Disclosed are oral care compositions of novel phosphono-phosphate and anionic group containing polymer compositions that have targeted uses with divalent cations and surfaces having divalent cations. These compounds can be used to deliver anionic character to surfaces such as calcium hydroxyapatite for use in oral care applications.

Disclosed are oral care compositions of novel phosphono-phosphate and anionic group containing polymer compositions that have targeted uses with divalent cations and surfaces having divalent cations. These compounds can be used to deliver anionic character to surfaces such as calcium hydroxyapatite for use in oral care applications.

An object of the present invention is to provide a thermosetting coating material composition of which a transesterification reaction is a curing reaction, the thermosetting coating material having a property of being usable as a coating material composition. The thermosetting resin composition includes a compound (A) which is a compound (A-a) having two or more —COOR (R is a primary or secondary alkyl group) and/or a compound (A-b) having one —COOR (R is a primary or secondary alkyl group) and a hydroxyl group, and a polyol (B) having two or more hydroxyl groups and a transesterification catalyst (C).

An object of the present invention is to provide a thermosetting coating material composition of which a transesterification reaction is a curing reaction, the thermosetting coating material having a property of being usable as a coating material composition. The thermosetting resin composition includes a compound (A) which is a compound (A-a) having two or more —COOR (R is a primary or secondary alkyl group) and/or a compound (A-b) having one —COOR (R is a primary or secondary alkyl group) and a hydroxyl group, and a polyol (B) having two or more hydroxyl groups and a transesterification catalyst (C).

The present invention provides a modified polyolefin resin composition including a modified polyolefin resin (X) formed by modifying an acid-modified polyolefin resin (A) with a modification component comprising an alcohol (B), in which the modified polyolefin resin composition satisfies the following (I) to (III) and also provides applications of the modified polyolefin resin composition.

(I) The resin (A) is a resin formed by modifying a polyolefin (a) with an α,β-unsaturated carboxylic acid and a derivative (b) of the α,β-unsaturated carboxylic acid having a structure (b1) derived from at least one carboxy group.

(II) A residual ratio of the structure (b1) in the resin (X) is more than 0% to 50% or less.

(III) A content of the alcohol in the composition is 1.0 mol to 5.0 mol relative to 1.0 mol of the structure (b1) that the resin (A) has.

The present invention provides a modified polyolefin resin composition including a modified polyolefin resin (X) formed by modifying an acid-modified polyolefin resin (A) with a modification component comprising an alcohol (B), in which the modified polyolefin resin composition satisfies the following (I) to (III) and also provides applications of the modified polyolefin resin composition.

(I) The resin (A) is a resin formed by modifying a polyolefin (a) with an α,β-unsaturated carboxylic acid and a derivative (b) of the α,β-unsaturated carboxylic acid having a structure (b1) derived from at least one carboxy group.

(II) A residual ratio of the structure (b1) in the resin (X) is more than 0% to 50% or less.

(III) A content of the alcohol in the composition is 1.0 mol to 5.0 mol relative to 1.0 mol of the structure (b1) that the resin (A) has.

A method for producing a vinyl polymer by suspension-polymerizing a vinyl compound in the presence of a dispersion stabilizer, wherein the dispersion stabilizer contains a polyvinyl alcohol and a composition containing a modified polyvinyl alcohol and a compound; the modified polyvinyl alcohol contains double bonds derived from an unsaturated carboxylic acid or a derivative thereof in side chains; the compound is a compound having two or more hydroxy groups bonded to a conjugated double bond; the modified polyvinyl alcohol has a saponification degree and a viscosity-average polymerization degree different from those of the polyvinyl alcohol; a content of the compound in the composition is 0.001 parts by mass or more and less than 5 parts by mass based on 100 parts by mass of the modified polyvinyl alcohol; and a mass ratio of the composition to the polyvinyl alcohol is 50/50 to 90/10.

A dual-cure method for forming a solid polymeric structure is provided. An end-capped, imide-terminated prepolymer is combined with at least one photopolymerizable olefinic monomer, at least one photoinitiator, and a diamine, to form a curable resin composition, which, in a first step, is irradiated under conditions effective to polymerize the at least one olefinic monomer, thus forming a scaffold composed of the prepolymer and the polyolefin with the diamine trapped therein. The irradiated composition is then thermally treated at a temperature effective to cause a transimidization reaction to occur between the prepolymer and the diamine, thereby releasing the end caps of the prepolymer and providing the solid polymeric structure. A curable resin composition comprising an end-capped, imide-terminated prepolymer, at least one photopolymerizable olefinic monomer, at least one photoinitiator, and a diamine, is also provided, as are related methods of use.

A dual-cure method for forming a solid polymeric structure is provided. An end-capped, imide-terminated prepolymer is combined with at least one photopolymerizable olefinic monomer, at least one photoinitiator, and a diamine, to form a curable resin composition, which, in a first step, is irradiated under conditions effective to polymerize the at least one olefinic monomer, thus forming a scaffold composed of the prepolymer and the polyolefin with the diamine trapped therein. The irradiated composition is then thermally treated at a temperature effective to cause a transimidization reaction to occur between the prepolymer and the diamine, thereby releasing the end caps of the prepolymer and providing the solid polymeric structure. A curable resin composition comprising an end-capped, imide-terminated prepolymer, at least one photopolymerizable olefinic monomer, at least one photoinitiator, and a diamine, is also provided, as are related methods of use.

The present invention provides a water-absorbent resin that has excellent water-absorption performance with respect to salt water; a water-blocking agent including the water-absorbent resin; and a method for producing the water-absorbent resin.

The water-absorbent resin of the present invention includes a partially neutralized polyacrylic acid having a crosslinked structure and has a swelling height of 3.5 mm/0.5 g or more with respect to 3.3 mass % salt water, as determined under the following measurement conditions.

Measurement Conditions for Salt Water Swelling Height

0.5 g of water-absorbent resin particles are sprayed over a circular concave cup having a height of 30 mm and an inner diameter of 80.5 mm. A nonwoven fabric 4 is spread thereon. A circular convex cylinder having an outer diameter of 80 mm is placed on the nonwoven fabric, and 55 g of 3.3 mass % salt water at 20° C. is poured into the circular concave cup. One minute after the start of water absorption by the water-absorbent resin particles, the degree that the circular convex cylinder is pushed up due to swelling of the water-absorbent resin particles is measured as a salt water swelling height of the water-absorbent resin.