This cellulose acetate has a total degree of acetyl substitution of 1.75 or more and 2.55 or less, and a degree of acetyl substitution at 2-position or a degree of acetyl substitution at 3-position is 0.7 or less. This cellulose acetate composition includes the cellulose acetate and an additive. The additive is one or more selected from the group consisting of (a) substances of which a pH of a 1 wt. % aqueous solution at 20° C. is 8 or more, (b) substances that dissolve in water at 20° C. in an amount of 2 wt. % or more, and (c) substances that exhibit biodegradability in seawater.

Dry solids of anionically modified cellulose nanofibers with good redispersion are provided by incorporating 5 to 300% by mass of a water-soluble polymer relative to the anionically modified cellulose nanofibers during the preparation of the dry solids of anionically modified cellulose nanofibers.

Dry solids of anionically modified cellulose nanofibers with good redispersion are provided by incorporating 5 to 300% by mass of a water-soluble polymer relative to the anionically modified cellulose nanofibers during the preparation of the dry solids of anionically modified cellulose nanofibers.

This cellulose acetate has a total degree of acetyl substitution of 1.75 or more and 2.55 or less, and a degree of acetyl substitution at 2-position or a degree of acetyl substitution at 3-position is 0.7 or less. This cellulose acetate composition includes the cellulose acetate and an additive. The additive is one or more selected from the group consisting of (a) substances of which a pH of a 1 wt. % aqueous solution at 20° C. is 8 or more, (b) substances that dissolve in water at 20° C. in an amount of 2 wt. % or more, and (c) substances that exhibit biodegradability in seawater.

Provided is a method that enables industrially efficient production of an esterified polysaccharide product. A method for producing an esterified polysaccharide product, the method including reacting a polysaccharide-containing biomass, a basic ionic liquid with a pKa of a conjugate acid of an anion from 2 to 19 as a calculated value in a vacuum, and an esterifying agent using a kneader equipped with a shear force application mechanism. A cation constituting the basic ionic liquid is preferably one selected from the group consisting of an imidazolium cation, a pyridinium cation, and a tetraalkylammonium cation.

Provided is a method that enables industrially efficient production of an esterified polysaccharide product. A method for producing an esterified polysaccharide product, the method including reacting a polysaccharide-containing biomass, a basic ionic liquid with a pKa of a conjugate acid of an anion from 2 to 19 as a calculated value in a vacuum, and an esterifying agent using a kneader equipped with a shear force application mechanism. A cation constituting the basic ionic liquid is preferably one selected from the group consisting of an imidazolium cation, a pyridinium cation, and a tetraalkylammonium cation.

An object of the present invention is to provide fine particles excellent in biodegradability and touch feeling. Disclosed are cellulose acetate particles, the cellulose acetate particles have an average particle size of 80 nm or more and 100 μm or less, a sphericity of 0.7 or more and 1.0 or less, and a surface smoothness of 80% or more and 100% or less, and the cellulose acetate has a total degree of acetyl substitution of 0.7 or more and 2.9 or less.

A shaped article comprising a polymer-based resin derived from cellulose, wherein the polymer-based resin has an HDT of at least 95° C., a bio-derived content of at least 20 wt %, a notched izod impact strength of greater than 80 J/m and at least one of the following properties chosen from: flexural modulus of greater than 1900 MPa; a spiral flow length or at least 3.0 cm; a flex creep deflection of less than 12 mm; a transmission of at least 70%; a ΔE value of less than 25; or an L* color of at least 85.

A shaped article comprising a polymer-based resin derived from cellulose, wherein the polymer-based resin has an HDT of at least 95° C., a bio-derived content of at least 20 wt %, a notched izod impact strength of greater than 80 J/m and at least one of the following properties chosen from: flexural modulus of greater than 1900 MPa; a spiral flow length or at least 3.0 cm; a flex creep deflection of less than 12 mm; a transmission of at least 70%; a ΔE value of less than 25; or an L* color of at least 85.

The present application discloses regioselectively substituted cellulose esters, films made from the regioselectively substituted cellulose esters and methods for making the same. The regioselectively substituted cellulose esters are synthesized using trifluoroacetic anhydride and cellulose with various acyl donors or acyl donor precursors.