Patent classifications
C08B1/08
METHOD FOR MANUFACTURING CARBOXYMETHYL CELLULOSE PARTICLES, CARBOXYMETHYL CELLULOSE PARTICLES MANUFACTURED THEREBY, AND ABSORBENT ARTICLE COMPRISING SAME
The present disclosure relates to a method for manufacturing carboxymethyl cellulose particles, cellulose inducer particles manufactured by the method, and an absorbent article comprising same. The method comprises: (1) a step of obtaining alkalized cellulose by reacting a cellulose raw material with an alkalizer; (2) a step of obtaining carboxymethyl cellulose by reacting the alkalized cellulose with a carboxy methylating agent; (3) a primary cross-linking step of obtaining a slurry-phase carboxymethyl cellulose cross-linked body by reacting the carboxymethyl cellulose with a core cross-linker; (4) a step of washing and dehydrating after filtering the slurry-phase carboxymethyl cellulose cross-linked body; (5) a secondary cross-linking step of obtaining carboxymethyl cellulose having a core-shell structure by reacting the carboxymethyl cellulose cross-linked body having undergone Step (4) with a surface cross-linker; and (6) a step of obtaining carboxymethyl cellulose particles having a core-shell structure by drying and pulverizing the carboxymethyl cellulose having a core-shell structure.
METHOD FOR MANUFACTURING CARBOXYMETHYL CELLULOSE PARTICLES, CARBOXYMETHYL CELLULOSE PARTICLES MANUFACTURED THEREBY, AND ABSORBENT ARTICLE COMPRISING SAME
The present disclosure relates to a method for manufacturing carboxymethyl cellulose particles, cellulose inducer particles manufactured by the method, and an absorbent article comprising same. The method comprises: (1) a step of obtaining alkalized cellulose by reacting a cellulose raw material with an alkalizer; (2) a step of obtaining carboxymethyl cellulose by reacting the alkalized cellulose with a carboxy methylating agent; (3) a primary cross-linking step of obtaining a slurry-phase carboxymethyl cellulose cross-linked body by reacting the carboxymethyl cellulose with a core cross-linker; (4) a step of washing and dehydrating after filtering the slurry-phase carboxymethyl cellulose cross-linked body; (5) a secondary cross-linking step of obtaining carboxymethyl cellulose having a core-shell structure by reacting the carboxymethyl cellulose cross-linked body having undergone Step (4) with a surface cross-linker; and (6) a step of obtaining carboxymethyl cellulose particles having a core-shell structure by drying and pulverizing the carboxymethyl cellulose having a core-shell structure.
HYDROXYALKYLALKYL CELLULOSE FOR TABLETING AND SOLID PREPARATION COMPRISING THE SAME
Provided are a hydroxyalkylalkyl cellulose excellent in formability and not causing marked delay in disintegration when added even in a small amount; a solid preparation including the hydroxyalkylalkyl cellulose; and a method for producing the solid preparation. More specifically, provided are a hydroxyalkylalkyl cellulose for tableting having a specific surface area of from 0.5 to 5.0 m.sup.2/g as measured by BET and a solid preparation including the hydroxyalkylalkyl cellulose. Also provided is a method for producing the hydroxyalkylalkyl cellulose for tableting, including the steps of: bringing pulp into contact with an alkali metal hydroxide solution to obtain an alkali cellulose, reacting the alkali cellulose with an etherifying agent to obtain a first hydroxyalkylalkyl cellulose, grinding the first hydroxyalkylalkyl cellulose, and subjecting the ground first hydroxyalkylalkyl cellulose to hydrolysis in the presence of an acid catalyst or oxidative degradation in the presence of an oxidant to obtain a second hydroxyalkylalkyl cellulose.
HYDROXYALKYLALKYL CELLULOSE FOR TABLETING AND SOLID PREPARATION COMPRISING THE SAME
Provided are a hydroxyalkylalkyl cellulose excellent in formability and not causing marked delay in disintegration when added even in a small amount; a solid preparation including the hydroxyalkylalkyl cellulose; and a method for producing the solid preparation. More specifically, provided are a hydroxyalkylalkyl cellulose for tableting having a specific surface area of from 0.5 to 5.0 m.sup.2/g as measured by BET and a solid preparation including the hydroxyalkylalkyl cellulose. Also provided is a method for producing the hydroxyalkylalkyl cellulose for tableting, including the steps of: bringing pulp into contact with an alkali metal hydroxide solution to obtain an alkali cellulose, reacting the alkali cellulose with an etherifying agent to obtain a first hydroxyalkylalkyl cellulose, grinding the first hydroxyalkylalkyl cellulose, and subjecting the ground first hydroxyalkylalkyl cellulose to hydrolysis in the presence of an acid catalyst or oxidative degradation in the presence of an oxidant to obtain a second hydroxyalkylalkyl cellulose.
Carboxymethylated cellulose
A carboxymethylated cellulose having a carboxymethyl substitution of no more than 0.50 and a cellulose I type crystallization of at least 50%. Ideally, the anionization is 0.00-1.00 meq/g. The Schopper-Riegler freeness is ideally at least 60.0° SR. Ideally the ratio of filtration residue is 0%-30% by mass. The viscosity (30 rpm, 25° C.) for an aqueous dispersion having a 1% solid content (w/v) is ideally no more than 10.0 mPa.Math.s.
Efficient methods and compositions for recovery of products from organic acid pretreatment of plant materials
Provided are compositions and processes concerning efficient downstream processing of products derived from organic acids pretreatment of plant materials.
Efficient methods and compositions for recovery of products from organic acid pretreatment of plant materials
Provided are compositions and processes concerning efficient downstream processing of products derived from organic acids pretreatment of plant materials.
CARBOXYMETHYLCELLULOSE OR SALT THEREOF FOR NONAQUEOUS ELECTROLYTE SECONDARY BATTERY
The present invention is aimed to provide carboxymethylcellulose or a salt thereof for a nonaqueous electrolyte secondary battery, an electrode composition containing the same for a nonaqueous electrolyte secondary battery, an electrode for a nonaqueous electrolyte secondary battery, and a nonaqueous electrolyte secondary battery, with a small reduction in the capacity even when charging and discharging are repeated, and with high durability. The carboxymethylcellulose or the salt thereof is used as a binder for an electrode of a nonaqueous electrolyte secondary battery, in which the degree of substitution with carboxymethyl of the carboxymethylcellulose or the salt thereof is 0.5 to 1.5, and a thermal rate of change T that is a difference (W.sub.B−W.sub.A) between a thermal weight reduction rate W.sub.A at a thermal decomposition start point and a thermal weight reduction rate W.sub.B at a thermal decomposition end point measured by a thermogravimetric-differential thermal analyzer is 45% or lower.
Carboxymethyl Cellulose and Method of Preparation
Provided is a method for producing a cellulose derivative. The method includes forming a first reaction product by reacting non-oxidized cellulose with at least one first alkalization agent in the presence of at least one suitable solvent, wherein the first reaction product includes a non-oxidized alkali-cellulose. The method further includes forming a second reaction product by reacting a monohalo-organic compound with a second alkalization agent in a solution, wherein the second reaction product includes a saturated solution and a sediment. The method further includes increasing a temperature of the saturated solution and dissolving at least a portion of the sediment, and reacting the non-oxidized alkali-cellulose with the second reaction product to form an improved carboxymethyl cellulose.
Carboxymethyl Cellulose and Method of Preparation
Provided is a method for producing a cellulose derivative. The method includes forming a first reaction product by reacting non-oxidized cellulose with at least one first alkalization agent in the presence of at least one suitable solvent, wherein the first reaction product includes a non-oxidized alkali-cellulose. The method further includes forming a second reaction product by reacting a monohalo-organic compound with a second alkalization agent in a solution, wherein the second reaction product includes a saturated solution and a sediment. The method further includes increasing a temperature of the saturated solution and dissolving at least a portion of the sediment, and reacting the non-oxidized alkali-cellulose with the second reaction product to form an improved carboxymethyl cellulose.