This document presents algae-derived antimicrobial fiber substrates, and a method of making the same. The fiber may be a synthetic fiber, but can also be formed as a cellulosic (e.g., cotton). In various implementations, an algae-derived antimicrobial fiber substrate can be made to have identical properties and characteristics of nylon-6 of nylon 6-6 polymer or the like, and yet contain antimicrobial, anti-viral, and/or flame retardant algal derived substances. Any of various species of red algae, brown algae, blue-green algae, and brown seaweed (marine microalgae and/or macroalgae) are known to contain a high level of sulfated polysaccharides with inherent antimicrobial, antiviral, and flame-retardant properties, and can be used as described herein. Additionally disclosed are algae-derived flexible foams, whether open-cell or closed-cell, with inherent antimicrobial, antiviral, and flame resistant properties. Further, a process of manufacturing is presented wherein the process may include one or more of the steps of: harvesting algae-biomass; sufficiently drying the algae biomass; blending the dried algae biomass with a carrier resin and various foaming ingredients; adding an algal-derived antimicrobial compound selected from various natural sulfated polysaccharides present in brown algae, red algae, and/or certain seaweeds (marine microalgae); and adding a sufficient quantity of dried algae biomass to the formulation to adequately create a fire resistant flexible foam material.

This document presents algae-derived antimicrobial fiber substrates, and a method of making the same. The fiber may be a synthetic fiber, but can also be formed as a cellulosic (e.g., cotton). In various implementations, an algae-derived antimicrobial fiber substrate can be made to have identical properties and characteristics of nylon-6 of nylon 6-6 polymer or the like, and yet contain antimicrobial, anti-viral, and/or flame retardant algal derived substances. Any of various species of red algae, brown algae, blue-green algae, and brown seaweed (marine microalgae and/or macroalgae) are known to contain a high level of sulfated polysaccharides with inherent antimicrobial, antiviral, and flame-retardant properties, and can be used as described herein. Additionally disclosed are algae-derived flexible foams, whether open-cell or closed-cell, with inherent antimicrobial, antiviral, and flame resistant properties. Further, a process of manufacturing is presented wherein the process may include one or more of the steps of: harvesting algae-biomass; sufficiently drying the algae biomass; blending the dried algae biomass with a carrier resin and various foaming ingredients; adding an algal-derived antimicrobial compound selected from various natural sulfated polysaccharides present in brown algae, red algae, and/or certain seaweeds (marine microalgae); and adding a sufficient quantity of dried algae biomass to the formulation to adequately create a fire resistant flexible foam material.

An ultra-light graphene-rubber foam particle for soles is prepared from, by weight, 60-65 parts of natural rubber, 8-12 parts of isoprene rubber, 8-12 parts of butadiene rubber, 6-8 parts of styrene butadiene rubber, 0.8-1.0 parts of modified graphene, 0.08-0.12 parts of poly(N-vinylacetamide), 0.8-1.0 parts of silicone oil, 3.0-3.5 parts of inorganic nano-particles, 1.2-1.5 parts of activated zinc oxide, 0.8-1.0 parts of zinc stearate, 1.0-1.2 parts of stearic acid, 0.8-1.0 parts of cross-linking agents, 2.0-3.0 parts of flow promotors, and 1.5-1.8 parts of foaming agents. According to the invention, the modified graphene is uniformly dispersed into the rubber materials, so that the ultra-light graphene-rubber foam particle has good thermal stability, wear resistance and tensile strength, the permanent compressive-deformation performance and thermal contraction resistance are improved, and the weight is reduced by over 50%.

An ultra-light graphene-rubber foam particle for soles is prepared from, by weight, 60-65 parts of natural rubber, 8-12 parts of isoprene rubber, 8-12 parts of butadiene rubber, 6-8 parts of styrene butadiene rubber, 0.8-1.0 parts of modified graphene, 0.08-0.12 parts of poly(N-vinylacetamide), 0.8-1.0 parts of silicone oil, 3.0-3.5 parts of inorganic nano-particles, 1.2-1.5 parts of activated zinc oxide, 0.8-1.0 parts of zinc stearate, 1.0-1.2 parts of stearic acid, 0.8-1.0 parts of cross-linking agents, 2.0-3.0 parts of flow promotors, and 1.5-1.8 parts of foaming agents. According to the invention, the modified graphene is uniformly dispersed into the rubber materials, so that the ultra-light graphene-rubber foam particle has good thermal stability, wear resistance and tensile strength, the permanent compressive-deformation performance and thermal contraction resistance are improved, and the weight is reduced by over 50%.

A midsole includes an upper layer and a lower layer made of a foamed material; the upper layer is a low-hardness foamed material; the lower layer is a high-hardness foamed material; the low-hardness foamed material of the upper layer is a low-hardness, high-resilience material that has a higher specific gravity than the high-hardness foamed material, that has a low hardness that is lower than the hardness of the high-hardness foamed material, and that has a higher speed at which to recover to an original shape after being deformed than that of the high-hardness foamed material.

A midsole includes an upper layer and a lower layer made of a foamed material; the upper layer is a low-hardness foamed material; the lower layer is a high-hardness foamed material; the low-hardness foamed material of the upper layer is a low-hardness, high-resilience material that has a higher specific gravity than the high-hardness foamed material, that has a low hardness that is lower than the hardness of the high-hardness foamed material, and that has a higher speed at which to recover to an original shape after being deformed than that of the high-hardness foamed material.

The present invention generally relates to the printing of materials, using 3-dimensional printing and other printing techniques, including the use of one or more mixing nozzles, and/or multi-axis control over the translation and/or rotation of the print head or the substrate onto which materials are printed. In some embodiments, a material may be prepared by extruding material through print head comprising a nozzle, such as a microfluidic printing nozzle, which may be used to mix materials within the nozzle and direct the resulting product onto a substrate. The print head and/or the substrate may be configured to be translated and/or rotated, for example, using a computer or other controller, in order to control the deposition of material onto the substrate.

A method of forming a composite article includes constructing a preform having a strand layer including an interior portion and a peripheral portion surrounding the interior portion. The strand layer includes a plurality of strand segments traversing the interior portion and defining a first strand segment population density and a second strand segment population density. The preform is inserted into the mold cavity so that the interior portion of the preform is received in a molding region of the mold cavity. The molding region has a first thickness corresponding to the first strand segment population density and a second thickness corresponding to the second strand segment population density. Following the inserting, the mold is closed and the interior portion of the preform is compressed within the molding region. In the closed mold, the peripheral portion of the strand layer may be maintained in a loose state within the relief region.

A method of forming a composite article includes constructing a preform having a strand layer including an interior portion and a peripheral portion surrounding the interior portion. The strand layer includes a plurality of strand segments traversing the interior portion and defining a first strand segment population density and a second strand segment population density. The preform is inserted into the mold cavity so that the interior portion of the preform is received in a molding region of the mold cavity. The molding region has a first thickness corresponding to the first strand segment population density and a second thickness corresponding to the second strand segment population density. Following the inserting, the mold is closed and the interior portion of the preform is compressed within the molding region. In the closed mold, the peripheral portion of the strand layer may be maintained in a loose state within the relief region.

The invention provides a shoe (1) with a sole providing a dynamic foot arch support, the shoe comprising a rubber outsole (9) and an upper (10), the shoe further comprises a midsole (2), the midsole comprising a harder elastic material (4), a softer elastic material (5), wherein the harder elastic material has elastic hardness in a range 1.3 to 3 times higher than the softer elastic material. The shoe is distinguished in that the harder elastic material is arranged in a band (3) inside the periphery of the midsole, wherein the softer elastic material (5) is arranged in the midsole inside the band of the harder elastic material, and the shoe further comprises: a support structure (8) arranged below the softer elastic material in direction medial to lateral and positioned from vertically below to 4 cm in front of the naviculare bone center of a typical user with feet fitting the shoe size, wherein the support structure has higher elastic hardness than the harder elastic material, with a larger vertical dimension medial compared to lateral as seen with the shoe standing on a horizontal surface, providing increased support under the medial side of the foot arch compared to the lateral side of the foot arch.