 0 to 6; represents an integer of 6 to 16; represents an integer of 0 to 4; represents an integer of 0 to 2; and .Math. represents an integer of 0 to 6).

Indium oxoalkoxides for producing coatings containing indium oxide

The present invention relates to halogenated indium oxo alkoxides of the generic formula In.sub.7O.sub.2(OH)(OR).sub.12X.sub.4(ROH).sub.x where R=C1-C15-alkyl, C1-C15-alkenyl, C1-C15-alkynyl, C1-C15-alkoxyalkyl, C6-C15-aryl- or C7-C15-alkoxyaryl, XF, Cl, Br, I and x=0 to 10, to processes for preparation thereof and to use thereof.

Indium oxoalkoxides for producing coatings containing indium oxide

The present invention relates to halogenated indium oxo alkoxides of the generic formula In.sub.7O.sub.2(OH)(OR).sub.12X.sub.4(ROH).sub.x where R=C1-C15-alkyl, C1-C15-alkenyl, C1-C15-alkynyl, C1-C15-alkoxyalkyl, C6-C15-aryl- or C7-C15-alkoxyaryl, XF, Cl, Br, I and x=0 to 10, to processes for preparation thereof and to use thereof.