C07C67/03

CARBON CAPTURE IN FERMENTATION FOR COMMODITY CHEMICALS

The disclosure relates to methods of capturing carbon by microbial fermentation of a gaseous substrate comprising CO into one or more first products which, in turn, may be incorporated into an article of manufacture or one or more second products. Further, the disclosure relates to improving carbon capture and/or efficiency.

CARBON CAPTURE IN FERMENTATION FOR COMMODITY CHEMICALS

The disclosure relates to methods of capturing carbon by microbial fermentation of a gaseous substrate comprising CO into one or more first products which, in turn, may be incorporated into an article of manufacture or one or more second products. Further, the disclosure relates to improving carbon capture and/or efficiency.

RENEWABLE BASE OIL PRODUCTION ENGAGING METATHESIS
20220340835 · 2022-10-27 · ·

A process is disclosed for producing renewable products, such as a renewable base oil, from a feedstock of biological origin. The process includes subjecting a feedstock containing free fatty acids and fatty acid glycerides, wherein at least one hydrocarbon chain is unsaturated, to esterification reaction in the presence of an alcohol. An ester stream thereby obtained is then subjected to metathesis conditions in the presence of a renewable alkene to obtain a metathesis product. Separation of the metathesis product includes recovery of a fraction containing or consisting essentially of C16 fatty acid esters, which is subjected to ketonisation reaction conditions to produce long chain ketones, which after hydrotreatment meet requirements for a renewable base oil. Ketonisation reaction produces renewable alkene usable in metathesis reaction.

RENEWABLE BASE OIL PRODUCTION ENGAGING METATHESIS
20220340835 · 2022-10-27 · ·

A process is disclosed for producing renewable products, such as a renewable base oil, from a feedstock of biological origin. The process includes subjecting a feedstock containing free fatty acids and fatty acid glycerides, wherein at least one hydrocarbon chain is unsaturated, to esterification reaction in the presence of an alcohol. An ester stream thereby obtained is then subjected to metathesis conditions in the presence of a renewable alkene to obtain a metathesis product. Separation of the metathesis product includes recovery of a fraction containing or consisting essentially of C16 fatty acid esters, which is subjected to ketonisation reaction conditions to produce long chain ketones, which after hydrotreatment meet requirements for a renewable base oil. Ketonisation reaction produces renewable alkene usable in metathesis reaction.

RENEWABLE BASE OIL PRODUCTION ENGAGING METATHESIS
20220340835 · 2022-10-27 · ·

A process is disclosed for producing renewable products, such as a renewable base oil, from a feedstock of biological origin. The process includes subjecting a feedstock containing free fatty acids and fatty acid glycerides, wherein at least one hydrocarbon chain is unsaturated, to esterification reaction in the presence of an alcohol. An ester stream thereby obtained is then subjected to metathesis conditions in the presence of a renewable alkene to obtain a metathesis product. Separation of the metathesis product includes recovery of a fraction containing or consisting essentially of C16 fatty acid esters, which is subjected to ketonisation reaction conditions to produce long chain ketones, which after hydrotreatment meet requirements for a renewable base oil. Ketonisation reaction produces renewable alkene usable in metathesis reaction.

METHOD FOR IMPROVING THE HUE OF RECYCLED BIS(2-HYDROXYETHYL) TEREPHTHALATE

A method for improving the hue of recycled BHET is provided. The method includes: providing a recycled polyester fabric; using a chemical de-polymerization liquid to chemically depolymerize the recycled polyester fabric to form a de-polymerization product; distilling out the chemical de-polymerization liquid from the de-polymerization product by evaporation; dissolving the BHET in water to form a aqueous phase liquid; adding an activated carbon material to the aqueous phase liquid to adsorb impurities; and cooling the aqueous phase liquid to crystallize the BHET from the aqueous phase liquid to obtain a recycled BHET.

METHOD FOR IMPROVING THE HUE OF RECYCLED BIS(2-HYDROXYETHYL) TEREPHTHALATE

A method for improving the hue of recycled BHET is provided. The method includes: providing a recycled polyester fabric; using a chemical de-polymerization liquid to chemically depolymerize the recycled polyester fabric to form a de-polymerization product; distilling out the chemical de-polymerization liquid from the de-polymerization product by evaporation; dissolving the BHET in water to form a aqueous phase liquid; adding an activated carbon material to the aqueous phase liquid to adsorb impurities; and cooling the aqueous phase liquid to crystallize the BHET from the aqueous phase liquid to obtain a recycled BHET.

METHOD FOR IMPROVING RECOVERY RATE OF RECYCLED BIS(2-HYDROXYETHYL) TEREPHTHALATE

A method for improving a recovery rate of recycled bis(2-hydroxyethyl) terephthalate (BHET) is provided, which includes: providing a recycled polyester fabric; using a chemical de-polymerization liquid to chemically depolymerize the recycled polyester fabric, so as to form a de-polymerization product containing BHET; dissolving the BHET in water to form a aqueous phase liquid; cooling the aqueous phase liquid from a dissolution temperature to a first crystallization temperature, so as to crystallize at least a part of the BHET; and cooling the aqueous phase liquid from the first crystallization temperature to a second crystallization temperature, so as to crystallize at least another part of the BHET.

METHOD FOR IMPROVING RECOVERY RATE OF RECYCLED BIS(2-HYDROXYETHYL) TEREPHTHALATE

A method for improving a recovery rate of recycled bis(2-hydroxyethyl) terephthalate (BHET) is provided, which includes: providing a recycled polyester fabric; using a chemical de-polymerization liquid to chemically depolymerize the recycled polyester fabric, so as to form a de-polymerization product containing BHET; dissolving the BHET in water to form a aqueous phase liquid; cooling the aqueous phase liquid from a dissolution temperature to a first crystallization temperature, so as to crystallize at least a part of the BHET; and cooling the aqueous phase liquid from the first crystallization temperature to a second crystallization temperature, so as to crystallize at least another part of the BHET.

Highly unsaturated fatty acid or highly unsaturated fatty acid ethyl ester with reduced environmental pollutants, and method for producing same

A highly unsaturated fatty acid or a highly unsaturated fatty acid ethyl ester that has been produced using as a feedstock oil a fat or oil that contains highly unsaturated fatty acids as constituent fatty acids and which has been reduced in the contents of environmental pollutants, wherein among the dioxins contained, polychlorinated dibenzoparadioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) are contained in amounts of less than 0.05 pg-TEQ/g and coplanar PCBs (Co-PCBs) in amounts of less than 0.03 pg-TEQ/g. Also disclosed is a method for producing the highly unsaturated fatty acid or highly unsaturated fatty acid ethyl ester by the steps of removing free fatty acids and environmental pollutants by thin-film distillation from a feedstock oil, ethyl esterifying the resulting fat or oil, and refining the same by rectification and column chromatography.