C07C231/06

Halogenated conjugated diene compound, and preparation and application thereof

Disclosed are a type of halogenated conjugated diene compounds (1), and preparation and application thereof. In this method, a conjugated diene compounds is subjected to halogenation reaction to prepare the compound (1). This disclosure further provides a method of preparing a 2-arylmalonic acid derivative from the compound (1) through dehydrohalogenation and aromatization reaction. ##STR00001##

Halogenated conjugated diene compound, and preparation and application thereof

Disclosed are a type of halogenated conjugated diene compounds (1), and preparation and application thereof. In this method, a conjugated diene compounds is subjected to halogenation reaction to prepare the compound (1). This disclosure further provides a method of preparing a 2-arylmalonic acid derivative from the compound (1) through dehydrohalogenation and aromatization reaction. ##STR00001##

ACRYLAMIDE PRODUCTION SYSTEM

The present disclosure provides an acrylamide production system. The acrylamide production system includes a storage device, a reaction kettle, a filter device, an impurity removal device, and a collection device. The storage device is used for storing microbes required for a reaction. A discharge end of the storage device is connected to a feed end of the reaction kettle through a pipeline. A discharge end of the reaction kettle is connected to a feed end of the filter device through a pipeline. A filtrate discharge end of the filter device is connected to a feed end of the impurity removal device through a pipeline. A discharge end of the impurity removal device is connected to the collection device through a pipeline. According to the acrylamide production system of the present disclosure, the whole process for producing an acrylamide aqueous solution is simple, which facilitates producing a high-purity acrylamide solution.

ACRYLAMIDE PRODUCTION SYSTEM

The present disclosure provides an acrylamide production system. The acrylamide production system includes a storage device, a reaction kettle, a filter device, an impurity removal device, and a collection device. The storage device is used for storing microbes required for a reaction. A discharge end of the storage device is connected to a feed end of the reaction kettle through a pipeline. A discharge end of the reaction kettle is connected to a feed end of the filter device through a pipeline. A filtrate discharge end of the filter device is connected to a feed end of the impurity removal device through a pipeline. A discharge end of the impurity removal device is connected to the collection device through a pipeline. According to the acrylamide production system of the present disclosure, the whole process for producing an acrylamide aqueous solution is simple, which facilitates producing a high-purity acrylamide solution.

CONJUGATED TRIENE COMPOUND, AND PREPARATION AND APPLICATION THEREOF
20220024861 · 2022-01-27 ·

Disclosed are a type of conjugated triene compounds (1), and a preparation and application thereof. In this method, a 2-(cyclohexenylidene)malonic acid derivative is sequentially subjected to isomerization, halogenation reaction in the presence of a halogenating agent and dehydrohalogenation to prepare the conjugated triene compounds (1). This disclosure further provides a method of preparing a 2-aryl malonic acid derivative from the conjugated triene compounds (1) through aromatization reaction.

##STR00001##

CONJUGATED TRIENE COMPOUND, AND PREPARATION AND APPLICATION THEREOF
20220024861 · 2022-01-27 ·

Disclosed are a type of conjugated triene compounds (1), and a preparation and application thereof. In this method, a 2-(cyclohexenylidene)malonic acid derivative is sequentially subjected to isomerization, halogenation reaction in the presence of a halogenating agent and dehydrohalogenation to prepare the conjugated triene compounds (1). This disclosure further provides a method of preparing a 2-aryl malonic acid derivative from the conjugated triene compounds (1) through aromatization reaction.

##STR00001##

CONJUGATED TRIENE COMPOUND, AND PREPARATION AND APPLICATION THEREOF
20220024861 · 2022-01-27 ·

Disclosed are a type of conjugated triene compounds (1), and a preparation and application thereof. In this method, a 2-(cyclohexenylidene)malonic acid derivative is sequentially subjected to isomerization, halogenation reaction in the presence of a halogenating agent and dehydrohalogenation to prepare the conjugated triene compounds (1). This disclosure further provides a method of preparing a 2-aryl malonic acid derivative from the conjugated triene compounds (1) through aromatization reaction.

##STR00001##

HALOGENATED CONJUGATED DIENE COMPOUND, AND PREPARATION AND APPLICATION THEREOF
20220017437 · 2022-01-20 ·

Disclosed are a type of halogenated conjugated diene compounds (1), and preparation and application thereof. In this method, a conjugated diene compounds is subjected to halogenation reaction to prepare the compound (1). This disclosure further provides a method of preparing a 2-arylmalonic acid derivative from the compound (1) through dehydrohalogenation and aromatization reaction.

##STR00001##

HALOGENATED CONJUGATED DIENE COMPOUND, AND PREPARATION AND APPLICATION THEREOF
20220017437 · 2022-01-20 ·

Disclosed are a type of halogenated conjugated diene compounds (1), and preparation and application thereof. In this method, a conjugated diene compounds is subjected to halogenation reaction to prepare the compound (1). This disclosure further provides a method of preparing a 2-arylmalonic acid derivative from the compound (1) through dehydrohalogenation and aromatization reaction.

##STR00001##

Method of producing methyl methacrylate or methacrylic acid
11174215 · 2021-11-16 · ·

There is described a method of reducing polymer tar build-up in the production of methyl methacrylate and/or methacrylic acid by the acetone cyanohydrin process. In the method a stabiliser is contacted with the amide stage reaction medium. The stabiliser includes a hydrocarbon moiety capable of donating a labile hydrogen atom to a methacrylamide derivative capable of reaction with said labile hydrogen atom under the conditions in the said medium. The method herein is especially useful for the continuous production of methyl methacrylate and/or methacrylic acid.