The present invention relates to the field of fine chemical industry. Specifically disclosed are a method for synthesizing 2-methylpyridine from aniline, and a method for selectively and continuously producing 2-methylpyridine and diphenylamine from aniline. The method comprises: in a hydrogen-containing atmosphere, enabling aniline and a catalyst to undergo a contact reaction at a temperature of 100-400 C., wherein the catalyst is zeolite carrying a metal component, and the metal component comprises an active metal component selected from at least one of W, Mo, Ni, and Co; controlling the temperature of the contact reaction to be 100-240 C. to obtain a product mainly consisting of 2-methylpyridine; and controlling the temperature of the contact reaction to be 260-400 C. to obtain a product mainly consisting of diphenylamine.

Disclosed herein are embodiments of methods for preparing aminated or alkylaminated CNTs wherein the aminated or alkylaminated CNTs are obtained in a reaction by reacting the CNTs with an aminating or alkylaminating reagent in a non-hazardous solvent or a non-hazardous solvent-deionized water mixture. The CNTs may be single-walled, double-walled or multi-walled CNTs. The disclosed processes for amination and alkylamination do not require treatment with concentrated acid, and with the use of solvent, the CNTs and aminating compound or alkylaminating compound are mixed thoroughly throughout the reaction.

Disclosed herein are embodiments of methods for preparing aminated or alkylaminated CNTs wherein the aminated or alkylaminated CNTs are obtained in a reaction by reacting the CNTs with an aminating or alkylaminating reagent in a non-hazardous solvent or a non-hazardous solvent-deionized water mixture. The CNTs may be single-walled, double-walled or multi-walled CNTs. The disclosed processes for amination and alkylamination do not require treatment with concentrated acid, and with the use of solvent, the CNTs and aminating compound or alkylaminating compound are mixed thoroughly throughout the reaction.

The present invention provides a simple, efficient, and industrially advantageous method for the alkylation of amines. The present invention relates to a production method for N-alkylamines whereby an amine is reacted with an alcohol in the presence of a ruthenium complex represented by general formula (1): RuXY(CO)(L) (wherein X and Y can be the same or different and represent a monovalent anionic ligand, and L represents a tridentate aminodiphosphine ligand).

The present invention provides a simple, efficient, and industrially advantageous method for the alkylation of amines. The present invention relates to a production method for N-alkylamines whereby an amine is reacted with an alcohol in the presence of a ruthenium complex represented by general formula (1): RuXY(CO)(L) (wherein X and Y can be the same or different and represent a monovalent anionic ligand, and L represents a tridentate aminodiphosphine ligand).

The present invention provides a simple, efficient, and industrially advantageous method for the alkylation of amines. The present invention relates to a production method for N-alkylamines whereby an amine is reacted with an alcohol in the presence of a ruthenium complex represented by general formula (1): RuXY(CO)(L) (wherein X and Y can be the same or different and represent a monovalent anionic ligand, and L represents a tridentate aminodiphosphine ligand).

The present invention provides novel synthetic methods for making acyclic secondary amines by reacting an azide with a compound bearing one or more CH groups, catalyzed by a Fe.sup.II-dipyrromethene complex. The acyclic secondary amines are thought to be formed through an intermolecular nitrene transfer. Also provided herein are methods of synthesizing protected (e.g., Boc- or Fmoc-protected) cyclic secondary amines (e.g., 5-, 6-, and 7-membered cyclic secondary amines) by reacting an azide that bears one or more CH groups, catalyzed by a Fe.sup.II-dipyrromethene complex. The protected cyclic secondary amines are thought to be formed through an intramolecular nitrene transfer and may be subsequently deprotected to yield cyclic secondary amines.

The present invention provides novel synthetic methods for making acyclic secondary amines by reacting an azide with a compound bearing one or more CH groups, catalyzed by a Fe.sup.II-dipyrromethene complex. The acyclic secondary amines are thought to be formed through an intermolecular nitrene transfer. Also provided herein are methods of synthesizing protected (e.g., Boc- or Fmoc-protected) cyclic secondary amines (e.g., 5-, 6-, and 7-membered cyclic secondary amines) by reacting an azide that bears one or more CH groups, catalyzed by a Fe.sup.II-dipyrromethene complex. The protected cyclic secondary amines are thought to be formed through an intramolecular nitrene transfer and may be subsequently deprotected to yield cyclic secondary amines.

The present invention provides novel synthetic methods for making acyclic secondary amines by reacting an azide with a compound bearing one or more CH groups, catalyzed by a Fe.sup.II-dipyrromethene complex. The acyclic secondary amines are thought to be formed through an intermolecular nitrene transfer. Also provided herein are methods of synthesizing protected (e.g., Boc- or Fmoc-protected) cyclic secondary amines (e.g., 5-, 6-, and 7-membered cyclic secondary amines) by reacting an azide that bears one or more CH groups, catalyzed by a Fe.sup.II-dipyrromethene complex. The protected cyclic secondary amines are thought to be formed through an intramolecular nitrene transfer and may be subsequently deprotected to yield cyclic secondary amines.

A process for preparing 4-aminodiphenylamine (4-ADPA) comprising steps of coupling of aniline with nitrobenzene in presence of a suitable base, e.g. tetramethylammonium hydroxide (TMAH), hydrogenation of the coupling mass, phase separation, hydrogenation of azobenzene in the separated organic mass and fractional distillation for 4-ADPA recovery. An improvement in 4-ADPA recovery and a lowering of tar formation are obtained due to azobenzene reduction prior to 4-ADPA isolation. Also a gain in volume productivity of 4-ADPA is obtained by suitably altering the batch cycle time of the coupling reaction.