The present invention relates to an organic electronic device comprising a semiconductor layer which comprises a compound of formula (1).

The present invention relates to an organic electronic device comprising a semiconductor layer which comprises a compound of formula (1).

The present invention concerns a method for preparing a compound of the following formula (III): R.sub.2(SO.sub.2)NM(SO.sub.2)F (III) in which R.sub.2 represents one of the following radicals: F, CF.sub.3, CHF.sub.2, CH.sub.2F, C.sub.2HF.sub.4, C.sub.2H.sub.2F.sub.3, C.sub.2H.sub.3F.sub.2, C.sub.2F, C.sub.3F.sub.7, C.sub.3H.sub.4F.sub.3, C.sub.3HF.sub.6, C.sub.4F.sub.9, C.sub.4H.sub.2F.sub.7, C.sub.4H.sub.4F, CF.sub.11, C.sub.6F.sub.13, C.sub.7F.sub.1, C.sub.8F.sub.17 or C.sub.9F.sub.19. M represents a monovalent or divalent cation; the method comprising: a step b) of fluorinating a compound of the following formula (I): R.sub.1(SO.sub.2)NH(SO.sub.2)Cl (I) in which R represents one of the following radicals: Cl, F, CF.sub.3, CHF.sub.2, CH.sub.2F, C.sub.2HF.sub.4, C.sub.2H.sub.2F.sub.3, C.sub.2H.sub.3F.sub.2, C.sub.2F, C.sub.3F.sub.7, C.sub.3H.sub.4F.sub.3, C.sub.3HF.sub.6, C.sub.4F.sub.9, C.sub.4H.sub.2F.sub.7, C.sub.4H.sub.4F, CF.sub.11, C.sub.6F.sub.13, C.sub.7F.sub.15, C.sub.8F.sub.17 or C.sub.9F.sub.19, R preferably representing Cl; with at least one fluorinating agent; 2a step c) of distilling the composition obtained in step b).

A method for preparing a compound having the following formula (IV): R.sub.2(SO.sub.2)NLi(SO.sub.2)F (IV), the method including a step a) of reacting a sulphamide having the following formula (A): R.sub.0(SO.sub.2)NH.sub.2 (A) with at least one sulphur-containing acid and at least one chlorinating agent, the step a) being carried out: at a temperature between 90 C. and 130 C., and at a pressure which is strictly greater than 7 bar (absolute).

A method for preparing a compound having the following formula (IV): R.sub.2(SO.sub.2)NLi(SO.sub.2)F (IV), the method including a step a) of reacting a sulphamide having the following formula (A): R.sub.0(SO.sub.2)NH.sub.2 (A) with at least one sulphur-containing acid and at least one chlorinating agent, the step a) being carried out: at a temperature between 90 C. and 130 C., and at a pressure which is strictly greater than 7 bar (absolute).

A class of sulfonimide salts for solid-state electrolytes can be synthesized based on successive S.sub.NAr reactions of fluorinated phenyl sulfonimides: Fluorinated Aryl Sulfonimide Tags (FAST). The chemical and electrochemical oxidative stability of these FAST salts as well as other properties like solubility, Lewis basicity, and conductivity can be tuned by introducing different numbers and types of nucleophilic functional groups to the FAST salt scaffold.

A class of sulfonimide salts for solid-state electrolytes can be synthesized based on successive S.sub.NAr reactions of fluorinated phenyl sulfonimides: Fluorinated Aryl Sulfonimide Tags (FAST). The chemical and electrochemical oxidative stability of these FAST salts as well as other properties like solubility, Lewis basicity, and conductivity can be tuned by introducing different numbers and types of nucleophilic functional groups to the FAST salt scaffold.

A salt, in particular a lithium salt, that is usable in alkali metal cells and/or batteries, and/or electrolytes and/or additives for same is described. To achieve good ion conductivity as well as temperature and high voltage stability and to prevent corrosion of aluminum, for example a current collector, the salt includes at least one alkali metal ion and/or at least one ammonium compound and at least one anion that contains at least one unfluorinated (N,N-dialkylamide)sulfonyl group and/or at least one unfluorinated (N,N-dialkylamide)sulfoximide group, and at least one (perfluoroalkyl)sulfonyl group. An electrolyte, an additive, a cell, a battery, and a preparation method, are also described.

Provided is a process for converting a hydrocarbon comprising at least one CH bond to a nitrogen-functionalized product. The process comprises contacting a hydrocarbon and (i) an oxidizing electrophile comprising (a) a main group element or transition metal in oxidized form and (b) at least one nitrogen-containing ligand, or (ii) an oxidant and a reduced form of an oxidizing electrophile comprising (a) a main group element or transition metal and (b) at least one nitrogen-containing ligand, in a solvent to provide the nitrogen-functionalized product and an electrophile reduction product. Further provided is an oxidizing composition comprising the oxidizing electrophile with at least one nitrogen-containing ligand and a non-oxidizable liquid.

Provided is a process for converting a hydrocarbon comprising at least one CH bond to a nitrogen-functionalized product. The process comprises contacting a hydrocarbon and (i) an oxidizing electrophile comprising (a) a main group element or transition metal in oxidized form and (b) at least one nitrogen-containing ligand, or (ii) an oxidant and a reduced form of an oxidizing electrophile comprising (a) a main group element or transition metal and (b) at least one nitrogen-containing ligand, in a solvent to provide the nitrogen-functionalized product and an electrophile reduction product. Further provided is an oxidizing composition comprising the oxidizing electrophile with at least one nitrogen-containing ligand and a non-oxidizable liquid.