Provided are a method for preparing a graft copolymer and a graft copolymer prepared thereby, the method comprising: preparing a reaction solution comprising a copolymer comprising a unit derived from a diene-based monomer and a unit derived from an alkene-based monomer, an aromatic vinyl-based monomer, a vinyl cyan-based monomer, and a reaction solvent; and adding the reaction solution to perform primary bulk polymerization at 100 to 110° C., wherein the copolymer comprises the unit derived from a diene-based monomer in an amount of 5 to 10 wt %, and the graft copolymer has an average rubber particle size of 2 to 5μm.

Provided are a method for preparing a graft copolymer and a graft copolymer prepared thereby, the method comprising: preparing a reaction solution comprising a copolymer comprising a unit derived from a diene-based monomer and a unit derived from an alkene-based monomer, an aromatic vinyl-based monomer, a vinyl cyan-based monomer, and a reaction solvent; and adding the reaction solution to perform primary bulk polymerization at 100 to 110° C., wherein the copolymer comprises the unit derived from a diene-based monomer in an amount of 5 to 10 wt %, and the graft copolymer has an average rubber particle size of 2 to 5μm.

The present invention relates to ophthalmic lenses comprising an oxazolone, a preparation method thereof and the use of an oxazolone in an ophthalmic lens to absorb blue light.

The present invention relates to ophthalmic lenses comprising an oxazolone, a preparation method thereof and the use of an oxazolone in an ophthalmic lens to absorb blue light.

To provide an electrolyte material which has a high proton conductivity and which is excellent in hot water resistance.

An electrolyte material which is formed of a polymer H having units represented by the formula u1 and units based on tetrafluoroethylene, wherein the polymer H has an equivalent weight EW of from 400 to 550 g/eq, and the mass reduction ratio when immersed in hot water at 120° C. for 24 hours is at most 15 mass %:

##STR00001##

wherein Q.sup.11 is a perfluoroalkylene group which may have an etheric oxygen atom, Q.sup.12 is a single bond or a perfluoroalkylene group which may have an etheric oxygen atom, Y.sup.1 is a fluorine atom or the like, s is 0 or 1, R.sup.f1 is a perfluoroalkyl group which may have an etheric oxygen atom, X.sup.1 is an oxygen atom or the like, a is 0 when X.sup.1 is an oxygen atom, and Z.sup.+ is H.sup.+ or the like.

To provide an electrolyte material which has a high proton conductivity and which is excellent in hot water resistance.

An electrolyte material which is formed of a polymer H having units represented by the formula u1 and units based on tetrafluoroethylene, wherein the polymer H has an equivalent weight EW of from 400 to 550 g/eq, and the mass reduction ratio when immersed in hot water at 120° C. for 24 hours is at most 15 mass %:

##STR00001##

wherein Q.sup.11 is a perfluoroalkylene group which may have an etheric oxygen atom, Q.sup.12 is a single bond or a perfluoroalkylene group which may have an etheric oxygen atom, Y.sup.1 is a fluorine atom or the like, s is 0 or 1, R.sup.f1 is a perfluoroalkyl group which may have an etheric oxygen atom, X.sup.1 is an oxygen atom or the like, a is 0 when X.sup.1 is an oxygen atom, and Z.sup.+ is H.sup.+ or the like.

A curable, partially hydrogenated butadiene polymer having a hydrogenation degree from 0.5 to 55% and having a total amount of butadiene-derived vinyl groups according to the general formula (I)

##STR00001##

and trans groups of the general formula (II)

##STR00002##

of from 0% to 9% by weight based on the total weight of the polymer and wherein the partially hydrogenated polybutadiene polymer is a butadiene polymer comprising at least 50% by weight based on the total weight of the polymer which is 100%, of units derived from 1,3-butadiene. Also provided are a process to make the polymer, compositions containing the polymer and articles obtained by using the polymer.

A curable, partially hydrogenated butadiene polymer having a hydrogenation degree from 0.5 to 55% and having a total amount of butadiene-derived vinyl groups according to the general formula (I)

##STR00001##

and trans groups of the general formula (II)

##STR00002##

of from 0% to 9% by weight based on the total weight of the polymer and wherein the partially hydrogenated polybutadiene polymer is a butadiene polymer comprising at least 50% by weight based on the total weight of the polymer which is 100%, of units derived from 1,3-butadiene. Also provided are a process to make the polymer, compositions containing the polymer and articles obtained by using the polymer.

Provided are a novel metallocene-supported catalyst and a method of preparing a polyolefin using the same. The metallocene-supported catalyst according to the present disclosure may be used in the preparation of polyolefins, it may have excellent activity and excellent reactivity with comonomers, and it may prepare olefinic polymers having a high molecular weight and a low molecular weight.

The various embodiments provide, a magnesium titanium polymerization procatalyst, and methods for making and using the same.