Provided are a method of preparing a vinyl chloride-based polymer composite, a vinyl chloride-based polymer composite, and a vinyl chloride-based polymer composite composition including the composite, the method including: a first step of performing bulk polymerization of vinyl chloride-based monomers; and a second step of recovering unreacted vinyl chloride-based monomers after the completion of the bulk polymerization and obtaining a vinyl chloride-based polymer composite, wherein polyvinyl alcohol is added in at least one step of the first step and the second step, and the polyvinyl alcohol is added in an amount of 0.003 parts by weight to 0.500 parts by weight based on a total of 100 parts by weight of the vinyl chloride-based monomers.

Provided are a method of preparing a vinyl chloride-based polymer composite, a vinyl chloride-based polymer composite, and a vinyl chloride-based polymer composite composition including the composite, the method including: a first step of performing bulk polymerization of vinyl chloride-based monomers; and a second step of recovering unreacted vinyl chloride-based monomers after the completion of the bulk polymerization and obtaining a vinyl chloride-based polymer composite, wherein polyvinyl alcohol is added in at least one step of the first step and the second step, and the polyvinyl alcohol is added in an amount of 0.003 parts by weight to 0.500 parts by weight based on a total of 100 parts by weight of the vinyl chloride-based monomers.

Provided is a solid catalyst component for olefin polymerization which is capable of exerting favorable ethylene responsiveness while forming a propylene homopolymer having high stereoregularity, when subjected to ethylene-propylene copolymerization reaction. The present invention provides a solid catalyst component for olefin polymerization, comprising titanium, magnesium, halogen, and an internal electron-donating compound, wherein the internal electron-donating compound comprises an electron-donating compound (i) having a phthalic acid ester structure, and an electron-donating compound (ii) having two or more kinds of groups selected from an ether group, an ester group and a carbonate group and having no phthalic acid ester structure, wherein a content ratio of the electron-donating compound (ii) having two or more kinds of groups selected from an ether group, an ester group and a carbonate group and having no phthalic acid ester structure is 0.5 to 1.5% by mass.

Provided is a solid catalyst component for olefin polymerization which is capable of exerting favorable ethylene responsiveness while forming a propylene homopolymer having high stereoregularity, when subjected to ethylene-propylene copolymerization reaction. The present invention provides a solid catalyst component for olefin polymerization, comprising titanium, magnesium, halogen, and an internal electron-donating compound, wherein the internal electron-donating compound comprises an electron-donating compound (i) having a phthalic acid ester structure, and an electron-donating compound (ii) having two or more kinds of groups selected from an ether group, an ester group and a carbonate group and having no phthalic acid ester structure, wherein a content ratio of the electron-donating compound (ii) having two or more kinds of groups selected from an ether group, an ester group and a carbonate group and having no phthalic acid ester structure is 0.5 to 1.5% by mass.

A catalyst compound and process for olefin polymerization. The catalyst can be represented by Formula (I):

##STR00001##

wherein: M is a transition metal selected from group 3, 4, or 5 of the Periodic Table of Elements; L is a linking group selected from any one or more difunctional C.sub.1-C.sub.20 hydrocarbyl, aryl or substituted aryl groups; T is an optional bridging group; each X is a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; R.sup.1 and R.sup.2 are each independently a hydrogen atom or substituted or unsubstituted C.sub.1 to C.sub.20 hydrocarbyl group; R.sup.3, R.sup.5, R.sup.6 and R.sup.7 are each independently a hydrogen atom or a substituted or unsubstituted C.sub.1 to C.sub.20 hydrocarbyl group, and, optionally, any two of R.sup.5, R.sup.6, and R.sup.7 can be joined to form a cyclic structure; R.sup.4 is a substituted or unsubstituted aryl group; and R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently a substituted or unsubstituted C.sub.1 to C.sub.6 hydrocarbyl group and, optionally, R.sup.9 and R.sup.10 are joined to form a cyclic structure.

A catalyst compound and process for olefin polymerization. The catalyst can be represented by Formula (I):

##STR00001##

wherein: M is a transition metal selected from group 3, 4, or 5 of the Periodic Table of Elements; L is a linking group selected from any one or more difunctional C.sub.1-C.sub.20 hydrocarbyl, aryl or substituted aryl groups; T is an optional bridging group; each X is a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; R.sup.1 and R.sup.2 are each independently a hydrogen atom or substituted or unsubstituted C.sub.1 to C.sub.20 hydrocarbyl group; R.sup.3, R.sup.5, R.sup.6 and R.sup.7 are each independently a hydrogen atom or a substituted or unsubstituted C.sub.1 to C.sub.20 hydrocarbyl group, and, optionally, any two of R.sup.5, R.sup.6, and R.sup.7 can be joined to form a cyclic structure; R.sup.4 is a substituted or unsubstituted aryl group; and R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently a substituted or unsubstituted C.sub.1 to C.sub.6 hydrocarbyl group and, optionally, R.sup.9 and R.sup.10 are joined to form a cyclic structure.

The present disclosure relates to compositions comprising a copolymer derived from a vinyl aromatic monomer, a (meth)acrylate monomer, an acid monomer, and a copolymerizable surfactant and compositions comprising the same. The (meth)acrylate monomer can be selected from a monomer having a theoretical glass transition temperature (Tg) for its corresponding homopolymer of 0° C. or less or a hydrophobic (meth)acrylate monomer. In some embodiments, the copolymer is further derived from an organosilane. The copolymers can have a theoretical glass transition temperature (Tg) from −60° C. to 80° C. and a number average particle size of 250 nm or less. The compositions can be used to prepare compositions such as coatings that have improved water resistance, blush resistance, and/or resistance to hydrostatic pressures. Methods of making the copolymers are also provided.

New polypropylene composition which combines low sealing initiation temperature (SIT), high hot-tack and good mechanical properties, like high dart drop strength (DDI), and its use especially for film applications.

New polypropylene composition which combines low sealing initiation temperature (SIT), high hot-tack and good mechanical properties, like high dart drop strength (DDI), and its use especially for film applications.

Disclosed is a polypropylene with an MFR of at least 20 g/10 min comprising a homopolypropylene and within a range from 2 wt % to 20 wt % of a propylene-α-olefin copolymer by weight of the polypropylene, where the homopolypropylene has a MFR within a range from 30 g/10 min to 200 g/10 min, where the propylene-α-olefin copolymer comprises within a range from 30 wt % to 50 wt % α-olefin derived units by weight of the propylene-α-olefin copolymer, and has an IV within a range from 4 to 9 dL/g. The polypropylene may be obtained by combining a Ziegler-Natta catalyst having two transition metals with propylene in reactors in series to produce the homopolypropylene followed by a gas phase reactor to produce a propylene-α-olefin copolymer blended with the homopolypropylene.