The invention relates to an organic molecule, in particular for use in organic optoelectronic devices. According to the invention, the organic molecule has one first chemical moiety with a structure of formula I, ##STR00001## and one second chemical moiety with a structure of formula II, ##STR00002## wherein the first chemical moiety is linked to the second chemical moiety via a single bond.

A trichlorogermanide of formula (I): [R.sub.4N]/[R.sub.4P]Cl[GeCl.sub.3] (I), where R is Me, Et, iPr, nBu, or Ph, tris(trichlorosilyl)germanide of formula (II): [R.sub.4N]/[R.sub.4P][Ge(SiCl.sub.3).sub.3] (II), where R is Me, Et, iPr, nBu, or Ph, a tris(trichlorosilyl)germanide adduct of GaCl.sub.3 of formula (III): [Ph.sub.4p][Ge(SiCl.sub.3).sub.3*GaCl.sub.3], and a tris(trichlorosilyl)germanide adduct of BBr.sub.3 of formula (IV): [Ph.sub.4P[]Ge(SiCl.sub.3).sub.3*BBr.sub.3]. Also, methods for preparing the trichlorogermanides of formula (I), the tris(trichlorosilyl)germanide of formula (II), the tris(trichlorosilyl)germanide adduct of BBr.sub.3 of formula (IV).

A trichlorogermanide of formula (I): [R.sub.4N]/[R.sub.4P]Cl[GeCl.sub.3] (I), where R is Me, Et, iPr, nBu, or Ph, tris(trichlorosilyl)germanide of formula (II): [R.sub.4N]/[R.sub.4P][Ge(SiCl.sub.3).sub.3] (II), where R is Me, Et, iPr, nBu, or Ph, a tris(trichlorosilyl)germanide adduct of GaCl.sub.3 of formula (III): [Ph.sub.4p][Ge(SiCl.sub.3).sub.3*GaCl.sub.3], and a tris(trichlorosilyl)germanide adduct of BBr.sub.3 of formula (IV): [Ph.sub.4P[]Ge(SiCl.sub.3).sub.3*BBr.sub.3]. Also, methods for preparing the trichlorogermanides of formula (I), the tris(trichlorosilyl)germanide of formula (II), the tris(trichlorosilyl)germanide adduct of BBr.sub.3 of formula (IV).

An aspect of the present disclosure is a method that includes combining a first organic salt (A.sup.1X.sup.1), a first metal salt (M.sup.1(X.sup.2).sub.2), a second organic salt (A.sup.2X.sup.3), a second metal salt (M.sup.2Cl.sub.2), and a solvent to form a primary solution, where A.sup.1X.sup.1 and M.sup.1(X.sup.2).sub.2 are present in the primary solution at a first ratio between about 0.5 to 1.0 and about 1.5 to 1.0, and A.sup.2X.sup.3 to M.sup.2Cl.sub.2 are present in the primary solution at a second ratio between about 2.0 to 1.0 and about 4.0 to 1.0. In some embodiments of the present disclosure, at least one of A.sup.1 or A.sup.2 may include at least one of an alkyl ammonium, an alkyl diamine, cesium, and/or rubidium.

An aspect of the present disclosure is a method that includes combining a first organic salt (A.sup.1X.sup.1), a first metal salt (M.sup.1(X.sup.2).sub.2), a second organic salt (A.sup.2X.sup.3), a second metal salt (M.sup.2Cl.sub.2), and a solvent to form a primary solution, where A.sup.1X.sup.1 and M.sup.1(X.sup.2).sub.2 are present in the primary solution at a first ratio between about 0.5 to 1.0 and about 1.5 to 1.0, and A.sup.2X.sup.3 to M.sup.2Cl.sub.2 are present in the primary solution at a second ratio between about 2.0 to 1.0 and about 4.0 to 1.0. In some embodiments of the present disclosure, at least one of A.sup.1 or A.sup.2 may include at least one of an alkyl ammonium, an alkyl diamine, cesium, and/or rubidium.

The present invention relates to an organic light emitting diode comprising: a first electrode; a second electrode facing the first electrode; a hole injecting layer or a hole transport layer, which is interposed between the first electrode and the second electrode; and a light emitting layer, wherein the hole injecting layer or the hole transport layer comprises at least one type of amine compound represented by chemical formula A or chemical formula B, and the chemical formula A and the chemical formula B are the same as those included in the description of the invention.

There is disclosed a compound having Formula I ##STR00001## In Formula, I: Ar.sup.1 is selected from the group consisting of dibenzofuran, dibenzothiophene, or deuterated analogs thereof; Ar.sup.2 and Ar.sup.3 are the same or different and are hydrocarbon aryl, substituted derivatives thereof, or deuterated analogs thereof, with the proviso that Ar.sup.2 and Ar.sup.3 are not the same as Ar.sup.1; a is 0; and Ar.sup.1, Ar.sup.2, and Ar.sup.3 have no additional amino substituents.

There is disclosed a compound having Formula I ##STR00001## In Formula, I: Ar.sup.1 is selected from the group consisting of dibenzofuran, dibenzothiophene, or deuterated analogs thereof; Ar.sup.2 and Ar.sup.3 are the same or different and are hydrocarbon aryl, substituted derivatives thereof, or deuterated analogs thereof, with the proviso that Ar.sup.2 and Ar.sup.3 are not the same as Ar.sup.1; a is 0; and Ar.sup.1, Ar.sup.2, and Ar.sup.3 have no additional amino substituents.

A compound of Formula I: ##STR00001##
wherein Y is O, S, or Se;
wherein each X.sup.1-X.sup.14 is independently C or N;
wherein two consecutive X.sup.1-X.sup.14 in the same ring are not N;
wherein any of X.sup.1-X.sup.14 is C when it forms a direct bond to R.sup.A, R.sup.B, R.sup.C, or R.sup.D;
wherein R.sup.A, R.sup.B, R.sup.C, and R.sup.D each independently represent mono to the maximum allowable substitution, or no substitution;
wherein each R.sup.A, R.sup.B, R.sup.C, and R.sup.D is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein R.sup.D represents mono to the maximum allowable substitution at least one R.sup.D is not hydrogen; and
wherein any two substituents are optionally joined or fused together to form a ring.

Provided are novel silyl-containing acetylacetonate derivatives compounds. Also provided are formulations comprising these silyl-containing acetylacetonate derivatives compounds. Further provided are OLEDs and related consumer products that utilize these silyl-containing acetylacetonate derivatives compounds.