C08F8/14

Method for producing end-modified polybutadiene or end-modified hydrogenated polybutadiene and composition containing same
09815922 · 2017-11-14 · ·

It is an object of the present invention to provide a method for producing a terminal-modified polybutadiene or terminal-modified hydrogenated polybutadiene that does not become colored or white and turbid, without using an organotin compound. The production method of the present invention includes reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organoaluminum compound and an organozinc compound (with the proviso that zinc naphthenate is excluded). ##STR00001##

Racemic drug resolution using polymer supported chiral selector

The present invention relates to a process for the separation of enantiomers or resolution of racemic mixtures using high surface area core-shell polymer beads. The present invention further relates to a core-shell functionalized polymer comprising a core which comprises copolymer made from monomers selected from non-aromatic acrylate, ethylene dimethacrylate and divinyl-benzene, a shell which comprises monomers selected from glycidyl ethers of methacrylate and a chiral selector selected from tartaric acid derivatives and amino acids.

Racemic drug resolution using polymer supported chiral selector

The present invention relates to a process for the separation of enantiomers or resolution of racemic mixtures using high surface area core-shell polymer beads. The present invention further relates to a core-shell functionalized polymer comprising a core which comprises copolymer made from monomers selected from non-aromatic acrylate, ethylene dimethacrylate and divinyl-benzene, a shell which comprises monomers selected from glycidyl ethers of methacrylate and a chiral selector selected from tartaric acid derivatives and amino acids.

Polyvinyl alcohol composition and use thereof

There is provided a composition (C) comprising a modified PVA (A) and a compound (B), wherein the modified PVA (A) contains 0.01 mol % or more and less than 2 mol % of double bonds derived from an unsaturated carboxylic acid or a derivative thereof in side chains; the compound (B) is a compound having a conjugated double bond and two or more hydroxy groups bonded to the conjugated double bond, or a salt or oxide thereof; and a content of the compound (B) in the composition (C) is 0.001 parts by mass or more and less than 5 parts by mass based on 100 parts by mass of the modified PVA (A). The composition (C) has excellent hue, contains less insolubles in water, and has excellent water solubility.

Polyvinyl alcohol composition and use thereof

There is provided a composition (C) comprising a modified PVA (A) and a compound (B), wherein the modified PVA (A) contains 0.01 mol % or more and less than 2 mol % of double bonds derived from an unsaturated carboxylic acid or a derivative thereof in side chains; the compound (B) is a compound having a conjugated double bond and two or more hydroxy groups bonded to the conjugated double bond, or a salt or oxide thereof; and a content of the compound (B) in the composition (C) is 0.001 parts by mass or more and less than 5 parts by mass based on 100 parts by mass of the modified PVA (A). The composition (C) has excellent hue, contains less insolubles in water, and has excellent water solubility.

POLYOLEFIN TERPOLYMERS, VITRIMERS MADE THEREFROM, AND METHOD OF MAKING THE POLYOLEFIN TERPOLYMERS AND VITRIMERS

Terpolymers that include a hydrocarbon unit, an acetoacetate terminated unit and a hydroxy-terminated unit are described. Vitrimers made from these terpolymers are also described.

POLYOLEFIN TERPOLYMERS, VITRIMERS MADE THEREFROM, AND METHOD OF MAKING THE POLYOLEFIN TERPOLYMERS AND VITRIMERS

Terpolymers that include a hydrocarbon unit, an acetoacetate terminated unit and a hydroxy-terminated unit are described. Vitrimers made from these terpolymers are also described.

Oral care compositions comprising phosphono-phosphate and anionic group containing polymers

Disclosed are oral care compositions of novel phosphono-phosphate and anionic group containing polymer compositions that have targeted uses with divalent cations and surfaces having divalent cations. These compounds can be used to deliver anionic character to surfaces such as calcium hydroxyapatite for use in oral care applications.

Oral care compositions comprising phosphono-phosphate and anionic group containing polymers

Disclosed are oral care compositions of novel phosphono-phosphate and anionic group containing polymer compositions that have targeted uses with divalent cations and surfaces having divalent cations. These compounds can be used to deliver anionic character to surfaces such as calcium hydroxyapatite for use in oral care applications.

Oral care compositions comprising phosphono-phosphate and anionic group containing polymers

Disclosed are oral care compositions of novel phosphono-phosphate and anionic group containing polymer compositions that have targeted uses with divalent cations and surfaces having divalent cations. These compounds can be used to deliver anionic character to surfaces such as calcium hydroxyapatite for use in oral care applications.