A lithium battery includes a cathode including a cathode active material; an anode including an anode active material; and an organic electrolytic solution between the cathode and the anode, wherein the cathode active material includes a first lithium transition metal oxide and a second lithium transition metal oxide, the first lithium transition metal oxide and the second lithium transition metal oxide have different particle diameters, the second lithium transition metal oxide includes primary particles having a particle diameter of about 1 μm or more, and the organic electrolytic solution includes a first lithium salt, an organic solvent, and a bicyclic sulfate-based compound represented by Formula 1 below:

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An electrolyte includes a compound of formula 1:

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R.sub.1 and R.sub.2 are each independently selected from H, halogen atom, a substituted or unsubstituted C.sub.1-10 alkyl group, a substituted or unsubstituted C.sub.3-10 cycloalkyl group, a substituted or unsubstituted C.sub.2-10 alkenyl group, a substituted or unsubstituted C.sub.2-10 alkynyl group, a substituted or unsubstituted C.sub.1-10 alkoxy group, a substituted or unsubstituted C.sub.6-10 aryl group, a substituted or unsubstituted C.sub.3-10 heteroaryl group, or any combination thereof. R is selected from a substituted or unsubstituted C.sub.1-10 alkyl group, a substituted or unsubstituted C.sub.3-10 cycloalkyl group, a substituted or unsubstituted C.sub.2-10 alkenyl group, a substituted or unsubstituted C.sub.2-10 alkynyl group, a substituted or unsubstituted C.sub.1-10 alkoxy group, a substituted or unsubstituted C.sub.6-10 aryl group or a substituted or unsubstituted C.sub.3-10 heteroaryl group, a substituted or unsubstituted C.sub.3-10 heterocycloalkyl group, a butyrolactam group,

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or any combination thereof.

An electrolyte includes a compound of formula 1:

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R.sub.1 and R.sub.2 are each independently selected from H, halogen atom, a substituted or unsubstituted C.sub.1-10 alkyl group, a substituted or unsubstituted C.sub.3-10 cycloalkyl group, a substituted or unsubstituted C.sub.2-10 alkenyl group, a substituted or unsubstituted C.sub.2-10 alkynyl group, a substituted or unsubstituted C.sub.1-10 alkoxy group, a substituted or unsubstituted C.sub.6-10 aryl group, a substituted or unsubstituted C.sub.3-10 heteroaryl group, or any combination thereof. R is selected from a substituted or unsubstituted C.sub.1-10 alkyl group, a substituted or unsubstituted C.sub.3-10 cycloalkyl group, a substituted or unsubstituted C.sub.2-10 alkenyl group, a substituted or unsubstituted C.sub.2-10 alkynyl group, a substituted or unsubstituted C.sub.1-10 alkoxy group, a substituted or unsubstituted C.sub.6-10 aryl group or a substituted or unsubstituted C.sub.3-10 heteroaryl group, a substituted or unsubstituted C.sub.3-10 heterocycloalkyl group, a butyrolactam group,

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or any combination thereof.

Thionyl tetrafluoride gas reacts efficiently with primary amines to form reactive iminosulfur oxydifluoride compounds. These dual S.sup.VI—F loaded iminosulfur oxydifluoride compounds, in turn, readily react with secondary amines or aryloxy silyl ethers (ArO—SiR.sub.3), yielding the corresponding fused heteroatom-linked substrates. Iminosulfur oxyfluoride polymers also are provided by disclosed methods.

Thionyl tetrafluoride gas reacts efficiently with primary amines to form reactive iminosulfur oxydifluoride compounds. These dual S.sup.VI—F loaded iminosulfur oxydifluoride compounds, in turn, readily react with secondary amines or aryloxy silyl ethers (ArO—SiR.sub.3), yielding the corresponding fused heteroatom-linked substrates. Iminosulfur oxyfluoride polymers also are provided by disclosed methods.

An electrolytic solution includes the compound of Formula I and a carboxylate compound:

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The electrochemical device prepared with the electrolytic solution has reduced storage impedance, and improved post-storage swelling, overcharge performance and hot box performance.

An electrolytic solution includes the compound of Formula I and a carboxylate compound:

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The electrochemical device prepared with the electrolytic solution has reduced storage impedance, and improved post-storage swelling, overcharge performance and hot box performance.

The present invention is aimed at providing: a non-aqueous electrolyte solution for a sodium ion secondary battery, with which a sodium ion secondary battery having a low resistance and showing a limited amount of gas generation after a durability test can be provided; and a sodium ion secondary battery obtained by using the same. The non-aqueous electrolyte solution for a sodium ion secondary battery comprises: a non-aqueous solvent; NaPF.sub.6; and a compound represented by the following Formula (1) (wherein, R.sub.1 and R.sub.2 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 6 carbon atoms, and n represents 0 or 1), and a ratio of the content of the compound represented by Formula (1) with respect to the content of NaPF.sub.6, [compound represented by Formula (1)]/[NaPF.sub.6] (molar ratio), is 0.001 to 1.5:

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The present invention is aimed at providing: a non-aqueous electrolyte solution for a sodium ion secondary battery, with which a sodium ion secondary battery having a low resistance and showing a limited amount of gas generation after a durability test can be provided; and a sodium ion secondary battery obtained by using the same. The non-aqueous electrolyte solution for a sodium ion secondary battery comprises: a non-aqueous solvent; NaPF.sub.6; and a compound represented by the following Formula (1) (wherein, R.sub.1 and R.sub.2 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 6 carbon atoms, and n represents 0 or 1), and a ratio of the content of the compound represented by Formula (1) with respect to the content of NaPF.sub.6, [compound represented by Formula (1)]/[NaPF.sub.6] (molar ratio), is 0.001 to 1.5:

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A non-aqueous electrolyte for a lithium-ion battery and a lithium-ion battery. The non-aqueous electrolyte comprises unsaturated phosphate compounds and unsaturated cyclic carboxylic acid anhydride compounds. The unsaturated phosphate compounds have the structure illustrated in structural formula 4; structural formula 4: R.sub.13, R.sub.11, and R.sub.12 are independently selected from hydrocarbon groups having 1-5 carbon atoms respectively, and at least one of R.sub.13, R.sub.11, and R.sub.12 is an unsaturated hydrocarbon group containing double bonds or triple bonds; the unsaturated cyclic carboxylic acid anhydride compounds have the structure illustrated in structural formula 5; structural formula 5: R.sub.14 is independently selected from vinylidene having 2-4 carbon atoms or fluoro-substituted vinylidene. By means of the synergistic effect of two compounds, the non-aqueous electrolyte has excellent high-temperature cycling performance and storage performance, and also has lower impedance and good low-temperature performance. ##STR00001##