C07C67/12

Polymeric materials having phthalate plasticizers covalently bonded to a polymer chain

In an example, a process of forming a polymeric material is disclosed. The process may include chemically reacting a polyvinyl chloride (PVC) material with a diamine to form a diamine-modified PVC material. The diamine has a chemical formula (CH.sub.2).sub.x(NH.sub.2).sub.2, where x is not less than 2. The process may also include chemically reacting a halogenated phthalate plasticizer with the diamine-modified PVC material to form a polymeric material having a phthalate plasticizer covalently bonded to a polymer chain.

PROCESS FOR THE MANUFACTURE OF TERPHENYL COMPOUNDS

A process for the manufacture of a terphenyl compound [compound (T), herein after] of formula (T): wherein each of R and R, equal to or different from each other, are selected from the group consisting of halogen, alkyl, aryl, ether, thioether, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; each of j and k, equal to or different from each other, are zero or are an integer from 1 to 4, including the steps of (i) reacting at least one organozinc compound of formula (I) with at least one dihalocompound of formula (II) in the presence of a catalyst compound; wherein Y is selected from the group consisting of a chloride, a bromide, an iodide, an alkanesulfonate or a fluoroalkanesulfonate anion, R2 is selected from selected from the group consisting of C.sub.1-C.sub.10-alkyl, C.sub.3-C.sub.10-cycloalkyl, C.sub.1-C.sub.10-halooalkyl and C.sub.3-C.sub.10 halocyclo alkyl, each of Z, equal to or different from each other, are selected from the group consisting of a chloride, a bromide, an iodide, an alkanesulfonate or a fluoroalkanesulfonate anion; (ii) a Bayer-Villiger oxidation and (iii) hydrolysis or alcoholysis.

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PROCESS FOR THE MANUFACTURE OF TERPHENYL COMPOUNDS

A process for the manufacture of a terphenyl compound [compound (T), herein after] of formula (T): wherein each of R and R, equal to or different from each other, are selected from the group consisting of halogen, alkyl, aryl, ether, thioether, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; each of j and k, equal to or different from each other, are zero or are an integer from 1 to 4, including the steps of (i) reacting at least one organozinc compound of formula (I) with at least one dihalocompound of formula (II) in the presence of a catalyst compound; wherein Y is selected from the group consisting of a chloride, a bromide, an iodide, an alkanesulfonate or a fluoroalkanesulfonate anion, R2 is selected from selected from the group consisting of C.sub.1-C.sub.10-alkyl, C.sub.3-C.sub.10-cycloalkyl, C.sub.1-C.sub.10-halooalkyl and C.sub.3-C.sub.10 halocyclo alkyl, each of Z, equal to or different from each other, are selected from the group consisting of a chloride, a bromide, an iodide, an alkanesulfonate or a fluoroalkanesulfonate anion; (ii) a Bayer-Villiger oxidation and (iii) hydrolysis or alcoholysis.

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Method for producing fatty alcohol esters of hydroxycarboxylic acids

The invention relates to a method for producing fatty alcohol esters of 3-hydroxybutyric acid and their acylated derivatives, as well as the products thus obtained and their use.

Method for producing fatty alcohol esters of hydroxycarboxylic acids

The invention relates to a method for producing fatty alcohol esters of 3-hydroxybutyric acid and their acylated derivatives, as well as the products thus obtained and their use.