The method according to this disclosure is a method for separating an unsaturated hydrocarbon having 2 or 3 carbon atoms and a halogenated unsaturated carbon compound formed by replacing at least one of hydrogen atoms included in the unsaturated hydrocarbon with a fluorine atom, from each other and is a method for selectively adsorbing either the unsaturated hydrocarbon or the halogenated unsaturated carbon compound by a porous coordination polymer that includes a metallic ion having a valence of 2 to 4 and an aromatic anion having 1 to 6 aromatic ring(s).

The present invention relates to the production of tri-functional aromatic molecules from diformylfuran, in particular to the production of tri-methyl benzene derivatives such as for example trimellitic acid or 1,2,4-tri(aminomethyl)benzene from diformylfuran and its derivatives.

The present invention relates to the production of tri-functional aromatic molecules from diformylfuran, in particular to the production of tri-methyl benzene derivatives such as for example trimellitic acid or 1,2,4-tri(aminomethyl)benzene from diformylfuran and its derivatives.

A supramolecular metal-organic framework material is a reaction product of a copper compound, a trialkylamine represented by Chemical Formula 1, and benzene substituted with 3 or more carboxyl groups.

A supramolecular metal-organic framework material is a reaction product of a copper compound, a trialkylamine represented by Chemical Formula 1, and benzene substituted with 3 or more carboxyl groups.

A supramolecular metal-organic framework material is a reaction product of a copper compound, a trialkylamine represented by Chemical Formula 1, and benzene substituted with 3 or more carboxyl groups.

The method according to this disclosure is a method for separating an unsaturated hydrocarbon having 2 or 3 carbon atoms and a halogenated unsaturated carbon compound formed by replacing at least one of hydrogen atoms included in the unsaturated hydrocarbon with a fluorine atom, from each other and is a method for selectively adsorbing either the unsaturated hydrocarbon or the halogenated unsaturated carbon compound by a porous coordination polymer that includes a metallic ion having a valence of 2 to 4 and an aromatic anion having 1 to 6 aromatic ring(s).

A method for preparing a two-dimensional sheet-shaped Cu-MOF material, includes mixing Cu-BTC with an alkaline solution at a certain solid-liquid ratio by stirring, reacting at a temperature of 25 to 120 C., filtering, washing with ionized water and drying under vacuum, to obtain a two-dimensional sheet-shaped Cu-MOF material, wherein the alkaline solution is at least one of urea, sodium carbonate, sodium bicarbonate, aqueous ammonia, sodium hydroxide or potassium hydroxide. The method has the characteristics of mild operation conditions, controllable transition process, high reaction yield and easy production at large scale, and exhibits excellent oxidation performance in styrene oxidation.

A method for preparing a two-dimensional sheet-shaped Cu-MOF material, includes mixing Cu-BTC with an alkaline solution at a certain solid-liquid ratio by stirring, reacting at a temperature of 25 to 120 C., filtering, washing with ionized water and drying under vacuum, to obtain a two-dimensional sheet-shaped Cu-MOF material, wherein the alkaline solution is at least one of urea, sodium carbonate, sodium bicarbonate, aqueous ammonia, sodium hydroxide or potassium hydroxide. The method has the characteristics of mild operation conditions, controllable transition process, high reaction yield and easy production at large scale, and exhibits excellent oxidation performance in styrene oxidation.

The subject invention concerns a method for identifying complementary chemical functionalities to form a desired supramolecular synthon. The subject invention also pertains to binary phase compositions comprising one or more pharmaceutical entities and methods for producing such compositions.