The present invention provides a novel process for subjecting a diene-based-polymer to a metathesis reaction in a first step and a selective hydrogenation of the carbon-carbon double bonds present in such diene-based polymers in a second step using a ruthenium or osmium based complex catalyst, wherein the diene-based polymer is present in latex form, this means as a suspension of diene-based polymer particles in an aqueous medium.

The present invention provides a novel process for subjecting a diene-based-polymer to a metathesis reaction in a first step and a selective hydrogenation of the carbon-carbon double bonds present in such diene-based polymers in a second step using a ruthenium or osmium based complex catalyst, wherein the diene-based polymer is present in latex form, this means as a suspension of diene-based polymer particles in an aqueous medium.

The present invention provides a pneumatic tire having well-improved rubber tensile strength and abrasion resistance while maintaining or improving good fuel economy. The present invention relates to a pneumatic tire formed from a rubber composition, the rubber composition containing: a hydrogenated copolymer obtained by copolymerization of an aromatic vinyl compound and a conjugated diene compound, the hydrogenated copolymer having a degree of hydrogenation of the conjugated diene units of 75 mol % or more; carbon black; and silica, the rubber composition containing, per 100% by mass of the rubber component, 75% by mass or more of the hydrogenated copolymer, the rubber composition containing, relative to 100 parts by mass of the rubber component, 3 parts by mass or more of the carbon black and 1 to 200 parts by mass of the silica.

The present invention provides a pneumatic tire having improved rubber tensile strength, abrasion resistance, and wet-grip performance while maintaining good fuel economy. The present invention relates to a pneumatic tire containing: a hydrogenated copolymer obtained by copolymerization of an aromatic vinyl compound and a conjugated diene compound, the hydrogenated copolymer having a degree of hydrogenation of the conjugated diene units of 75 mol % or more; and a resin having a softening point of 60° C. to 120° C., the rubber composition containing, per 100% by mass of a rubber component, 75% by mass or more of the hydrogenated copolymer, the rubber composition containing, relative to 100 parts by mass of the rubber component, 1 to 30 parts by mass of the resin.

It is an object of the present invention to provide a method for producing a terminal-modified polybutadiene or terminal-modified hydrogenated polybutadiene that does not become colored or white and turbid, without using an organotin compound. The production method of the present invention includes reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organoaluminum compound and an organozinc compound (with the proviso that zinc naphthenate is excluded). ##STR00001##

It is an object of the present invention to provide a method for producing a terminal-modified polybutadiene or terminal-modified hydrogenated polybutadiene that does not become colored or white and turbid, without using an organotin compound. The production method of the present invention includes reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organoaluminum compound and an organozinc compound (with the proviso that zinc naphthenate is excluded). ##STR00001##

The present invention relates to a process for preparing solutions of hydrogenated nitrile-diene copolymer, wherein the nitrile-diene copolymer dissolved in an ether-containing or ketone-containing solvent mixture is subjected to hydrogenation conditions. The invention further relates to solutions of hydrogenated nitrile-diene copolymer (HNBR solutions) comprising CPME as solvent, and to the use of HNBR solutions in CPME-containing solvent mixtures as binder in electrodes.

The present invention relates to a process for preparing solutions of hydrogenated nitrile-diene copolymer, wherein the nitrile-diene copolymer dissolved in an ether-containing or ketone-containing solvent mixture is subjected to hydrogenation conditions. The invention further relates to solutions of hydrogenated nitrile-diene copolymer (HNBR solutions) comprising CPME as solvent, and to the use of HNBR solutions in CPME-containing solvent mixtures as binder in electrodes.

A molded bale of a rubber composition, containing: a rubber-like polymer (A) having an iodine value of 10 to 250, 3% by mass or more of an ethylene structure, and less than 10% by mass of a vinyl aromatic monomer block; and titanium (C), in which a content of the titanium (C) is 3 ppm or more and 120 ppm or less, and a content of aluminum (B) is less than 2 ppm.

An object of the present invention is to obtain a molded bale of a rubber composition that is difficult to cold flow and difficult to be thermally deteriorated. The present invention provides a molded bale of a rubber composition containing: a rubber-like polymer (A) having an iodine value of 10 to 250, 3% by mass or more of an ethylene structure, and less than 10% by mass of a vinyl aromatic monomer block; and aluminum (B), in which a content of the aluminum (B) is 2 ppm or more and 200 ppm or less.