An object of the present invention is to provide a photosensitive resin composition having good liquid repellency. The photosensitive resin composition of the present invention at least contains a fluororesin having a crosslinking site, a solvent, and a photopolymerization initiator, and the fluororesin contains a repeating unit derived from a hydrocarbon having a fluorine atom.

An object of the present invention is to provide a photosensitive resin composition having good liquid repellency. The photosensitive resin composition of the present invention at least contains a fluororesin having a crosslinking site, a solvent, and a photopolymerization initiator, and the fluororesin contains a repeating unit derived from a hydrocarbon having a fluorine atom.

The present invention provides a composition comprising 1) an aqueous dispersion of polymer particles having a core-shell morphology wherein the core protuberates from the shell; wherein the core comprises from 5 to 90 weight percent structural units of a fluoroalkylated monomer, and 2) less than 0.09 weight percent structural units of a phosphorus acid monomer; and wherein the shell comprises from 0.1 to 5 weight percent of itaconic acid or a phosphorus acid monomer, based on the weight of the shell. The present invention addresses a need in the art by providing a way of selectively concentrating fluoroalkyl functionality into polymer particles with acorn morphology, thereby providing an improvement in dirt pick-up resistance of the subsequent coating.

Disclosed herein is a composition comprising a co-continuous interpenetrating network of an organic polymer and a electroactive moiety; where the organic polymer is operative to depolymerize at a temperature of 50 to 500? C. and to repolymerize on a surface in the presence of the electroactive moiety; and where the electroactive moiety is an organic semiconductor that does not react with a repolymerized polymer. Disclosed herein too is a method comprising co-evaporating a polymeric precursor and an electroactive moiety onto a substrate; condensing the polymeric precursor and an electroactive moiety on the substrate; and polymerizing the polymeric precursor to form a co-continuous interpenetrating network of an organic polymer and an electroactive moiety; where the electroactive moiety is defined as a chemical functional group which is capable of transporting an electrical charge.

Disclosed herein is a composition comprising a co-continuous interpenetrating network of an organic polymer and a electroactive moiety; where the organic polymer is operative to depolymerize at a temperature of 50 to 500? C. and to repolymerize on a surface in the presence of the electroactive moiety; and where the electroactive moiety is an organic semiconductor that does not react with a repolymerized polymer. Disclosed herein too is a method comprising co-evaporating a polymeric precursor and an electroactive moiety onto a substrate; condensing the polymeric precursor and an electroactive moiety on the substrate; and polymerizing the polymeric precursor to form a co-continuous interpenetrating network of an organic polymer and an electroactive moiety; where the electroactive moiety is defined as a chemical functional group which is capable of transporting an electrical charge.

A method of making a functionalized fluorinated monomer for use in making oligomers and polymers that can be used to improve surface properties of polymer-derived systems, such as coatings. The method of making a functionalized fluorinated monomer includes reacting at least one fluorinated nucleophilic reactant, such as a fluorinated alcohol, with at least one compound containing at least one epoxide group. Other methods include reaction of a fluorinated alcohol with a cyclic carboxylic anhydride. In another embodiment, a method includes reacting a fluorinated mesylate, tosylate or triflate with an amine, alkoxide or phenoxide. In other embodiments, the method includes reacting a fluorinated alcohol with an alkyl halide, or reacting a fluorinated alkyl halide with an amine. The functionalized fluorinated monomers may be used as intermediates and reacted to modify the functional groups thereon. Further, the functionalized fluorinated monomers may be reacted to form polymers or oligomers, or with polymers or oligomers having functional groups to modify the polymer or oligomer through the functional group thereon.

A method of making a functionalized fluorinated monomer for use in making oligomers and polymers that can be used to improve surface properties of polymer-derived systems, such as coatings. The method of making a functionalized fluorinated monomer includes reacting at least one fluorinated nucleophilic reactant, such as a fluorinated alcohol, with at least one compound containing at least one epoxide group. Other methods include reaction of a fluorinated alcohol with a cyclic carboxylic anhydride. In another embodiment, a method includes reacting a fluorinated mesylate, tosylate or triflate with an amine, alkoxide or phenoxide. In other embodiments, the method includes reacting a fluorinated alcohol with an alkyl halide, or reacting a fluorinated alkyl halide with an amine. The functionalized fluorinated monomers may be used as intermediates and reacted to modify the functional groups thereon. Further, the functionalized fluorinated monomers may be reacted to form polymers or oligomers, or with polymers or oligomers having functional groups to modify the polymer or oligomer through the functional group thereon.

A method of making a functionalized fluorinated monomer for use in making oligomers and polymers that can be used to improve surface properties of polymer-derived systems, such as coatings. The method of making a functionalized fluorinated monomer includes reacting at least one fluorinated nucleophilic reactant, such as a fluorinated alcohol, with at least one compound containing at least one epoxide group. Other methods include reaction of a fluorinated alcohol with a cyclic carboxylic anhydride. In another embodiment, a method includes reacting a fluorinated mesylate, tosylate or triflate with an amine, alkoxide or phenoxide. In other embodiments, the method includes reacting a fluorinated alcohol with an alkyl halide, or reacting a fluorinated alkyl halide with an amine. The functionalized fluorinated monomers may be used as intermediates and reacted to modify the functional groups thereon. Further, the functionalized fluorinated monomers may be reacted to form polymers or oligomers, or with polymers or oligomers having functional groups to modify the polymer or oligomer through the functional group thereon,

The present invention provides a polymer compound for a conductive polymer comprising one or more repeating units a shown by the formula (1), and having a weight-average molecular weight in the range of 1,000 to 500,000. There can be provided a polymer compound for a conductive polymer having a specific superacidic sulfo group which is soluble in an organic solvent, and suitably used for a fuel cell or a dopant for a conductive material. ##STR00001##
wherein R.sup.1 represents a hydrogen atom or a methyl group; R.sup.2 represents any of a single bond, an ester group, and a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms, the hydrocarbon group optionally containing an ether group, an ester group, or both; Z represents any of a single bond, a phenylene group, a naphthylene group, an ether group, and an ester group; and a is a number satisfying 0<a1.0.

Provided are: a polymer film of which film strength is difficult to be degraded and which has a lower reflectance, even when an additive is used, and an optical member, a polarizing member, and a display device employing the same. A low refractive index layer (the polymer film 13) includes a binder 132 including a product obtained by photopolymerizing a mixture of a side-chain-reactive photopolymerizable fluoropolymer and a siloxane compound. Further, the low refractive index layer 13 includes hollow silica particles 131 distributed in the binder 132. Further, the low refractive index layer 13 includes a product obtained by photopolymerizing a one-end reactive-type photopolymerizable fluoropolymer, and a modified silicone, which are mainly distributed in a surface side.