The present invention relates to a process for producing butadiene from ethanol, in two reaction steps, comprising a step a) of converting ethanol into acetaldehyde and a step b) of conversion into butadiene, said step b) simultaneously implementing a reaction step and a regeneration step in (n+n/2) fixed-bed reactors, n being equal to 2 or a multiple thereof, comprising a catalyst, said regeneration step comprising four successive regeneration phases, said step b) also implementing a regeneration loop for the inert gas and at least one regeneration loop for the gas streams comprising oxygen.

The present invention relates to a process for producing butadiene from ethanol, in two reaction steps, comprising a step a) of converting ethanol into acetaldehyde and a step b) of conversion into butadiene, said step b) simultaneously implementing a reaction step and a regeneration step in (n+n/2) fixed-bed reactors, n being equal to 2 or a multiple thereof, comprising a catalyst, said regeneration step comprising four successive regeneration phases, said step b) also implementing a regeneration loop for the inert gas and at least one regeneration loop for the gas streams comprising oxygen.

The present invention relates to a transition metal complex having a PNNP4 ligand, which is easy to manufacture and handle and is relatively inexpensively available, and a method for manufacturing the same, as well as a method using this transition metal complex as a catalyst for hydrogenation reduction of ketones, esters and amides to manufacture corresponding alcohols, aldehydes, hemiacetals and hemiaminals, a method using this transition metal complex as a catalyst for oxidation of alcohols, hemiacetals and hemiaminals to manufacture corresponding carbonyl compounds, and a method using this transition metal complex as a catalyst for dehydrogenation condensation between alcohols and amines to manufacture alkylamines.

The present invention relates to a transition metal complex having a PNNP4 ligand, which is easy to manufacture and handle and is relatively inexpensively available, and a method for manufacturing the same, as well as a method using this transition metal complex as a catalyst for hydrogenation reduction of ketones, esters and amides to manufacture corresponding alcohols, aldehydes, hemiacetals and hemiaminals, a method using this transition metal complex as a catalyst for oxidation of alcohols, hemiacetals and hemiaminals to manufacture corresponding carbonyl compounds, and a method using this transition metal complex as a catalyst for dehydrogenation condensation between alcohols and amines to manufacture alkylamines.

The present invention relates to a process for preparing a poly(meth)acrylic acid, characterized in that a (meth)acrylic acid-containing process stream from (meth)acrolein synthesis is subjected to free-radical polymerization. The invention also relates to the esterification of the polymer obtained to give a homopolymer or copolymer ester, and to the use thereof as additive, flow improver and water reducer.

Disclosed are a nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst and a preparation method thereof. The preparation method includes preparing nitrogen-doped hierarchical-porous carbon, mixing the nitrogen-doped hierarchical-porous carbon with water, adjusting a pH value of the mixed solution to be alkaline, mixing the mixed solution with a Pd metal precursor aqueous solution, and then adding a reducing agent to obtain the nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst after reduction. The prepared nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst includes a nitrogen-doped porous carbon material carrier with hierarchical pores and Pd metal nanoparticles loaded in the hierarchical pores of the carrier. The Pd metal nanoparticles have a size of 2˜14 nm and a regular polyhedron shape. The nitrogen-doped hierarchical-porous carbon-loaded nano-Pd catalyst has excellent catalytic performance, especially has ultra-high conversion rate, selectivity and cycle stability in the selective hydrogenation reaction of unsaturated ketones, and is a key to open a new synthetic route of vitamin E.

A device includes: a storage section which stores a solution containing an organic compound; a catalyst holding section to hold a solid catalyst; and a microwave irradiation mechanism which irradiates the solution passing through the catalyst holding section with a microwave, wherein the solid catalyst is a molded catalyst containing a noble metal supported on a carrier that has an average particle diameter larger than 100 m. A hydrogen production method includes irradiating a solution containing an organic compound, the solution passing through a catalyst holding section holding a solid catalyst, with a microwave, the solid catalyst being a molded catalyst containing a noble metal supported on a carrier that has an average particle diameter larger than 100 m. Both device and method do not require a high-temperature heat source, enable easy collection, replacement, of the catalyst, and can be used for production of hydrogen.

A device includes: a storage section which stores a solution containing an organic compound; a catalyst holding section to hold a solid catalyst; and a microwave irradiation mechanism which irradiates the solution passing through the catalyst holding section with a microwave, wherein the solid catalyst is a molded catalyst containing a noble metal supported on a carrier that has an average particle diameter larger than 100 m. A hydrogen production method includes irradiating a solution containing an organic compound, the solution passing through a catalyst holding section holding a solid catalyst, with a microwave, the solid catalyst being a molded catalyst containing a noble metal supported on a carrier that has an average particle diameter larger than 100 m. Both device and method do not require a high-temperature heat source, enable easy collection, replacement, of the catalyst, and can be used for production of hydrogen.

An apparatus for the production of formaldehyde is disclosed. The apparatus comprises a cooled tubular reactor section (8, 108, 208, 308, 408, 508) having a first inlet, a first outlet and a plurality of tubes each having a first end in fluid communication with the first inlet and a second end in fluid communication with the first outlet. The plurality of tubes contain a first catalyst for the production of formaldehyde by oxidative dehydrogenation. The apparatus is characterised in that the apparatus further comprises a pre-reactor section (7, 107, 207, 307, 407, 507). The pre-reactor section (7, 107, 207, 307, 407, 507) has an inlet. The pre-reactor section (7, 107, 207, 307, 407, 507) has an outlet in fluid communication with the first inlet of the cooled tubular reactor section (8, 108, 208, 308, 408, 508). The pre-reactor section (7, 107, 207, 307, 407, 507) is configured to contain, in use, an adiabatic catalyst bed. The adiabatic catalyst bed comprises a second catalyst for the production of formaldehyde by catalytic oxidative dehydrogenation.

An apparatus for the production of formaldehyde is disclosed. The apparatus comprises a cooled tubular reactor section (8, 108, 208, 308, 408, 508) having a first inlet, a first outlet and a plurality of tubes each having a first end in fluid communication with the first inlet and a second end in fluid communication with the first outlet. The plurality of tubes contain a first catalyst for the production of formaldehyde by oxidative dehydrogenation. The apparatus is characterised in that the apparatus further comprises a pre-reactor section (7, 107, 207, 307, 407, 507). The pre-reactor section (7, 107, 207, 307, 407, 507) has an inlet. The pre-reactor section (7, 107, 207, 307, 407, 507) has an outlet in fluid communication with the first inlet of the cooled tubular reactor section (8, 108, 208, 308, 408, 508). The pre-reactor section (7, 107, 207, 307, 407, 507) is configured to contain, in use, an adiabatic catalyst bed. The adiabatic catalyst bed comprises a second catalyst for the production of formaldehyde by catalytic oxidative dehydrogenation.