Patent classifications
C07F1/06
POLYMERIZATION INHIBITOR FOR N-VINYL PYRROLIDONE MONOMER AND USE THEREOF
Disclosed is a polymerization inhibitor of N-vinyl pyrrolidone monomers and use thereof. The polymerization inhibitor is selected from an inorganic weak acid potassium salt and/or an organic acid potassium salt. The polymerization inhibitor is added to N-vinyl pyrrolidone monomers, and is sealed and preserved under the protection of inert gas, wherein the addition amount of the polymerization inhibitor is 0.005-0.2% by mass with respect to the mass of the N-vinyl pyrrolidone monomers. Directly adding the polymerization inhibitor into the N-vinyl pyrrolidone monomers in proportion can inhibit the self-polymerization of the N-vinyl pyrrolidone monomers, and hence extend the shelf life. The chromaticity and toxicity of the monomers can be reduced to a great extent. The polymerization inhibitor can be used directly during solution polymerization without being removed, and does not affect the chromaticity of a polymerization solution.
METHOD OF PRODUCING A 2-((METH)ALLYLOXYMETHYL)ACRYLIC ACID DERIVATIVE, AND 2-((METH)ALLYLOXYMETHYL)ACRYLIC ACID ALKALI METAL SALT POWDER
Provided is a method of producing various 2-((meth)allyloxymethyl)acrylic acid derivatives in high yields with no need to load a raw material in a large excess for improving a reaction conversion ratio, and without use of a catalyst having high toxicity or a strong acid catalyst. Also provided are powder compounds that may be utilized as raw materials for synthesizing various chemical products. A method of producing a 2-((meth)allyloxymethyl)acrylic acid derivative includes causing the powder of a salt of a 2-((meth)allyloxymethyl)acrylic acid anion and an alkali metal cation (component A), and a halide (component B) to react with each other to produce a 2-((meth)allyloxymethyl)acrylic acid derivative. The 2-((meth)allyloxymethyl)acrylic acid alkali metal salt powder is the powder of a salt of a 2-((meth)allyloxymethyl)acrylic acid anion and an alkali metal cation, and has a bulk density of 0.50 g/mL or more, or a water content of 0.05 wt % or less.
METHOD OF PRODUCING A 2-((METH)ALLYLOXYMETHYL)ACRYLIC ACID DERIVATIVE, AND 2-((METH)ALLYLOXYMETHYL)ACRYLIC ACID ALKALI METAL SALT POWDER
Provided is a method of producing various 2-((meth)allyloxymethyl)acrylic acid derivatives in high yields with no need to load a raw material in a large excess for improving a reaction conversion ratio, and without use of a catalyst having high toxicity or a strong acid catalyst. Also provided are powder compounds that may be utilized as raw materials for synthesizing various chemical products. A method of producing a 2-((meth)allyloxymethyl)acrylic acid derivative includes causing the powder of a salt of a 2-((meth)allyloxymethyl)acrylic acid anion and an alkali metal cation (component A), and a halide (component B) to react with each other to produce a 2-((meth)allyloxymethyl)acrylic acid derivative. The 2-((meth)allyloxymethyl)acrylic acid alkali metal salt powder is the powder of a salt of a 2-((meth)allyloxymethyl)acrylic acid anion and an alkali metal cation, and has a bulk density of 0.50 g/mL or more, or a water content of 0.05 wt % or less.
Viologen compound, method for producing the same, negative electrode active material, and electricity storage device
A viologen compound is a crystalline compound including a heterocyclic moiety in which a carboxylate of an alkali metal is bound directly or indirectly to both ends of a basic skeleton containing 4,4-bipyridinium and an anionic moiety that pairs with 4,4-bipyridinium. The viologen compound can be used, for example, as a negative electrode active material for an electricity storage device including a negative electrode containing the negative electrode active material, a positive electrode containing a positive electrode active material capable of giving and receiving anions, and an ion-conducting medium that is disposed between the positive electrode and the negative electrode and conducts anions.
Metal-organic hybrid structures built with multi-directional polydentate ligands
A compound represented by Chemical Formula 1 according to the present invention can coordinate with metal ions to form a bidirectional or multidirectional metal-organic hybrid structure. Thus, the present invention can synthesize various ligands using amine-aldehyde condensation, and synthesize metal-organic materials using the same.
Metal-organic hybrid structures built with multi-directional polydentate ligands
A compound represented by Chemical Formula 1 according to the present invention can coordinate with metal ions to form a bidirectional or multidirectional metal-organic hybrid structure. Thus, the present invention can synthesize various ligands using amine-aldehyde condensation, and synthesize metal-organic materials using the same.
Double metal cyanide catalyst for the production of polyether polyols and a process thereof
The present invention discloses a Double Metal Cyanide (DMC) catalyst(s) useful for the production of polyether polyols (PEPO) and a less energy intensive room temperature method for the synthesis thereof. The catalyst(s) comprises of a DMC complex, an organic complexing agent, i.e., ethylenediaminetetraacetic acid (EDTA) and other co-complexing organic agents, e.g., t-BuOH, PEPO of composition ranging from about 1 to 10 wt %, wherein the average molecular weight of PEPO used ranged from 200 to 1000. A method of preparing a series of DMC catalyst(s) at room temperature with varying compositional ratios of the complexing and co-complexing agents targeting a wide range of PEPO of varying kinematic viscosity range is also disclosed. These DMC catalyst(s) are amorphous, highly active, and easily separable from product PEPO with recyclability/recoverability, making the product PEPO better industrially applicable and DMC catalyst more cost-effective.
Double metal cyanide catalyst for the production of polyether polyols and a process thereof
The present invention discloses a Double Metal Cyanide (DMC) catalyst(s) useful for the production of polyether polyols (PEPO) and a less energy intensive room temperature method for the synthesis thereof. The catalyst(s) comprises of a DMC complex, an organic complexing agent, i.e., ethylenediaminetetraacetic acid (EDTA) and other co-complexing organic agents, e.g., t-BuOH, PEPO of composition ranging from about 1 to 10 wt %, wherein the average molecular weight of PEPO used ranged from 200 to 1000. A method of preparing a series of DMC catalyst(s) at room temperature with varying compositional ratios of the complexing and co-complexing agents targeting a wide range of PEPO of varying kinematic viscosity range is also disclosed. These DMC catalyst(s) are amorphous, highly active, and easily separable from product PEPO with recyclability/recoverability, making the product PEPO better industrially applicable and DMC catalyst more cost-effective.
POTASSIUM MIXTURES COMPOSITIONS AND METHODS
Composition and methods of applying potassium mixtures are disclosed. Applications include: fertilizer and fertilizer additives, freeze conditioning, dust control, coating oil, and fire prevention.
POTASSIUM MIXTURES COMPOSITIONS AND METHODS
Composition and methods of applying potassium mixtures are disclosed. Applications include: fertilizer and fertilizer additives, freeze conditioning, dust control, coating oil, and fire prevention.