Patent classifications
C07C51/54
METHOD AND APPARATUS FOR PRODUCING A CHEMICAL COMPOUND AND THE PRODUCED CHEMICAL COMPOUND
A method and an apparatus for producing a chemical compound from biomass based raw material. The bio-mass based raw material is gasified in a gasification device for forming a gasification gas, the gasification gas is treated in the reactor which includes at least one catalyst layer including Fe-based catalyst for forming a hydrocarbon composition, at least one hydrocarbon fraction including olefins is recovered from the hydrocarbon composition, and a chemical compound is formed from the hydrocarbon fraction. Further, the invention relates to the produced chemical compound.
METHOD AND APPARATUS FOR PRODUCING A CHEMICAL COMPOUND AND THE PRODUCED CHEMICAL COMPOUND
A method and an apparatus for producing a chemical compound from biomass based raw material. The bio-mass based raw material is gasified in a gasification device for forming a gasification gas, the gasification gas is treated in the reactor which includes at least one catalyst layer including Fe-based catalyst for forming a hydrocarbon composition, at least one hydrocarbon fraction including olefins is recovered from the hydrocarbon composition, and a chemical compound is formed from the hydrocarbon fraction. Further, the invention relates to the produced chemical compound.
METHOD AND APPARATUS FOR PRODUCING A CHEMICAL COMPOUND AND THE PRODUCED CHEMICAL COMPOUND
A method and an apparatus for producing a chemical compound from biomass based raw material. The bio-mass based raw material is gasified in a gasification device for forming a gasification gas, the gasification gas is treated in the reactor which includes at least one catalyst layer including Fe-based catalyst for forming a hydrocarbon composition, at least one hydrocarbon fraction including olefins is recovered from the hydrocarbon composition, and a chemical compound is formed from the hydrocarbon fraction. Further, the invention relates to the produced chemical compound.
Method for producing carboxylic acid anhydride and method for producing carboxylic acid ester
Provided is a production method whereby corresponding carboxylic acid anhydrides and carboxylic acid esters can be obtained at high yield from various carboxylic acids even without a solvent and near room temperature. A method for producing a carboxylic acid anhydride represented by formula (II), the method comprising reacting a compound represented by formula (I) and a carboxylic acid in the presence of a Group II metal compound having an ionic ligand containing an oxygen atom. A method for producing a carboxylic acid ester, the method comprising reacting a carboxylic acid anhydride produced by the aforementioned method and an alcohol. In formula (I), R.sup.1 represents a C.sub.1-20 hydrocarbon group. In formula (II), R.sup.2 represents a C.sub.1-20 hydrocarbon group.
Method for producing carboxylic acid anhydride and method for producing carboxylic acid ester
Provided is a production method whereby corresponding carboxylic acid anhydrides and carboxylic acid esters can be obtained at high yield from various carboxylic acids even without a solvent and near room temperature. A method for producing a carboxylic acid anhydride represented by formula (II), the method comprising reacting a compound represented by formula (I) and a carboxylic acid in the presence of a Group II metal compound having an ionic ligand containing an oxygen atom. A method for producing a carboxylic acid ester, the method comprising reacting a carboxylic acid anhydride produced by the aforementioned method and an alcohol. In formula (I), R.sup.1 represents a C.sub.1-20 hydrocarbon group. In formula (II), R.sup.2 represents a C.sub.1-20 hydrocarbon group.
Process for the functionalization of heteroalkanes and arenes
Provided are methods and materials for the functionalization of a heteroalkane or arene using an oxidizing electrophile as a stoichiometric agent or catalyst. The reaction involves the replacement of a hydrogen atom on an sp3-hybridized carbon atom of the heteroalkane or of a hydrogen atom on an sp2-hybridized carbon atom of the arene. A main group element organometallic intermediate is formed that undergoes further conversion to a functionalized heteroalkane or arene.
Process for the functionalization of heteroalkanes and arenes
Provided are methods and materials for the functionalization of a heteroalkane or arene using an oxidizing electrophile as a stoichiometric agent or catalyst. The reaction involves the replacement of a hydrogen atom on an sp3-hybridized carbon atom of the heteroalkane or of a hydrogen atom on an sp2-hybridized carbon atom of the arene. A main group element organometallic intermediate is formed that undergoes further conversion to a functionalized heteroalkane or arene.
METHOD AND APPARATUS FOR PRODUCING A CHEMICAL COMPOUND AND THE PRODUCED CHEMICAL COMPOUND
A method and an apparatus for producing a chemical compound from biomass based raw material. The bio-mass based raw material is gasified in a gasification device for forming a gasification gas, the gasification gas is treated in the reactor which includes at least one catalyst layer including Fe-based catalyst for forming a hydrocarbon composition, at least one hydrocarbon fraction including olefins is recovered from the hydrocarbon composition, and a chemical compound is formed from the hydrocarbon fraction. Further, the invention relates to the produced chemical compound.
METHOD AND APPARATUS FOR PRODUCING A CHEMICAL COMPOUND AND THE PRODUCED CHEMICAL COMPOUND
A method and an apparatus for producing a chemical compound from biomass based raw material. The bio-mass based raw material is gasified in a gasification device for forming a gasification gas, the gasification gas is treated in the reactor which includes at least one catalyst layer including Fe-based catalyst for forming a hydrocarbon composition, at least one hydrocarbon fraction including olefins is recovered from the hydrocarbon composition, and a chemical compound is formed from the hydrocarbon fraction. Further, the invention relates to the produced chemical compound.
Method for separating high-boiling carboxylic acid vinyl ester/carboxylic acid mixtures
The invention relates to a method for separating a mixture containing at least one carboxylic acid vinyl ester of general formula RC(O)OCHCH.sub.2 and at least one carboxylic acid of general formula RCOOH, wherein R in either case can be an aliphatic group having 12 to 22 C atoms or a cycloaliphatic group having 12 to 22 C atoms, or an aromatic group having 12 to 22 C atoms, and R can be identical or different, characterized in that the carboxylic acid is converted to its anhydride RC(O)OC(O)R and the carboxylic acid vinyl ester is subsequently separated.