A method for producing a 1-(acyloxy)alkyl carbamate derivative (III), using a fluorous alkyl carbonate derivative (I), and a fluorous alkyl carbonate derivative (I) and a method for producing the same. In the formula, R.sup.1 represents C.sub.1-C.sub.4 alkyl group or a C.sub.3-C.sub.6 cycloalkyl group, R.sup.2 represents a C.sub.1-C.sub.4 alkyl group or a hydrogen atom, and A represents a fluorous alkyl group (wherein the fluorous alkyl group represents a C.sub.2-C.sub.11 alkyl group in which 40% or more of the hydrogen atoms are replaced by fluorine atoms).

A method for producing a 1-(acyloxy)alkyl carbamate derivative (III), using a fluorous alkyl carbonate derivative (I), and a fluorous alkyl carbonate derivative (I) and a method for producing the same. In the formula, R.sup.1 represents C.sub.1-C.sub.4 alkyl group or a C.sub.3-C.sub.6 cycloalkyl group, R.sup.2 represents a C.sub.1-C.sub.4 alkyl group or a hydrogen atom, and A represents a fluorous alkyl group (wherein the fluorous alkyl group represents a C.sub.2-C.sub.11 alkyl group in which 40% or more of the hydrogen atoms are replaced by fluorine atoms).

A foaming agent comprising organic amine salt compounds of the following general formula A.sup.n [B.sup.m+].sub.p (I) is disclosed, wherein A.sup.n is a CO.sub.2-donating anion with a valence of n, wherein n=1, 2 or 3; each B.sup.m+ comprises: ammonium ion and/or organic amine (B) cation, wherein

[00001]$m=1.Math.\text{-10;}.Math..Math.0<p\frac{n}{m};$

and wherein A.sup.n is one or more selected from following anions: (a) carbamate; (b) carbonate; (c) formate; (d) bicarbonate radical; (e) organic mono carbonate; (f) organic radical multi-carbamate; (g) orthoformate; or (h) organic radical poly-carbonate. The compound of the general formula (I) has at least one of hydroxyalkyl group linked to N atom, i.e., has alkanolamine residue. They can be used as polyurethane foaming agent, polystyrene foaming agent or polyvinyl choride foaming agent.

The invention relates to a composition comprising a titanium or zirconium alkoxide or aryloxide, wherein the alkoxy group in the titanium or zirconium alkoxide is a group of formula RO.sup. wherein R is an alkyl group having 1 to 4 carbon atoms and the aryloxy group in the titanium or zirconium aryloxide is a group of formula ArO.sup. wherein Ar is an aryl group having 6 to 12 carbon atoms, and wherein the composition additionally comprises 0.1 to 50 wt. % of an organic carbonate, based on the total weight of the composition.

The invention relates to a composition comprising a titanium or zirconium alkoxide or aryloxide, wherein the alkoxy group in the titanium or zirconium alkoxide is a group of formula RO.sup. wherein R is an alkyl group having 1 to 4 carbon atoms and the aryloxy group in the titanium or zirconium aryloxide is a group of formula ArO.sup. wherein Ar is an aryl group having 6 to 12 carbon atoms, and wherein the composition additionally comprises 0.1 to 50 wt. % of an organic carbonate, based on the total weight of the composition.

The invention relates to a composition comprising a titanium or zirconium alkoxide or aryloxide, wherein the alkoxy group in the titanium or zirconium alkoxide is a group of formula RO.sup. wherein R is an alkyl group having 1 to 4 carbon atoms and the aryloxy group in the titanium or zirconium aryloxide is a group of formula ArO.sup. wherein Ar is an aryl group having 6 to 12 carbon atoms, and wherein the composition additionally comprises 0.1 to 50 wt. % of an organic carbonate, based on the total weight of the composition.

The present disclosure discloses an energy-saving method for preparing electronic-grade carbonate, including the following steps that: industrial-grade dimethyl carbonate and anhydrous ethanol enter a reaction process after being preheated by a preheater, and are subjected to an esterification reaction under the action of a catalyst to obtain a mixture containing dimethyl carbonate, ethyl methyl carbonate and diethyl carbonate, and an azeotrope of dimethyl carbonate and methanol; the above-mentioned mixture enters a recovery process of dimethyl carbonate to recover unreacted dimethyl carbonate; a mixture of ethyl methyl carbonate and diethyl carbonate then enters a crude separation process to obtain crude ethyl methyl carbonate and crude diethyl carbonate; and the crude ethyl methyl carbonate is subjected to a refining process of ethyl methyl carbonate to obtain electronic-grade ethyl methyl carbonate, and the crude diethyl carbonate is subjected to a refining process of diethyl carbonate to obtain electronic-grade diethyl carbonate.

The present disclosure discloses an energy-saving method for preparing electronic-grade carbonate, including the following steps that: industrial-grade dimethyl carbonate and anhydrous ethanol enter a reaction process after being preheated by a preheater, and are subjected to an esterification reaction under the action of a catalyst to obtain a mixture containing dimethyl carbonate, ethyl methyl carbonate and diethyl carbonate, and an azeotrope of dimethyl carbonate and methanol; the above-mentioned mixture enters a recovery process of dimethyl carbonate to recover unreacted dimethyl carbonate; a mixture of ethyl methyl carbonate and diethyl carbonate then enters a crude separation process to obtain crude ethyl methyl carbonate and crude diethyl carbonate; and the crude ethyl methyl carbonate is subjected to a refining process of ethyl methyl carbonate to obtain electronic-grade ethyl methyl carbonate, and the crude diethyl carbonate is subjected to a refining process of diethyl carbonate to obtain electronic-grade diethyl carbonate.

The present disclosure discloses an energy-saving method for preparing electronic-grade carbonate, including the following steps that: industrial-grade dimethyl carbonate and anhydrous ethanol enter a reaction process after being preheated by a preheater, and are subjected to an esterification reaction under the action of a catalyst to obtain a mixture containing dimethyl carbonate, ethyl methyl carbonate and diethyl carbonate, and an azeotrope of dimethyl carbonate and methanol; the above-mentioned mixture enters a recovery process of dimethyl carbonate to recover unreacted dimethyl carbonate; a mixture of ethyl methyl carbonate and diethyl carbonate then enters a crude separation process to obtain crude ethyl methyl carbonate and crude diethyl carbonate; and the crude ethyl methyl carbonate is subjected to a refining process of ethyl methyl carbonate to obtain electronic-grade ethyl methyl carbonate, and the crude diethyl carbonate is subjected to a refining process of diethyl carbonate to obtain electronic-grade diethyl carbonate.

A macromolecules containing metal and a use thereof as a catalyst, said macromolecules containing metal being obtained by causing a ligand to react with a zinc compound or a cobalt compound, said ligand having an imidazole group that is bonded to a macromolecule via a linker.