Patent classifications
C07C2531/02
Integrated reactor for ionic liquid alkylation using bio-ethylene feedstock
An alkylation process is described. The process involves alkylation of isobutane and ethylene in a loop reactor using an ionic liquid catalyst as a continuous phase. The alkylate typically has a research octane number of at least about 93, and the olefin conversion is typically at least about 95%.
REGENERATION OF AN IONIC LIQUID CATALYST BY HYDROGENATION USING A MACROPOROUS NOBLE METAL CATALYST
The present disclosure provides a macroporous noble metal catalyst and processes employing such catalysts for the regeneration of deactivated ionic liquid catalyst containing conjunct polymer.
Method for Depolymerising Oxygenated Polymer Materials
The present invention concerns a method for depolymerizing oxygenated polymer materials and the use of said method in the recycling of plastic materials and the preparation of aromatic compounds that can be used as fuel, synthesis intermediates and raw materials in the construction sectors and in the petrochemical, electrical, electronic, textile, aeronautical, pharmaceutical, cosmetics and agrochemical industries. The present invention also concerns the use of aromatic compounds obtained by the method for depolymerizing oxygenated polymer materials according to the invention, in the production of fuels, electronic components, plastic polymers, rubber, drugs, vitamins, cosmetic products, perfumes, food products, synthetic threads and fibres, synthetic leathers, glues, pesticides and fertilizers.
IONIC LIQUID ALKYLATION OF ISOBUTANE WITH ETHYLENE TO PRODUCE ALKYLATE
A process for producing high octane alkylate is provided. The process involves reacting isobutane and ethylene using an ionic liquid catalyst. Reaction conditions can be chosen to assist in attaining, or to optimize, desirable alkylate yields and/or properties.
COMBINED PROCESS FOR ALKYLATION OF LIGHT OLEFINS USING IONIC LIQUID CATALYSTS
Processes for the direct alkylation of ethylene with isobutane or isopentane using a highly active ionic liquid alkylation catalyst are described. Ethylene is sent to a high-temperature alkylation reactor loop, and C.sub.3, C.sub.4, and C.sub.5 olefins are routed to a low temperature alkylation reactor loop. In each reactor, the olefins are contacted with an excess of isobutane or isopentane in the presence of a highly active ionic liquid catalyst. Portions of the reactor effluent streams are fed to a common downstream catalyst separation and product fractionation sections. The remainder of the reactor effluent is recycled back to the respective alkylation reactor.
HIGH VISCOSITY INDEX LUBRICANTS BY ISOALKANE ALKYLATION
An isoalkane alkylate base oil and a process to make an isoalkane alkylate base oil having a VI higher than 90, comprising: a. selecting an isoalkane feed containing at least one isoalkane and an olefin feed containing at least one linear olefin such that a combined carbon number of the isoalkane feed and the olefin feed is from 20 to 60; and b. alkylating the isoalkane feed with the olefin feed in the presence of an acidic alkylation catalyst under alkylation conditions to make the isoalkane alkylate base oil having the VI higher than 90; wherein the isoalkane alkylate base oil has a kinematic viscosity at 100° C. from 2 to 30 mm.sup.2/s, a pour point less than 0° C., and a bromine index less than 2000 mg Br/100 g.
Farnesane alkylation
An alkylate base oil of biological origin and a process to make an alkylate base oil comprising: a) hydrogenating a farnesene to make a farnesane comprising from zero to less than 5 wt % unsaturated molecules; and b) alkylating the farnesane with one or more C6 to C43 olefins in the presence of an acidic alkylation catalyst to make the alkylate base oil having a kinematic viscosity at 100° C. from 3 mm.sup.2/s to 20 mm.sup.2/s.
SYNTHESIS METHOD AND SYNTHESIS DEVICE FOR CYCLODODECENE
A synthesis method and a synthesis device of cyclododecene according to the present invention have a high conversion rate of cyclododecatriene which is a reactant and a high selectivity of cyclododecene which is a required product, and even so, have an effect of significantly decreasing a reaction time. In addition, the method and the device have an excellent conversion rate of cyclododecatriene and an excellent selectivity of cyclododecene, while maintaining excellent reactivity without an organic solvent such as ethanol. Therefore, a volume of the reactor relative to an output of cyclododecene may be further decreased. Moreover, the method and the device may minimize costs for facilities and process, are practical, decrease a process time, and are industrially advantageous for mass production as compared with the conventional art.
ALKYLATION OF METALLOCENE-OLIGOMER WITH ISOALKANE TO MAKE HEAVY BASE OIL
A process to make an isoalkane alkylate base oil, comprising: a. oligomerizing an olefin feed having a carbon number from 3 to 6 using a metallocene catalyst to make an unsaturated olefin oligomer; and b. alkylating an isoalkane feed with the unsaturated olefin oligomer in the presence of an acidic alkylation catalyst, and without any addition of hydrogen, to make an alkylate product comprising the isoalkane alkylate base oil having a kinematic viscosity at 100° C. greater than 10 mm.sup.2/s, a VI higher than 80, and a bromine index less than 1000 mg Br/100 g.
BASE OIL HAVING HIGH VISCOSITY INDEX FROM ALKYLATION OF DIMER KETONE-DERIVED OLEFIN
A process to make an alkylate base oil having a viscosity index greater than or equal to 90, comprising: a. converting an at least one dimeric ketone to an at least one alcohol; b. dehydrating the at least one alcohol to make one or more corresponding olefins; and c. alkylating at least one isoalkane with the one or more corresponding olefins to form the alkylate base oil.