Patent classifications
C07C68/06
PROCESS FOR MAKING A CONJUGATED DIENE FROM AN ALLYL ALCOHOL
An in-situ method for making a conjugated diene from an allyl alcohol comprising the conversion of the allyl alcohol to an allyl carbonate, allyl ester or allyl formate with concomitant or subsequent conversion of the allyl carbonate, allyl ester or allyl formate to the conjugated diene; the products obtained by said method, and the uses of said products.
METHOD FOR PRODUCING ASYMMETRIC LINEAR CARBONATE
The present specification relates to a method for preparing an asymmetric linear carbonate.
METHOD FOR PRODUCING ASYMMETRIC LINEAR CARBONATE
The present specification relates to a method for preparing an asymmetric linear carbonate.
System and process for co-producing dimethyl carbonate and ethylene glycol
A system and a process for co-producing dimethyl carbonate and ethylene glycol. The system comprises an interconnected ethylene carbonate preparation unit and an ethylene carbonate alcoholysis unit. The ethylene carbonate preparation unit comprises a fixed bed reactor and a light-component stripping column connected to each other. The fixed bed reactor is filled with a supported ionic liquid catalyst. The process comprises the steps of: reacting carbon dioxide and ethylene oxide as raw materials in the fixed bed reactor to produce ethylene carbonate, purifying the ethylene carbonate and then mixing it with an alcoholysis reaction catalyst, and reacting the mixture with methanol in a reactive distillation tower, producing dimethyl carbonate and ethylene glycol. The process increases the conversion rate of ethylene oxide and avoids the need for a process of separating conventional homogeneous catalysts from ethylene carbonate, thereby reducing process energy consumption and simplifying process procedures.
Diaryl carbonate and method for producing the same, and method for producing an aromatic polycarbonate resin
Disclosed are a diaryl carbonate containing a compound of the following formula (I) in an amount of less than 1,000 ppm by mass, and a method for producing the same: ##STR00001## wherein R.sup.l represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an aryl group, or an aryloxy group. Disclosed methods include reacting urea with an alkyl alcohol to provide a dialkyl carbonate; reacting the dialkyl carbonate with an aryl alcohol to provide an alkylaryl carbonate; subjecting the alkylaryl carbonate to disproportionation to yield a mixture comprising a diaryl carbonate; and purifying the mixture.
Diaryl carbonate and method for producing the same, and method for producing an aromatic polycarbonate resin
Disclosed are a diaryl carbonate containing a compound of the following formula (I) in an amount of less than 1,000 ppm by mass, and a method for producing the same: ##STR00001## wherein R.sup.l represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an aryl group, or an aryloxy group. Disclosed methods include reacting urea with an alkyl alcohol to provide a dialkyl carbonate; reacting the dialkyl carbonate with an aryl alcohol to provide an alkylaryl carbonate; subjecting the alkylaryl carbonate to disproportionation to yield a mixture comprising a diaryl carbonate; and purifying the mixture.
SOLVENT COMPOUNDS FOR USE AS REPLACEMENTS FOR SLOW EVAPORATING SOLVENTS
The present disclosure provides, in part, a solvent compound for use as a slow evaporating replacement. More specifically, the present disclosure relates to VOC-exempt solvent compounds that may be used as a slow evaporating replacement.
SOLVENT COMPOUNDS FOR USE AS REPLACEMENTS FOR SLOW EVAPORATING SOLVENTS
The present disclosure provides, in part, a solvent compound for use as a slow evaporating replacement. More specifically, the present disclosure relates to VOC-exempt solvent compounds that may be used as a slow evaporating replacement.
METHOD OF PREPARING HETEROGENEOUS LINEAR CARBONATE USING AMINE-BASED COMPOUND CATALYST
The present invention is directed to providing a method of preparing a heterogeneous linear carbonate, including: performing a transesterification reaction of dimethyl carbonate (DMC) and ethanol (EtOH) in the presence of a catalyst, wherein the catalyst is an amine-based compound having a boiling point of 150 C. or more.
METHOD OF PREPARING HETEROGENEOUS LINEAR CARBONATE USING AMINE-BASED COMPOUND CATALYST
The present invention is directed to providing a method of preparing a heterogeneous linear carbonate, including: performing a transesterification reaction of dimethyl carbonate (DMC) and ethanol (EtOH) in the presence of a catalyst, wherein the catalyst is an amine-based compound having a boiling point of 150 C. or more.