Patent classifications
C08C19/22
RUBBER COMPOSITION FOR A TIRE TREAD
A tire exhibits an improved performance compromise, the tread of which comprises a rubber composition based on an elastomeric matrix comprising from 25 to 95 parts by weight per hundred parts by weight of elastomer, phr, of copolymer based on butadiene and on styrene having a glass transition temperature of less than −70° C., and from 5 to 75 phr of polybutadiene, the elastomeric matrix comprising less than 15 phr of isoprene elastomer; at least one reinforcing filler; from 25 to 100 phr of at least one plasticizing resin having a glass transition temperature of greater than 20° C.; and a vulcanization system.
RUBBER COMPOSITION FOR A TIRE TREAD
A tire exhibits an improved performance compromise, the tread of which comprises a rubber composition based on an elastomeric matrix comprising from 25 to 95 parts by weight per hundred parts by weight of elastomer, phr, of copolymer based on butadiene and on styrene having a glass transition temperature of less than −70° C., and from 5 to 75 phr of polybutadiene, the elastomeric matrix comprising less than 15 phr of isoprene elastomer; at least one reinforcing filler; from 25 to 100 phr of at least one plasticizing resin having a glass transition temperature of greater than 20° C.; and a vulcanization system.
OIL-EXTENDED MODIFIED CONJUGATED DIENE-BASED POLYMER, METHOD FOR PREPARING SAME AND RUBBER COMPOSITION COMPRISING SAME
The present invention relates to an oil-extended modified conjugated diene-based polymer having excellent tensile properties and abrasion resistance, a method for preparing same and a rubber composition including same, and provides an oil-extended modified conjugated diene-based polymer including a modified polymer chain including a repeating unit derived from a conjugated diene-based monomer and a functional group derived from an aminoalkoxysilane-based modifier; and a derived unit from a vegetable oil, wherein at least one of the modified polymer chain is coupled with the derived unit from vegetable oil, N and Si atoms are included in 100 ppm or more each based on a total weight of the polymer, two glass transition temperatures of Tg1 and Tg2 measured by differential scanning calorimetry (DSC) are shown, Tg1 is −80° C. to −20° C., Tg2 is −50° C. to 30° C., and Tg2 is higher than Tg1, a method for preparing same and a rubber composition including same.
Nitrile group-containing copolymer rubber
A nitrile group-containing copolymer rubber including 10 to 60 wt % of an α,β-ethylenically unsaturated nitrile monomer unit and 1 to 60 wt % of an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and having an iodine value of 120 or less, wherein a processability index Ipro (Ipro=CC×SA) is 0.0030 or less, where the processability index Ipro is the product of the carboxyl group content CC, which is the number of moles of carboxyl groups per 100 g of nitrile group-containing copolymer rubber, and the absorbance area SA of a carboxylic anhydride group determined by infrared spectroscopy.
Nitrile group-containing copolymer rubber
A nitrile group-containing copolymer rubber including 10 to 60 wt % of an α,β-ethylenically unsaturated nitrile monomer unit and 1 to 60 wt % of an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and having an iodine value of 120 or less, wherein a processability index Ipro (Ipro=CC×SA) is 0.0030 or less, where the processability index Ipro is the product of the carboxyl group content CC, which is the number of moles of carboxyl groups per 100 g of nitrile group-containing copolymer rubber, and the absorbance area SA of a carboxylic anhydride group determined by infrared spectroscopy.
BINDER FOR ALL-SOLID SECONDARY BATTERY, BINDER COMPOSITION FOR ALL-SOLID SECONDARY BATTERY, SLURRY FOR ALL-SOLID SECONDARY BATTERY, SOLID ELECTROLYTE SHEET FOR ALL-SOLID SECONDARY BATTERY AND PRODUCTION METHOD THEREOF, AND ALL-SOLID SECONDARY BATTERY AND PRODUCTION METHOD THEREOF
A binder for an all-solid-state secondary battery, including a polymer (A) that has an aromatic vinyl unit including an aromatic vinyl compound and a conjugated diene unit including a conjugated diene compound. The binder has a Mooney viscosity (ML.sub.1+4, 100° C.) from 10 to 100 and has a value α, which is represented by the following equation (i), of less than 0.7, where “p”, “q”, “r”, and “s” represent constituent ratios (molar ratios) of a structural unit represented by the following formula (1), a structural unit represented by the following formula (2), a structural unit represented by the following formula (3), and a structural unit represented by the following formula (4) in the polymer, respectively. α=(p+(0.5×r))/(p+q+(0.5×r)+s) • • • (i)
##STR00001##
##STR00002##
Oil-Extended Conjugated Diene-Based Polymer and Rubber Composition Comprising the Same
The present invention relates to an oil-extended conjugated diene-based polymer or an oil-extended modified conjugated diene-based polymer, which has excellent wet skid resistance and abrasion resistance in a balanced way, and a rubber composition including the same, and by controlling the microstructure of the polymer such that a full width at half maximum (FWHM) value of a tan δ peak shown in a temperature range of -100° C. to 100° C. becomes 20° C. or higher in a tan δ graph in accordance with temperature, derived from dynamic viscoelasticity analysis by an Advanced Rheometric Expansion System (ARES), and by including a vegetable oil in a polymer, excellent viscoelasticity behavior properties may be shown, and accordingly, the improvement of overall physical properties may be expected.
Oil-Extended Conjugated Diene-Based Polymer and Rubber Composition Comprising the Same
The present invention relates to an oil-extended conjugated diene-based polymer or an oil-extended modified conjugated diene-based polymer, which has excellent wet skid resistance and abrasion resistance in a balanced way, and a rubber composition including the same, and by controlling the microstructure of the polymer such that a full width at half maximum (FWHM) value of a tan δ peak shown in a temperature range of -100° C. to 100° C. becomes 20° C. or higher in a tan δ graph in accordance with temperature, derived from dynamic viscoelasticity analysis by an Advanced Rheometric Expansion System (ARES), and by including a vegetable oil in a polymer, excellent viscoelasticity behavior properties may be shown, and accordingly, the improvement of overall physical properties may be expected.
Modified natural rubber, rubber composition using the rubber, and pneumatic tire using the composition
A modified natural rubber has a branching degree of 0.40 to 0.70 and includes a linking structure represented by formula (C), the linking structure having been formed by allowing polyisoprene, having a structure represented by formula (A) and/or formula (B), to bind in the structure to an amino compound having two or more primary amino groups: ##STR00001##
wherein X represents a hydrogen atom or a methyl group, and Ps, which may be the same or different from each other, represent a polyisoprene unit;
W-(Q).sub.m (C)
wherein W represents a residue obtained by removing amino end groups from the amino compound Q represents at least one selected from the group consisting of the following general formulae (Q-1) to (Q-4), and m represents 2 to 4; ##STR00002##
wherein *.sup.1 indicates binding to a carbon atom of a polyisoprene unit, and *.sup.2 indicates binding to a carbon atom of the residue represented by W.
PNEUMATIC TIRE
A pneumatic tire includes: a rubber member A containing a rubber component containing 70 mass % to 100 mass % of a hydrogenated copolymer, sulfur, and a triazine-thiol compound; and a rubber member B containing sulfur and a rubber component containing a diene rubber. The hydrogenated copolymer is obtained by hydrogenating an aromatic vinyl-conjugated diene copolymer, has a weight average molecular weight of 300,000 or more as measured by gel permeation chromatography, and has a hydrogenation rate of a conjugated diene moiety of 80 mol % or more, the rubber member A and the rubber member B are in contact with each other at an interface, and a content of the triazine-thiol compound is 0.1 parts by mass to 5 parts by mass with respect to 100 parts by mass of the rubber component in the rubber member A.