In a method for producing an aliphatic carboxylic acid ester by reacting an aliphatic carboxylic acid having from 1 to 5 carbon atoms and an olefin having from 2 to 4 carbon atoms in a gas phase by use of a solid acid catalyst, a solid acid catalyst in which a heteropolyacid or a salt thereof is supported on a silica carrier obtainable by kneading fumed silica obtained by a combustion method, silica gel obtained by a gel method, and colloidal silica obtained by a sol-gel method or a water glass method, molding the resulting kneaded product, and calcining the resulting molded body, is used.

Disclosed are compositions containing at least one of the following: (1) estolide polyethylene glycol diesters; (2) hydroxy derived estolide polyethylene glycol diesters; (3) unsaturated hydroxy derived estolide polyethylene glycol diesters; (4) estolide trimetholpropane diesters; (5) hydroxy derived estolide trimetholpropane diesters; (6) unsaturated hydroxy derived estolide trimetholpropane diesters; (7) estolide epoxide polyethylene glycol diesters; (8) estolide dihydroxide polyethylene glycol diesters; (9) mono-capped hydroxy derived estolide epoxide polyethylene glycol diesters; (10) mono-capped hydroxy derived estolide dihydroxide polyethylene glycol diesters;
and mixtures thereof; and optionally a carrier. All the compounds can be used as a viscosity index improver thereby improving a lubricant's performance.

Disclosed are compositions containing at least one of the following: (1) estolide polyethylene glycol diesters; (2) hydroxy derived estolide polyethylene glycol diesters; (3) unsaturated hydroxy derived estolide polyethylene glycol diesters; (4) estolide trimetholpropane diesters; (5) hydroxy derived estolide trimetholpropane diesters; (6) unsaturated hydroxy derived estolide trimetholpropane diesters; (7) estolide epoxide polyethylene glycol diesters; (8) estolide dihydroxide polyethylene glycol diesters; (9) mono-capped hydroxy derived estolide epoxide polyethylene glycol diesters; (10) mono-capped hydroxy derived estolide dihydroxide polyethylene glycol diesters;
and mixtures thereof; and optionally a carrier. All the compounds can be used as a viscosity index improver thereby improving a lubricant's performance.

A method for preparing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as catalyst, wherein e) boron trifluoride is initially charged in (meth)acrylic acid, f) the initial charge is heated to a temperature of 75 to 110 C., g) norbornene is added and h) the norbornyl (meth)acrylate obtained is isolated from the reaction mixture.

A method for preparing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as catalyst, wherein e) boron trifluoride is initially charged in an organic solvent, f) the initial charge is heated to a temperature of 75 to 110 C., g) a mixture comprising norbornene and (meth)acrylic acid is added and h) the norbornyl (meth)acrylate obtained is isolated from the reaction mixture.

A method for preparing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as catalyst, wherein e) boron trifluoride is initially charged in (meth)acrylic acid, f) the initial charge is heated to a temperature of 75 to 110 C., g) norbornene is added and h) the norbornyl (meth)acrylate obtained is isolated from the reaction mixture.

A method for preparing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as catalyst, wherein e) boron trifluoride is initially charged in an organic solvent, f) the initial charge is heated to a temperature of 75 to 110 C., g) a mixture comprising norbornene and (meth)acrylic acid is added and h) the norbornyl (meth)acrylate obtained is isolated from the reaction mixture.

A method for synthesizing halogenated organic compounds, such as halogenated alkenyl group-containing and halogenated alkyl group-containing compounds having a heteroatom (e.g., O,N.S) coupled to a carbon atom of a halogenated alkenyl or halogenated alkyl group, involves reacting a halogenated olefin such as a chloro-substituted trifluoropropenyl compound with an active hydrogen-containing organic compound such as an alcohol (e.g., an aliphatic monoalcohol, aliphatic polyalcohol, or a phenolic compound), a primary amine, a secondary amine or a thiol.

A method for synthesizing halogenated organic compounds, such as halogenated alkenyl group-containing and halogenated alkyl group-containing compounds having a heteroatom (e.g., O,N.S) coupled to a carbon atom of a halogenated alkenyl or halogenated alkyl group, involves reacting a halogenated olefin such as a chloro-substituted trifluoropropenyl compound with an active hydrogen-containing organic compound such as an alcohol (e.g., an aliphatic monoalcohol, aliphatic polyalcohol, or a phenolic compound), a primary amine, a secondary amine or a thiol.

A method for synthesizing halogenated organic compounds, such as halogenated alkenyl group-containing and halogenated alkyl group-containing compounds having a heteroatom (e.g., O,N.S) coupled to a carbon atom of a halogenated alkenyl or halogenated alkyl group, involves reacting a halogenated olefin such as a chloro-substituted trifluoropropenyl compound with an active hydrogen-containing organic compound such as an alcohol (e.g., an aliphatic monoalcohol, aliphatic polyalcohol, or a phenolic compound), a primary amine, a secondary amine or a thiol.

In a method for producing an aliphatic carboxylic acid ester by reacting an aliphatic carboxylic acid having from 1 to 5 carbon atoms and an olefin having from 2 to 4 carbon atoms in a gas phase by use of a solid acid catalyst, a solid acid catalyst in which a heteropolyacid or a salt thereof is supported on a silica carrier obtainable by kneading fumed silica obtained by a combustion method, silica gel obtained by a gel method, and colloidal silica obtained by a sol-gel method or a water glass method, molding the resulting kneaded product, and calcining the resulting molded body, is used.

In a method for producing an aliphatic carboxylic acid ester by reacting an aliphatic carboxylic acid having from 1 to 5 carbon atoms and an olefin having from 2 to 4 carbon atoms in a gas phase by use of a solid acid catalyst, a solid acid catalyst in which a heteropolyacid or a salt thereof is supported on a silica carrier obtainable by kneading fumed silica obtained by a combustion method, silica gel obtained by a gel method, and colloidal silica obtained by a sol-gel method or a water glass method, molding the resulting kneaded product, and calcining the resulting molded body, is used.