Patent classifications
C07C209/54
Process for producing isocyanate and at least one further chemical product in an integrated production
The present invention relates to a process for producing isocyanates in process chains, each of which produce an isocyanate end product via at least one intermediate product, wherein the heat energy liberated in a first production plant in a heat-emitting operation of producing an intermediate product, an isocyanate end product or a catalyst required for a substep of the process chain (first chemical product) is at least partly utilized for generating vapour, in particular water vapour, having a pressure of 1.31 bar.sub.(abs.) to 1.91 bar.sub.(abs.) and a temperature of 107 C. to 119 C. and the thus generated vapour is employed for performing a heat-consuming operation in the preparation of another chemical product (second chemical product) in a second production plant.
METHOD OF PRODUCING DIAMINES AND POLYAMINES OF THE DIPHENYLMETHANE SERIES
The invention relates to a method for producing diamines and polyamines of the diphenylmethane series, by condensing aniline and formaldehyde followed by an acid-catalysed rearrangement at different production capacities with alteration of the isomer composition in the resulting diamines of the diphenylmethane series (altering the 2,4-MDA content). Adapting the molar ratios of the total used aniline to the total used formaldehyde and of the total used acid catalyst to the total used aniline, and adapting the reaction temperature, allows the rearrangement reaction to be fully completed despite the change in dwell time inevitably associated with a change in production capacity, and allows the formation of undesired by-products to be avoided as far as possible; the intended modification to binuclear content is likewise achieved.
METHOD OF PRODUCING DIAMINES AND POLYAMINES OF THE DIPHENYLMETHANE SERIES
The invention relates to a method for producing diamines and polyamines of the diphenylmethane series, by condensing aniline and formaldehyde followed by an acid-catalysed rearrangement at different production capacities with alteration of the isomer composition in the resulting diamines of the diphenylmethane series (altering the 2,4-MDA content). Adapting the molar ratios of the total used aniline to the total used formaldehyde and of the total used acid catalyst to the total used aniline, and adapting the reaction temperature, allows the rearrangement reaction to be fully completed despite the change in dwell time inevitably associated with a change in production capacity, and allows the formation of undesired by-products to be avoided as far as possible; the intended modification to binuclear content is likewise achieved.
METHOD OF PRODUCING DIAMINES AND POLYAMINES OF THE DIPHENYLMETHANE SERIES
The invention relates to a method for producing diamines and polyamines of the diphenylmethane series, by condensing aniline and formaldehyde followed by an acid-catalysed rearrangement at different production capacities with alteration of the isomer composition in the resulting diamines of the diphenylmethane series (altering the 2,4-MDA content). Adapting the molar ratios of the total used aniline to the total used formaldehyde and of the total used acid catalyst to the total used aniline, and adapting the reaction temperature, allows the rearrangement reaction to be fully completed despite the change in dwell time inevitably associated with a change in production capacity, and allows the formation of undesired by-products to be avoided as far as possible; the intended modification to binuclear content is likewise achieved.
METHOD OF PRODUCING DIAMINES AND POLYAMINES OF THE DIPHENYLMETHANE SERIES AT DIFFERENT PRODUCTION CAPACITIES
The invention relates to a method for producing diamines and polyamines of the diphenylmethane series, by condensing aniline and formaldehyde followed by an acid-catalysed rearrangement at different production capacities. By adapting the temperatures in the acid-catalysed rearrangement step, the rearrangement reaction can be fully completed despite the change in dwell time inevitably associated with changed production capacity, with no undesired changes occurring in the product composition.
METHOD OF PRODUCING DIAMINES AND POLYAMINES OF THE DIPHENYLMETHANE SERIES AT DIFFERENT PRODUCTION CAPACITIES
The invention relates to a method for producing diamines and polyamines of the diphenylmethane series, by condensing aniline and formaldehyde followed by an acid-catalysed rearrangement at different production capacities. By adapting the temperatures in the acid-catalysed rearrangement step, the rearrangement reaction can be fully completed despite the change in dwell time inevitably associated with changed production capacity, with no undesired changes occurring in the product composition.
METHOD OF PRODUCING DIAMINES AND POLYAMINES OF THE DIPHENYLMETHANE SERIES AT DIFFERENT PRODUCTION CAPACITIES
The invention relates to a method for producing diamines and polyamines of the diphenylmethane series, by condensing aniline and formaldehyde followed by an acid-catalysed rearrangement at different production capacities. By adapting the temperatures in the acid-catalysed rearrangement step, the rearrangement reaction can be fully completed despite the change in dwell time inevitably associated with changed production capacity, with no undesired changes occurring in the product composition.
Process for the production of di- and polyamines of the diphenylmethane series
The invention relates to a production process for di- and polyamines of the diphenylmethane series by the rearrangement of a condensation product of aniline and a methylene group-supplying agent preferably selected from the group consisting of aqueous formaldehyde solution, gaseous formaldehyde, para-formaldehyde, trioxane and mixtures thereof, wherein said condensation product is reacted in the presence of at least one silica-alumina catalyst, said catalyst having a surface area as determined by the BET method carried out according to ASTM D3663-03 (2015) of from 200 m.sup.2/g to 520 m.sup.2/g, preferably of from 350 m.sup.2/g to 495 m.sup.2/g, particularly preferably of from 400 m.sup.2/g to 490 m.sup.2/g, a molar ratio of silica/alumina on the catalyst surface of A, an overall (bulk) molar ratio of silica/alumina of C, and a quotient B=A/C;
said catalyst being characterised in that low A values (i.e. equal to or lower than 8.0) are combined with high B values (i.e. of from 1.50 to 3.00), and high A values (i.e. larger than 8.00, especially equal to or larger than 8.50) are combined with low B values (i.e. of from 0.15 to 1.40).
Process for the production of di- and polyamines of the diphenylmethane series
The invention relates to a production process for di- and polyamines of the diphenylmethane series by the rearrangement of a condensation product of aniline and a methylene group-supplying agent preferably selected from the group consisting of aqueous formaldehyde solution, gaseous formaldehyde, para-formaldehyde, trioxane and mixtures thereof, wherein said condensation product is reacted in the presence of at least one silica-alumina catalyst, said catalyst having a surface area as determined by the BET method carried out according to ASTM D3663-03 (2015) of from 200 m.sup.2/g to 520 m.sup.2/g, preferably of from 350 m.sup.2/g to 495 m.sup.2/g, particularly preferably of from 400 m.sup.2/g to 490 m.sup.2/g, a molar ratio of silica/alumina on the catalyst surface of A, an overall (bulk) molar ratio of silica/alumina of C, and a quotient B=A/C;
said catalyst being characterised in that low A values (i.e. equal to or lower than 8.0) are combined with high B values (i.e. of from 1.50 to 3.00), and high A values (i.e. larger than 8.00, especially equal to or larger than 8.50) are combined with low B values (i.e. of from 0.15 to 1.40).
PROCESS FOR PRODUCING ISOCYANATE AND AT LEAST ONE FURTHER CHEMICAL PRODUCT IN AN INTEGRATED PRODUCTION
The present invention relates to a process for producing isocyanates in process chains, each of which produce an isocyanate end product via at least one intermediate product, wherein the heat energy liberated in a first production plant in a heat-emitting operation of producing an intermediate product, an isocyanate end product or a catalyst required for a substep of the process chain (first chemical product) is at least partly utilized for generating vapour, in particular water vapour, having a pressure of 1.31 bar.sub.(abs.) to 1.91 bar.sub.(abs.) and a temperature of 107 C. to 119 C. and the thus generated vapour is employed for performing a heat-consuming operation in the preparation of another chemical product (second chemical product) in a second production plant.