Patent classifications
C07C68/02
CONTINUOUS METHOD FOR PREPARING CARBONATE ESTERS
In one embodiment, a continuous process for preparing organic carbonate solvent of Formula (I) as described herein comprises contacting a first reactant (an alcohol) with a reactive carbonyl source (carbonyldiimidazole (CDI) or an alkylchloroformate) in the presence of a catalyst in reaction stream flowing through a continuous flow reactor at temperature 20° C. to about 160° C. and at a flow rate providing a residence time in the range of about 0.1 minute to about 24 hours; collecting a reactor effluent exiting from the continuous flow reactor; recovering a crude product from the reactor effluent; and distilling the crude product to obtain the organic carbonate compound of Formula (I). In another embodiment, the first reactant is an epoxide and the carbonyl source is carbon dioxide.
CONTINUOUS METHOD FOR PREPARING CARBONATE ESTERS
In one embodiment, a continuous process for preparing organic carbonate solvent of Formula (I) as described herein comprises contacting a first reactant (an alcohol) with a reactive carbonyl source (carbonyldiimidazole (CDI) or an alkylchloroformate) in the presence of a catalyst in reaction stream flowing through a continuous flow reactor at temperature 20° C. to about 160° C. and at a flow rate providing a residence time in the range of about 0.1 minute to about 24 hours; collecting a reactor effluent exiting from the continuous flow reactor; recovering a crude product from the reactor effluent; and distilling the crude product to obtain the organic carbonate compound of Formula (I). In another embodiment, the first reactant is an epoxide and the carbonyl source is carbon dioxide.
PROCESS FOR THE WORK-UP AND REUSE OF SALT-CONTAINING PROCESS WATER
A process for the work-up of salt-containing process water which contains an alkali metal chloride as salt in a concentration of at least 4% by weight and organic or inorganic and organic impurities from chemical production processes and reuse of the salt by a combination of prepurification and concentration, crystallization and purification of the salt and optionally subsequently use of the salt in an electrolysis for producing basic chemicals are described.
PROCESS FOR THE WORK-UP AND REUSE OF SALT-CONTAINING PROCESS WATER
A process for the work-up of salt-containing process water which contains an alkali metal chloride as salt in a concentration of at least 4% by weight and organic or inorganic and organic impurities from chemical production processes and reuse of the salt by a combination of prepurification and concentration, crystallization and purification of the salt and optionally subsequently use of the salt in an electrolysis for producing basic chemicals are described.
Method for producing fluorine-containing dialkyl carbonate compounds
The present invention relates to a method for producing fluorine-containing dialkyl carbonate compounds, which are suitable as non-aqueous solvents for non-aqueous electrolytes used in secondary batteries. When an alkyl chloroformate and an alcohol are reacted in the presence of an ether-containing imidazole derivative base, the reaction can be carried out at room temperature as compared with the prior art, and the products can be separated within a short time from the reactants. This is an economical process, and according to the present invention, it is possible to obtain alkyl carbonates containing fluorine atoms simply and without difficulty in the removal of solvents, salts formed during the reaction, and by-products.
Method for producing fluorine-containing dialkyl carbonate compounds
The present invention relates to a method for producing fluorine-containing dialkyl carbonate compounds, which are suitable as non-aqueous solvents for non-aqueous electrolytes used in secondary batteries. When an alkyl chloroformate and an alcohol are reacted in the presence of an ether-containing imidazole derivative base, the reaction can be carried out at room temperature as compared with the prior art, and the products can be separated within a short time from the reactants. This is an economical process, and according to the present invention, it is possible to obtain alkyl carbonates containing fluorine atoms simply and without difficulty in the removal of solvents, salts formed during the reaction, and by-products.
Method for producing fluorine-containing dialkyl carbonate compounds
The present invention relates to a method for producing fluorine-containing dialkyl carbonate compounds, which are suitable as non-aqueous solvents for non-aqueous electrolytes used in secondary batteries. When an alkyl chloroformate and an alcohol are reacted in the presence of an ether-containing imidazole derivative base, the reaction can be carried out at room temperature as compared with the prior art, and the products can be separated within a short time from the reactants. This is an economical process, and according to the present invention, it is possible to obtain alkyl carbonates containing fluorine atoms simply and without difficulty in the removal of solvents, salts formed during the reaction, and by-products.
Method for preparing dialkyl dicarbonates using amine oxides
The present invention relates to a method for preparing dialkyl dicarbonates from the corresponding alkyl chloroformates using specific amine oxides as catalysts.
Method for preparing dialkyl dicarbonates using amine oxides
The present invention relates to a method for preparing dialkyl dicarbonates from the corresponding alkyl chloroformates using specific amine oxides as catalysts.
Method for preparing dialkyl dicarbonates using amine oxides
The present invention relates to a method for preparing dialkyl dicarbonates from the corresponding alkyl chloroformates using specific amine oxides as catalysts.