Patent classifications
C07C2529/04
SCM-11 MOLECULAR SIEVE, PROCESS FOR PRODUCING SAME AND USE THEREOF
The present invention relates to an SCM-11 molecular sieve, a process for producing same and use thereof. The molecular sieve has an empirical chemical composition as illustrated by the formula the first oxide.Math.the second oxide, wherein the ratio by molar of the first oxide to the second oxide is more than 2, the first oxide is silica, the second oxide is at least one selected from the group consisting of germanium dioxide, alumina, boron oxide, iron oxide, gallium oxide, titanium oxide, rare earth oxides, indium oxide and vanadium oxide. The molecular sieve has specific XRD pattern, and can be used as an adsorbent or a catalyst for converting an organic compound.
SCM-10 MOLECULAR SIEVE, PROCESS FOR PRODUCING SAME AND USE THEREOF
The present invention relates to an SCM-10 molecular sieve, a process for producing same and use thereof. The molecular sieve has an empirical chemical composition as illustrated by the formula the first oxide.Math.the second oxide, wherein the ratio by molar of the first oxide to the second oxide is less than 40, the first oxide is at least one selected from the group consisting of silica and germanium dioxide, the second oxide is at least one selected from the group consisting of alumina, boron oxide, iron oxide, gallium oxide, titanium oxide, rare earth oxides, indium oxide and vanadium oxide. The molecular sieve has specific XRD pattern and can be used as an adsorbent or a catalyst for converting an organic compound.
A PROCESS FOR CONVERTING NATURAL GAS TO HIGHER HYDROCARBON(S)
The present invention relates to a process for converting natural gas to higher hydrocarbon(s) including aromatic hydrocarbon(s) in n reaction zones operated in series, wherein m reaction zones are not participating in the conversion process and only (nm) reaction zones are operated under reaction conditions sufficient to convert at least a portion of said natural gas to an effluent having said higher hydrocarbon(s). An object of the present invention is to provide a process for converting natural gas to higher hydrocarbon(s) including aromatic hydrocarbon(s) wherein a high reactant, i.e. methane, conversion can be achieved.
Removal of nitrogen-containing impurities form alcohol compositions
Process for the treatment of an alcohol composition containing nitrogen-containing contaminants by contacting the alcohol composition in the vapor phase with an adsorbent in an adsorption zone.
Efficient conversion of pure and mixed terpene feedstocks to high density fuels
A process for making high density fuels, pure terpene dimers, and byproducts from mixed terpene feedstocks and the resulting high density fuel products. The fuels produced by the process includes, dimerizing at least one terpene feedstock by mixing at least one terpene with at least one heterogeneous acidic catalyst and at least one solvent used to control the reaction temperature for a desired time and temperature to produce a crude terpene dimer (C.sub.20H.sub.32 mixture) in about 65% to about 95% chemical yield, hydrogenating the crude terpene dimer (C.sub.20H.sub.32 mixture) with at least one hydrogenation catalyst under a hydrogen atmosphere and removing the hydrogenating catalyst(s) to produce about 65% by weight to about 95% by weight of hydrogenated terpene dimer mixture, and utilizing a separation method against the hydrogenated terpene dimer mixture to produce byproducts, where the process generates a hydrocarbon mixture with a viscosity of between about 20 and 50 cSt at 40 C.
Hydrocarbon Conversion
The invention relates to the conversion of paraffinic hydrocarbon to oligomers of greater molecular weight and/or to aromatic hydrocarbon. The invention also relates to equipment and materials useful in such conversion, and to the use of such conversion for, e.g., natural gas upgrading. Corresponding olefinic hydrocarbon is produced from the paraffinic hydrocarbon in the presence of a dehydrogenation catalyst containing a catalytically active carbonaceous component. The corresponding olefinic hydrocarbon is then converted by oligomerization and/or dehydrocyclization in the presence of at least one molecular sieve catalyst.
PROCESS FOR PREPARING LINEAR ALPHA-OLEFIN BY OLIGOMERIZATION OF ETHYLENE
The present invention relates to a process for preparing a catalyst, wherein the process comprises steps of: 1) providing a molecular sieve, adding an active metal promoter into the molecular sieve, and shaping the molecular sieve into a shaped body, 2) placing the shaped body in a fixed bed reactor, 3) dissolving a transition metal salt in a first valence state and a bidentate ligand into a solvent to prepare a solution, 4) passing the solution and ethylene through the fixed bed reactor charged with the shaped body, loading the transition metal onto the molecular sieve through ion exchange, and at the same time the transition metal in the first valence state at least partially being reduced into a transition metal salt in a second valence state by the active metal promoter, wherein the second valence state is lower than the first valence state, so as to obtain the catalyst.
Continuous mixing reactor and method of use
A continuous mixing reactor has an outer shell having a cylindrical portion with a central section and two opposite conical end sections; a circulation tube within the shell so that an annular passage forms between the shell and the circulation tube; an impeller within and positioned adjacent to one end of the circulation tube; and heat exchange means penetrating the outer shell and extending into the end of the circulation tube opposite the impeller. The outer shell has a hydraulic head forming one end of the shell, a heat exchange medium header at the opposite end of the shell. The circulation tube nearer the heat exchange medium header terminates at or downstream from a tangential plane extending through the shell at the intersection of the central section and the conical end section of the cylindrical portion of shell. The reactor is useful in an alkylation process.
CIT-10: A TWO DIMENSIONAL LAYERED CRYSTALLINE MICROPOROUS SILICATE COMPOSITION AND COMPOSITIONS DERIVED THEREFROM
This disclosure relates to a new crystalline microporous silicate solid, designated CIT-10, comprising a two dimensional layered structure, having an organic interlayer sandwiched between individual crystalline silicate layers. This CIT-10 material can be converted to a pure-silicate of RTH topology, as well as two new of pillared silicate structures, designated CIT-11 and CIT-12. This disclosure characterizes new materials and provides methods of preparing and using these new crystalline microporous solids.
Molecular sieve SSZ-116, its synthesis and use
A novel synthetic crystalline aluminogermanosilicate molecular sieve material, designated SSZ-116, is provided. SSZ-116 can be synthesized using 3-[(3,5-di-tert-butylphenyl)methyl]-1,2-dimethyl-1H-imidazolium cations as a structure directing agent. SSZ-116 may be used in organic compound conversion reactions and/or sorptive processes. This disclosure also relates to the structure directing agents used in the methods for making the SSZ-116 material as well as the synthesis method used to prepare such structure directing agents.