A method of forming a microphase separated block copolymer includes exposing a block copolymer to acid vapor under conditions effective to provide the microphase separated block copolymer. The block copolymer includes a first hydrophobic block and a second hydrophobic block that is acid-sensitive. The microphase separated block copolymer includes the first hydrophobic block and a hydrophilic block derived from the second hydrophobic block. Exposing the block copolymer to the acid vapor is conducted in the solid state.

A method of manufacturing fluoropolymer micropowders with low perfluoroalkyl species (PFAS) content, such as perfluorooctanoic acid (PFOA). The method includes thermally treating, at a temperature from 125 C. to 300 C. Ma substantially oxygen free atmosphere and/or in a fluidized bed reactor, an irradiated or thermally degraded perfluorinated fluoropolymer. The method may also include micronizing the thermally treated low molecular weight fluoropolymer intermediate to provide a micropowder.

A method of manufacturing fluoropolymer micropowders with low perfluoroalkyl species (PFAS) content, such as perfluorooctanoic acid (PFOA). The method includes thermally treating, at a temperature from 125 C. to 300 C. Ma substantially oxygen free atmosphere and/or in a fluidized bed reactor, an irradiated or thermally degraded perfluorinated fluoropolymer. The method may also include micronizing the thermally treated low molecular weight fluoropolymer intermediate to provide a micropowder.

A process to form a polymer composition comprising an ethylene-based polymer and a functionalized ethylene-based polymer, said process comprising the steps described herein, which include passing a polymer melt through at least one static mixer, and wherein the functionalized ethylene-based polymer, in melt form, is introduced into the polymer melt, before the polymer melt enters the static mixer.

An extrusion dryer for a rubbery polymer includes a cylinder equipped with a hopper for injection of the rubbery polymer at one end and a die at the other end. A screw is rotatably arranged inside of the cylinder, the screw having a shaft and a spiral flight formed on an outer surface of the shaft. The shaft includes multiple zones, each including a conveyance section and a compression section. In the zone closest to the die, the outer diameter of the shaft at the conveyance section is smaller than the outer diameter at the compression section.

An extrusion dryer for a rubbery polymer includes a cylinder equipped with a hopper for injection of the rubbery polymer at one end and a die at the other end. A screw is rotatably arranged inside of the cylinder, the screw having a shaft and a spiral flight formed on an outer surface of the shaft. The shaft includes multiple zones, each including a conveyance section and a compression section. In the zone closest to the die, the outer diameter of the shaft at the conveyance section is smaller than the outer diameter at the compression section.

A method of forming a microphase separated block copolymer includes exposing a block copolymer to acid vapor under conditions effective to provide the microphase separated block copolymer. The block copolymer includes a first hydrophobic block and a second hydrophobic block that is acid-sensitive. The microphase separated block copolymer includes the first hydrophobic block and a hydrophilic block derived from the second hydrophobic block. Exposing the block copolymer to the acid vapor is conducted in the solid state.

A method of forming a microphase separated block copolymer includes exposing a block copolymer to acid vapor under conditions effective to provide the microphase separated block copolymer. The block copolymer includes a first hydrophobic block and a second hydrophobic block that is acid-sensitive. The microphase separated block copolymer includes the first hydrophobic block and a hydrophilic block derived from the second hydrophobic block. Exposing the block copolymer to the acid vapor is conducted in the solid state.

A method of forming a microphase separated block copolymer includes exposing a block copolymer to acid vapor under conditions effective to provide the microphase separated block copolymer. The block copolymer includes a first hydrophobic block and a second hydrophobic block that is acid-sensitive. The microphase separated block copolymer includes the first hydrophobic block and a hydrophilic block derived from the second hydrophobic block. Exposing the block copolymer to the acid vapor is conducted in the solid state.

A process of manufacturing a polyolefin drag reducing agent comprises: injecting a catalyst and a drag reducing agent forming component comprising (i) at least one olefin monomer, or (ii) at least one olefin oligomer, or a combination of (i) and (ii) into a temporary container comprising a container material, sealing the temporary container; allowing the drag reducing agent forming component to polymerize in the sealed temporary container to form the polyolefin drag reducing agent; and at least partially dissolving the container material. The container material includes an ethylene vinyl acetate copolymer, an ethylene vinyl alcohol copolymer, a polyvinylpyrrolidone, an ethylene vinylpyrrolidone copolymer, a vinylpyrrolidone vinyl acetate copolymer, a polyvinyl acetate, a polyvinyl alcohol, a polyethylene glycol, a polysaccharide or its derivative, or a combination comprising at least one of the foregoing, provided that when the container material comprises polyvinyl acetate or polyvinyl alcohol, the temporary container is coated or has two or more layers.