Disclosed is a support material for a fused deposition modeling. The support material has excellent adhesion to a variety of model materials and is easily dissolved and removed by washing with water. Also, the waste liquid (PVA-based aqueous solution) generated after the washing operation may be allowed to be drained as it is, in compliance with environmental regulations. The support material comprises (A) PVA-based resin having a group containing sulfonic acid or a salt thereof and (B) biodegradable polyester. The (A) PVA-based resin having a group containing sulfonic acid or a salt thereof and (B) biodegradable polyester have a sea-island structure in which one is dispersed in the other as a matrix.

A block copolymer (A) including a vinyl alcohol-based polymer block (b) and an ionic polymer block (c) containing a monomer unit with an ionic group forming a salt and a vinyl alcohol-based monomer unit. The ionic group is a carboxylic acid group, a sulfonic acid group, or an ammonium group. The vinyl alcohol-based polymer block (b) has a number-average molecular weight (Mn.sub.b) from 15,000 to 220,000. The ionic polymer block (c) has a content of the vinyl alcohol-based monomer unit from 5 to 95 mol % based on the total monomer units. The block copolymer (A) has a number-average molecular weight (Mn.sub.A) from 20,000 to 440,000. A ratio (Mn.sub.b/Mn.sub.A) of the number-average molecular weight (Mn.sub.b) to the number-average molecular weight (Mn.sub.A) is from 0.1 to 0.9.

Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.

Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.

Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.

Provided by the present invention are a dispersant for suspension polymerization which enables production of vinyl polymer particles having a small particle diameter at a small added amount, a method for producing such a dispersant for suspension polymerization, and a method for producing vinyl polymer particles by using such a dispersant for suspension polymerization.

Provided by the present invention are a dispersant for suspension polymerization which enables production of vinyl polymer particles having a small particle diameter at a small added amount, a method for producing such a dispersant for suspension polymerization, and a method for producing vinyl polymer particles by using such a dispersant for suspension polymerization.

The present invention relates to a method of manufacturing an ionomer resin, comprising the steps of: (i) adding a poor solvent to a crude ionomer resin solution comprising a (meth)acrylic acid unit (A), a neutralized (meth)acrylic acid unit (B) and an ethylene unit (C) to allow a granular resin with a peak top particle size of from 50 to 700 μm to be precipitated; and (ii) washing the precipitated granular resin with a washing solution; wherein the total amount of the unit (A) and the unit (B) is from 6 to 10 mol % based on the entire monomeric units constituting the crude ionomer resin.

The present invention relates to a method of manufacturing an ionomer resin, comprising the steps of: (i) adding a poor solvent to a crude ionomer resin solution comprising a (meth)acrylic acid unit (A), a neutralized (meth)acrylic acid unit (B) and an ethylene unit (C) to allow a granular resin with a peak top particle size of from 50 to 700 μm to be precipitated; and (ii) washing the precipitated granular resin with a washing solution; wherein the total amount of the unit (A) and the unit (B) is from 6 to 10 mol % based on the entire monomeric units constituting the crude ionomer resin.

In surface functionalization of a surface with nano- or microparticles, a process is for functionalizing a surface of a solid support with nano- or microparticles. Polymers include polymerized amine-functionalized monomer units. The polymers are used to functionalize a solid support with nano- or microparticles. The resulting nano- or microparticles functionalized polymers includes polymerized amine-functionalized monomer units.