Patent classifications
C08F10/04
Production method of olefin polymer and olefin polymerization catalyst
To provide a method of efficiently affording olefin polymers having a high molecular weight and a high melting point even under industrially advantageous high-temperature conditions. A production method of an olefin polymer to solve the above problem includes polymerizing monomer(s) including at least one -olefin having 3 or more carbon atoms at 50 C. to 200 C. in the presence of an olefin polymerization catalyst including; (A) a crosslinked metallocene compound represented by General Formula [I] below; and (B) at least one compound selected from (b-1) an organoaluminum oxy-compound, (b-2) a compound that forms an ion pair by reacting with the crosslinked metallocene compound (A), and (b-3) an organoalunimum compound. ##STR00001##
Metal-Containing Bis(Imino) per-Substituted Aryl Compounds and Methods Thereof
The present disclosure related to metal-containing compounds that, in some embodiments, are compounds represented by Formula (I). M is Fe or Co. Each of R.sup.8, R.sup.9, R.sup.10, R.sup.13, R.sup.14, and R.sup.15 is independently C.sub.1-C.sub.40 hydrocarbyl, OR.sup.16, NR.sup.172, halogen, or five-, six-, or seven-membered heterocyclic ring comprising at least one atom selected from the group consisting of N, P, O and S. Each of R.sup.6, R.sup.7, R.sup.11, and R.sup.12 is independently C.sub.1-C.sub.40 hydrocarbyl, a heteroatom or a heteroatom-containing group. Each of X.sup.1 and X.sup.2 is independently an anionic ligand.
Metal-Containing Bis(Imino) per-Substituted Aryl Compounds and Methods Thereof
The present disclosure related to metal-containing compounds that, in some embodiments, are compounds represented by Formula (I). M is Fe or Co. Each of R.sup.8, R.sup.9, R.sup.10, R.sup.13, R.sup.14, and R.sup.15 is independently C.sub.1-C.sub.40 hydrocarbyl, OR.sup.16, NR.sup.172, halogen, or five-, six-, or seven-membered heterocyclic ring comprising at least one atom selected from the group consisting of N, P, O and S. Each of R.sup.6, R.sup.7, R.sup.11, and R.sup.12 is independently C.sub.1-C.sub.40 hydrocarbyl, a heteroatom or a heteroatom-containing group. Each of X.sup.1 and X.sup.2 is independently an anionic ligand.
Method for fabricating pattern of cured product and methods for manufacturing optical component, circuit board and quartz mold replica as well as coating material for imprint pretreatment and cured product thereof
The method for fabricating pattern of a cured product includes a first step (arranging step) of arranging a layer formed of a liquid film of a curable composition (1) containing at least a component (A1) serving as a polymerizable compound on a substrate and a second step (dispensing step) of dispensing liquid droplets of a curable composition (a2) containing at least a component (A2) serving as a polymerizable compound discretely onto a layer formed of a composition (1) of components of the curable composition (1) except a component (D1) serving as a solvent, in which: the mixing of the composition (1) and the curable composition (2) is exothermic.
Method for fabricating pattern of cured product and methods for manufacturing optical component, circuit board and quartz mold replica as well as coating material for imprint pretreatment and cured product thereof
The method for fabricating pattern of a cured product includes a first step (arranging step) of arranging a layer formed of a liquid film of a curable composition (1) containing at least a component (A1) serving as a polymerizable compound on a substrate and a second step (dispensing step) of dispensing liquid droplets of a curable composition (a2) containing at least a component (A2) serving as a polymerizable compound discretely onto a layer formed of a composition (1) of components of the curable composition (1) except a component (D1) serving as a solvent, in which: the mixing of the composition (1) and the curable composition (2) is exothermic.
POLYETHYLENE COMPOSITIONS AND PROCESSES FOR THEIR PRODUCTION
Provided are polyethylene copolymers with an improved balance of melt strength and processability and methods for making such polyethylene copolymers. In some embodiments, the polyethylene copolymers include from 9 to 11 weight percent of at least one comonomer having 4 to 8 carbon atoms, and have a density in the range of from 0.908 to 0.916 g/cm.sup.3, a melt index I.sub.2 in the range of 0.10 to 0.60 g/10 min., and a melt index ratio I.sub.21/I.sub.2 greater than or equal to 46.9(33.3(I.sub.2)), wherein I.sub.2 is provided in g/10 min. In some embodiments, the polyethylene copolymer is produced in a dry mode gas phase process using a metallocene catalyst.
POLYETHYLENE COMPOSITIONS AND PROCESSES FOR THEIR PRODUCTION
Provided are polyethylene copolymers with an improved balance of melt strength and processability and methods for making such polyethylene copolymers. In some embodiments, the polyethylene copolymers include from 9 to 11 weight percent of at least one comonomer having 4 to 8 carbon atoms, and have a density in the range of from 0.908 to 0.916 g/cm.sup.3, a melt index I.sub.2 in the range of 0.10 to 0.60 g/10 min., and a melt index ratio I.sub.21/I.sub.2 greater than or equal to 46.9(33.3(I.sub.2)), wherein I.sub.2 is provided in g/10 min. In some embodiments, the polyethylene copolymer is produced in a dry mode gas phase process using a metallocene catalyst.
Polymers for use as anion exchange membranes
Polymers for use as an Anion Exchange Membranes (AEMs) and produce an alkaline stable AEM. The multinuclear aromatic and amine-functionalized acetal (ketal) come together to form a polymer with a hydrocarbon backbone that is stable to alkaline conditions. The use of an amine-functionalized acetal allows for the incorporation of a stable cation, dimethyl piperidinium, in the most stable confirmation while avoiding incorporation of a CF3 group with every cation. The amines within the amine-functionalized polyaromatic that results from this polymerization are quaternized to form the desired cationic groups to create an AEM that is mechanically robust, conductive, and stable.