Methods, including a one-step synthesis method, for chemically modifying crosslinked sodium polyacrylate to form pressure sensitive adhesives are disclosed.

Methods, including a one-step synthesis method, for chemically modifying crosslinked sodium polyacrylate to form pressure sensitive adhesives are disclosed.

Methods, including a one-step synthesis method, for chemically modifying crosslinked sodium polyacrylate to form pressure sensitive adhesives are disclosed.

The present invention relates to an ethylene-vinyl alcohol copolymer (EVOH) resin composition, an EVOH film formed therefrom, and a multilayer structure containing the same. The core void volume (Vvc) of the surface of the EVOH resin composition is more than 0.010 μm.sup.3/μm.sup.2 and less than 50 μm.sup.3/μm.sup.2; or its surface pole height (Sxp) is more than 0.010 μm and less than 9.0 μm. The invention can reduce the torque output during processing, reduce the adsorption of fine powder on the surface caused by static electricity generated on the surface of the EVOH, and provide good film thickness uniformity.

The present invention relates to an ethylene-vinyl alcohol copolymer (EVOH) resin composition, an EVOH film formed therefrom, and a multilayer structure containing the same. The core void volume (Vvc) of the surface of the EVOH resin composition is more than 0.010 μm.sup.3/μm.sup.2 and less than 50 μm.sup.3/μm.sup.2; or its surface pole height (Sxp) is more than 0.010 μm and less than 9.0 μm. The invention can reduce the torque output during processing, reduce the adsorption of fine powder on the surface caused by static electricity generated on the surface of the EVOH, and provide good film thickness uniformity.

A novel graft polymer can include a block copolymer backbone (A) as a graft base having polymeric sidechains (B) grafted thereon. The polymeric sidechains (B) are obtainable by polymerization of at least one vinyl ester monomer (B1) and optionally N-vinylpyrrolidone as optional further monomer (B2). For example, the block copolymer backbone (A) is a triblock copolymer of polyethylene oxide (PEG) and polypropylene oxide (PPG). Also included is a process for obtaining such a graft polymer, the process is preferably carried out by free-radical polymerization.

A novel graft polymer can include a block copolymer backbone (A) as a graft base having polymeric sidechains (B) grafted thereon. The polymeric sidechains (B) are obtainable by polymerization of at least one vinyl ester monomer (B1) and optionally N-vinylpyrrolidone as optional further monomer (B2). For example, the block copolymer backbone (A) is a triblock copolymer of polyethylene oxide (PEG) and polypropylene oxide (PPG). Also included is a process for obtaining such a graft polymer, the process is preferably carried out by free-radical polymerization.

One aspect of this invention is a novel functional polymer having a polydispersity from 1 to about 1.12 comprising at least one reactive moiety, selected from a moiety comprising at least one N-coordinative functional group having at least one lone pair of electrons, a moiety comprising a dialkylsilyl group, or a mixture of both groups, wherein said reactive moiety is present in said functional styrenic polymer either on a repeat unit, on an end group or on both, and said N-coordinative functional group is either a monodentate N-coordinative functional group, a polydendate N-coordinative group or a mixture of thereof, and said monodentate coordinative functional group is an azide moiety (—N.sub.3) or a cyano moiety (—CN). Another aspect of this invention is the use of these novel polymer to selectively deposit a DSA directing layer on a metallic substrate.

One aspect of this invention is a novel functional polymer having a polydispersity from 1 to about 1.12 comprising at least one reactive moiety, selected from a moiety comprising at least one N-coordinative functional group having at least one lone pair of electrons, a moiety comprising a dialkylsilyl group, or a mixture of both groups, wherein said reactive moiety is present in said functional styrenic polymer either on a repeat unit, on an end group or on both, and said N-coordinative functional group is either a monodentate N-coordinative functional group, a polydendate N-coordinative group or a mixture of thereof, and said monodentate coordinative functional group is an azide moiety (—N.sub.3) or a cyano moiety (—CN). Another aspect of this invention is the use of these novel polymer to selectively deposit a DSA directing layer on a metallic substrate.

The present invention relates to ethylene-vinyl alcohol copolymer particles, comprising an ethylene-vinyl alcohol copolymer having an ethylene unit content of 1 mol % or more and less than 20 mol %, a viscosity-average polymerization degree of 200 to 5000, and a saponification degree of 80 to 99.99 mol %, wherein a crystallinity in water Cw (30° C.) at 30° C. and a crystallinity in water Cw (70° C.) at 70° C. as determined by pulse NMR satisfy formula (I). There is thus provided ethylene-vinyl alcohol copolymer particles having excellent solubility in water and excellent gas barrier performance.