Patent classifications
C07C2531/02
Ethylene Oligomerization Processes
Disclosed herein is a process for forming an oligomer product comprising (a) introducing into a reaction zone (i) ethylene; (ii) a heteroatomic ligand metal salt complex comprising a heteroatomic ligand complexed to a first metal salt; (iii) a second metal salt wherein an equivalent molar ratio of the second metal salt to the heteroatomic ligand of the heteroatomic ligand metal salt complex is at least 0.5:1 and where the second metal salt is an iron salt, a cobalt salt, or any combination thereof; (iv) an organoaluminum compound; and (b) forming an oligomer product. Also disclosed herein is a process comprising (a) introducing into a reaction zone (i) ethylene; (ii) a heteroatomic ligand; (iii) a metal salt where an equivalent molar ratio of the metal salt to the heteroatomic ligand is at least 1.5:1; (iv) an organoaluminum compound; and (b) forming an oligomer product.
IONIC LIQUID ALKYLATION OF ISOBUTANE WITH ETHYLENE TO PRODUCE ALKYLATE
A process for producing high octane alkylate is provided. The process involves reacting isobutane and ethylene using an ionic liquid catalyst. Reaction conditions can be chosen to assist in attaining, or to optimize, desirable alkylate yields and/or properties.
Natural gas liquid upgrading by ionic liquid catalyzed alkylation
We provide a process, comprising: a. dehydrogenating natural gas liquid to produce a mixture comprising olefins and unconverted paraffins; b. without further purification or modification other than mixing with an isoparaffin, sending the mixture to a single alkylation reactor; c. alkylating the olefins with the isoparaffin, using an ionic liquid catalyst, to produce one or more alkylate products; and d. distilling the one or more alkylate products and collecting a bottoms distillation fraction that is a middle distillate blending component having a sulfur level of 50 wppm or less and a Bromine number less than 1.
CATALYST BASED ON CATECHOLAMINE AND ITS USE IN A HYDROTREATMENT AND/OR HYDROCRACKING PROCESS
The invention concerns a catalyst comprising a support based on alumina or silica or silica-alumina, at least one element selected from group VIII and/or group VIB, and at least one catecholamine. The invention also concerns the process for the preparation of said catalyst and its use in a hydrotreatment and/or hydrocracking process.
Ethylene selective oligomerization catalyst systems and method for ethylene oligomerization using the same
The disclosure provides a catalyst system and a method for ethylene oligomerization using this. The catalyst system contains: ligand a, containing carbene groups of imidazole ring type; transition metal compound b, that is one of IVBVIII group metal compounds; activator c, that is a compound containing III A group metals; the ligand a contains at least one group as shown in general formula I:
##STR00001##
in which, bridging group A contains a main chain including alkyl, alkenyl, aryl groups or the combination of them and the first heteratom; E is a linear or cyclic group containing the second heteroatom; R is a hydrocarbyl group. The catalyst system is especially used for trimerization and tetramerization of ethylene. The catalyst system has high selectivity for 1-hexene and 1-octene, low selectivity for 1-butene and I-C.sub.10+, and the total percent content of C.sub.6C.sub.8 linear -olefin in the product is more than 90% by mass.
Viscosity modifiers for decreasing the viscosity of ionic liquids
A process utilizing an ionic liquid is described. The process includes contacting a hydrocarbon feed with an ionic liquid component, the ionic liquid component comprising a mixture of a first ionic liquid and a viscosity modifier, wherein a viscosity of the ionic liquid component is at least about 10% less than a viscosity of the first ionic liquid.
Alkylate base oil of biological origin
An alkylate base oil of a biological origin having a kinematic viscosity at 100 C. from 3 mm.sup.2/s to 20 mm.sup.2/s, and characterized by having a total integral of a .sup.13C NMR spectrum wherein 25-60% of the total integral of the .sup.13C NMR spectrum falls within .sup.13C NMR resonances in ranges for linear long chain alkyl groups given by: C1(13.9-14.2 ppm), C2(22.6-22.8 ppm), C3(31.9-32.05 ppm), C4(29.35-29.45 ppm), and C5+(29.6-29.8 ppm).
Method for depolymerising oxygenated polymer materials
The present invention concerns a method for depolymerizing oxygenated polymer materials and the use of said method in the recycling of plastic materials and the preparation of aromatic compounds that can be used as fuel, synthesis intermediates and raw materials in the construction sectors and in the petrochemical, electrical, electronic, textile, aeronautical, pharmaceutical, cosmetics and agrochemical industries. The present invention also concerns the use of aromatic compounds obtained by the method for depolymerizing oxygenated polymer materials according to the invention, in the production of fuels, electronic components, plastic polymers, rubber, drugs, vitamins, cosmetic products, perfumes, food products, synthetic threads and fibers, synthetic leathers, glues, pesticides and fertilizers.
NATURAL GAS LIQUID UPGRADING BY IONIC LIQUID CATALYZED ALKYLATION
We provide a process, comprising:
a. dehydrogenating natural gas liquid to produce a mixture comprising olefins and unconverted paraffins;
b. without further purification or modification other than mixing with an isoparaffin, sending the mixture to a single alkylation reactor;
c. alkylating the olefins with the isoparaffin, using an ionic liquid catalyst, to produce one or more alkylate products; and
d. distilling the one or more alkylate products and collecting a bottoms distillation fraction that is a middle distillate blending component having a sulfur level of 50 wppm or less and a Bromine number less than 1.
Synthesis method of 3,4-hexanedione
A synthesis method of 3,4-hexanedione comprises a step of 4-hydroxy-3-hexanonen oxidation, and in the step of 4-hydroxy-3-hexanonen oxidation, water is used as a catalyst, acetic acid is used as a cocatalyst, and ozone is used as an oxidizing agent to carry out an oxidation reaction on 4-hydroxy-3-hexanonen, and after the reaction, distillation under reduced pressure is carried out to obtain the 3,4-hexanedione. According to the synthesis method of 3,4-hexanedione in the invention, in the process of 4-hydroxy-3-hexanone oxidation, the 4-hydroxy-3-hexanone is placed in the water, the ozone is used for oxidation on the 4-hydroxy-3-hexanone, and the acetic acid is used as the cocatalyst, so that the entire oxidation reaction process is mild in conditions and simple to operate, no sewage is produced when the final product (3,4-hexanedione) is obtained, and the yield is greatly increased.