Disclosed are a method of preparing a modified conjugated diene-based polymer, a modified conjugated diene-based polymer prepared thereby, a rubber composition including the modified conjugated diene-based polymer, and a tire including the rubber composition. The method of preparing the modified conjugated diene-based polymer includes (a) polymerizing a vinyl aromatic monomer and a conjugated diene monomer through continuous solution polymerization using a multifunctional anionic polymerization initiator in the presence of a hydrocarbon solvent, thus forming an active polymer having a reactive end; and (b) coupling or linking the reactive end of the active polymer with an alkylamino alkoxy silane compound.

Disclosed are a method of preparing a modified conjugated diene-based polymer, a modified conjugated diene-based polymer prepared thereby, a rubber composition including the modified conjugated diene-based polymer, and a tire including the rubber composition. The method of preparing the modified conjugated diene-based polymer includes (a) polymerizing a vinyl aromatic monomer and a conjugated diene monomer through continuous solution polymerization using a multifunctional anionic polymerization initiator in the presence of a hydrocarbon solvent, thus forming an active polymer having a reactive end; and (b) coupling or linking the reactive end of the active polymer with an alkylamino alkoxy silane compound.

The present invention provides a method for the preparation of thin film composite (TFC) membranes, preferably solvent resistant TFC membranes, by interracial polymerization (IFP), more in particular solvent resistant TFC membranes wherein a thin PA-layer is deposited on a porous support membrane. Said method comprises the replacement of the aqueous and/or the organic solvent in the IFP method by an ionic liquid (IL) as solvent for the monomers which form said TFC membranes, to alter the top layer morphology, thickness and crosslinking degree.

The present invention provides a method for the preparation of thin film composite (TFC) membranes, preferably solvent resistant TFC membranes, by interracial polymerization (IFP), more in particular solvent resistant TFC membranes wherein a thin PA-layer is deposited on a porous support membrane. Said method comprises the replacement of the aqueous and/or the organic solvent in the IFP method by an ionic liquid (IL) as solvent for the monomers which form said TFC membranes, to alter the top layer morphology, thickness and crosslinking degree.

The invention provides a process to form a composition comprising at least one ethylene-based polymer and at least one oil, said process comprising the following: polymerizing a mixture comprising ethylene, and optionally one or more comonomers, in a reactor system, comprising at least one reactor and at least one mixer, located downstream from the reactor, to form the ethylene-based polymer; and wherein the oil is added to the ethylene-based polymer upstream of the mixer. The invention also provides a reactor system for a process to form a composition comprising at least one ethylene-based polymer and at least one oil, said reactor system comprising at least one reactor, at least one mixer, and an oil feed into the ethylene-based polymer, and wherein the oil feed is located after the reactor and before the mixer.

The present disclosure is directed towards a solution or bulk polymerization process for preparing high-cis polydienes that utilizes at least one vinyl aromatic compound as a molecular weight regulator. The disclosed solution or bulk polymerization processes are useful for preparing high-cis polydienes with a Mooney viscosity between 30 and 55 while allowing the use of lower amounts of catalyst.

The present disclosure is directed towards a solution or bulk polymerization process for preparing high-cis polydienes that utilizes at least one vinyl aromatic compound as a molecular weight regulator. The disclosed solution or bulk polymerization processes are useful for preparing high-cis polydienes with a Mooney viscosity between 30 and 55 while allowing the use of lower amounts of catalyst.

A radical polymerization method that enables synthesis, at a high conversion rate, of polymers having a relatively uniform molecular weight and is applicable to various monomers, and an apparatus used for the method. A reaction solution containing monomer and initiator is continuously or intermittently circulated in the apparatus and is heated in a heating-initiation unit to a predetermined temperature simultaneously across a radial direction of a cross section of the flow path whereby the initiator located in a particular volume of the reaction solution is cleaved all at once. The apparatus includes a heating medium production unit 10, a heating medium-reaction solution mixing unit 20, a cooling unit 30, and a recovery unit 40 for a reaction mixture, all communicatively connected by the flow path and optionally a heating reaction unit 60, a cooling unit 70, and a recovery unit 80, all communicatively connected by the flow path.

A method for the control of a plant (10) for the production in continuous of a polymer, wherein the plant (10) comprises at least one reactor (11) fed with at least a first monomer and a second monomer, a first stripper (12), a second stripper (17), a third stripper (18), at least one recycling vat (13) of the fine products, measurement equipment (14) and a control system comprising distributed control devices (15) controllable by at least one electronic processing and control unit (16) based on a plurality of control variables, the control method comprising the following steps: collecting data comprising recipe parameters, laboratory analysis results and predefined coefficients stored in a database (40); collecting the data measured by the measurement equipment (14); determining, by means of a first calculation module (20) a production potentiality value of the at least one reactor (11); determining, by means of a second calculation module (21) the polymer concentration in the at least one reactor (11), in the first stripper (12) and in the at least one recycling vat of the fine products (13); determining, by means of a third calculation module (22) the flow-rate of oil for feeding the second stripper (17); determining, by means of a fourth calculation module (23), the flow-rate of the chain terminator (TERM) for feeding the at least one reactor (11), controlling the plant (10) on the basis of the plurality of control variables.

A method for the control of a plant (10) for the production in continuous of a polymer, wherein the plant (10) comprises at least one reactor (11) fed with at least a first monomer and a second monomer, a first stripper (12), a second stripper (17), a third stripper (18), at least one recycling vat (13) of the fine products, measurement equipment (14) and a control system comprising distributed control devices (15) controllable by at least one electronic processing and control unit (16) based on a plurality of control variables, the control method comprising the following steps: collecting data comprising recipe parameters, laboratory analysis results and predefined coefficients stored in a database (40); collecting the data measured by the measurement equipment (14); determining, by means of a first calculation module (20) a production potentiality value of the at least one reactor (11); determining, by means of a second calculation module (21) the polymer concentration in the at least one reactor (11), in the first stripper (12) and in the at least one recycling vat of the fine products (13); determining, by means of a third calculation module (22) the flow-rate of oil for feeding the second stripper (17); determining, by means of a fourth calculation module (23), the flow-rate of the chain terminator (TERM) for feeding the at least one reactor (11), controlling the plant (10) on the basis of the plurality of control variables.