A viscosity index improver comprising a reaction product of (i) an acylated copolymer obtainable by acylating a copolymer of ethylene and one or more C.sub.3-C.sub.10 alpha-olefins having an Mn of 3,000 to 250,000 g/mol; and (ii) a compound of the formulae (III)-(V):

##STR00001##

wherein R.sub.6, R.sub.8, R.sub.9, R.sub.10, R.sub.12 and R.sub.15 are independently selected from a hydrogen and an optionally substituted linear or branched alkyl or alkenyl group, and R.sub.7, R.sub.11, R.sub.13, R.sub.14, R.sub.16, and R.sub.17 are independent selected from an optionally substituted linear or branched alkyl or alkenyl group, and a sum of the number of carbon atoms in each compound of the formulae (III)-(V) is from 6 to 31.

Methods for upcycling crosslinked sodium polyacrylate to pressure sensitive adhesives via (a) mechanochemical chain-shortening and esterification or (b) esterifying with high conversion with a Fischer esterification process are disclosed. Also disclosed is a pressure sensitive adhesive prepared by the disclosed methods and articles comprising the pressure sensitive adhesive, including, but not limited to, pressure sensitive tape, a bandage, a label, note pads, a decal, a stamp, an envelope, a sticker, packaging, automobile trim, and a film.

Methods for upcycling crosslinked sodium polyacrylate to pressure sensitive adhesives via (a) mechanochemical chain-shortening and esterification or (b) esterifying with high conversion with a Fischer esterification process are disclosed. Also disclosed is a pressure sensitive adhesive prepared by the disclosed methods and articles comprising the pressure sensitive adhesive, including, but not limited to, pressure sensitive tape, a bandage, a label, note pads, a decal, a stamp, an envelope, a sticker, packaging, automobile trim, and a film.

Methods for upcycling crosslinked sodium polyacrylate to pressure sensitive adhesives via (a) mechanochemical chain-shortening and esterification or (b) esterifying with high conversion with a Fischer esterification process are disclosed. Also disclosed is a pressure sensitive adhesive prepared by the disclosed methods and articles comprising the pressure sensitive adhesive, including, but not limited to, pressure sensitive tape, a bandage, a label, note pads, a decal, a stamp, an envelope, a sticker, packaging, automobile trim, and a film.

The application relates to a polymeric film (FILM 1) for a release liner (REL2), comprising a polymeric support layer (S1) of a first composition comprising one or more polyolefins and/or polyesters, and an extruded primer layer (PRIM1) of a second composition comprising a thermoplastic polymer covalently bounded to functional vinyl groups.

The application relates to a polymeric film (FILM 1) for a release liner (REL2), comprising a polymeric support layer (S1) of a first composition comprising one or more polyolefins and/or polyesters, and an extruded primer layer (PRIM1) of a second composition comprising a thermoplastic polymer covalently bounded to functional vinyl groups.

Provided is a polymer having a sharp melting peak and allowing easy adjustment of the melting peak temperature. Specifically provided is a polymer having two or more kinds of constitutional units containing an alkyl group having 14 or more and 30 or less carbon atoms, wherein the proportions of the number of the two or more kinds of constitutional units containing an alkyl group having 14 or more and 30 or less carbon atoms are each 20% or more, with respect to 100% of the total number of all constitutional units containing an alkyl group having 14 or more and 30 or less carbon atoms. An enthalpy of fusion of the polymer observed within a temperature range of 10° C. or higher and lower than 60° C. in differential scanning calorimetry is 30 J/g or more.

Provided is a polymer having a sharp melting peak and allowing easy adjustment of the melting peak temperature. Specifically provided is a polymer having two or more kinds of constitutional units containing an alkyl group having 14 or more and 30 or less carbon atoms, wherein the proportions of the number of the two or more kinds of constitutional units containing an alkyl group having 14 or more and 30 or less carbon atoms are each 20% or more, with respect to 100% of the total number of all constitutional units containing an alkyl group having 14 or more and 30 or less carbon atoms. An enthalpy of fusion of the polymer observed within a temperature range of 10° C. or higher and lower than 60° C. in differential scanning calorimetry is 30 J/g or more.

Provided is a polymer having a sharp melting peak and allowing easy adjustment of the melting peak temperature. Specifically provided is a polymer having two or more kinds of constitutional units containing an alkyl group having 14 or more and 30 or less carbon atoms, wherein the proportions of the number of the two or more kinds of constitutional units containing an alkyl group having 14 or more and 30 or less carbon atoms are each 20% or more, with respect to 100% of the total number of all constitutional units containing an alkyl group having 14 or more and 30 or less carbon atoms. An enthalpy of fusion of the polymer observed within a temperature range of 10° C. or higher and lower than 60° C. in differential scanning calorimetry is 30 J/g or more.

A (meth)acrylate functional copolymer is useful as a dispersant for solid particulates in paints, inks and coatings. The copolymers have (meth)acrylate functionality positioned pendant to the polymer chain. Also positioned pendant to the polymer backbone chain are non-(meth)acrylate-functional hydrophobic and/or hydrophilic pendant groups. The copolymers are useful as dispersants in dispersions of particulate solids in organic media and aqueous media, such in paints and printing inks.