The present disclosure is directed towards methods of converting glycerol to an allyl compound, involving deoxydehydrating glycerol with formic acid and heat to form allyl alcohol; and esterifying the allyl alcohol with formic acid and/or phthalic anhydride and heat to form allyl formate and diallyl phthalate. In some instances, the heat is generated by a microwave. In further instances, the methods involve polymerizing the allyl alcohol, allyl formate and/or diallyl phthalate to form poly(allyl alcohol) or poly(allyl formate) or poly (diallyl phthalate). In some instances, the allyl polymers were used for the consolidation of oil sands tailings.

The present disclosure is directed towards methods of converting glycerol to an allyl compound, involving deoxydehydrating glycerol with formic acid and heat to form allyl alcohol; and esterifying the allyl alcohol with formic acid and/or phthalic anhydride and heat to form allyl formate and diallyl phthalate. In some instances, the heat is generated by a microwave. In further instances, the methods involve polymerizing the allyl alcohol, allyl formate and/or diallyl phthalate to form poly(allyl alcohol) or poly(allyl formate) or poly (diallyl phthalate). In some instances, the allyl polymers were used for the consolidation of oil sands tailings.

An acrylic polyester resin is provided by grafting an acrylic polymer with a polyester material. Also provided is an aqueous coating composition with at least the acrylic polyester resin and a metal packaging container coated with the aqueous coating composition.

An acrylic polyester resin is provided by grafting an acrylic polymer with a polyester material. Also provided is an aqueous coating composition with at least the acrylic polyester resin and a metal packaging container coated with the aqueous coating composition.

Provided is a colored resin composition which can be applied as a color filter of a solid-state imaging device capable of performing high-level imaging by not only spectrally splitting light in a visible region into three colors but also spectrally splitting infrared rays. The colored resin composition includes a colorant (A), a solvent (B), and a binder resin (C), and has a maximum transmittance in a specific wavelength region in a wavelength range of 400 to 900 nm. The colorant (A) includes a colorant having specific light absorbing characteristics and a near-infrared absorbing compound.

The present invention provides a stretchable film including: a cured product of a composition which contains (A) a (meth)acrylate compound having silsesquioxane, (B) a (meth)acrylate compound other than the component (A) having a urethane bond, and (C) an organic solvent having a boiling point in the range of 115 to 200 C. at atmospheric pressure; wherein the component (A) is localized in the direction of a surface of the film. The stretchable film of the present invention is excellent in stretchability and strength as well as repellency on the film surface.

The present invention provides a stretchable film including: a cured product of a composition which contains (A) a (meth)acrylate compound having silsesquioxane, (B) a (meth)acrylate compound other than the component (A) having a urethane bond, and (C) an organic solvent having a boiling point in the range of 115 to 200 C. at atmospheric pressure; wherein the component (A) is localized in the direction of a surface of the film. The stretchable film of the present invention is excellent in stretchability and strength as well as repellency on the film surface.

A resist composition which generates an acid upon exposure and whose solubility on a developing solution changes under the action of the acid, including a polymer compound having units represented by formulas (a0-1), (a0-2), and (a0-3) in an amount of 0 to 10 mol %. In the formulas, R is a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, or a halogenated alkyl group having 1 to 5 carbon atoms, Va.sup.01 and Va.sup.03 are a divalent hydrocarbon group, n.sub.a01 and n.sub.a03 each are an integer of 0 to 2, Ra.sup.0 is a specific acid dissociable group, Va.sup.02 is a divalent linking group containing a hetero atom or a single bond, Ra.sup.07 is a monovalent organic group, n.sub.a021 is an integer of 0 to 3, and n.sub.a022 is an integer of 1 to 3.

##STR00001##

A resist composition which generates an acid upon exposure and whose solubility on a developing solution changes under the action of the acid, including a polymer compound having units represented by formulas (a0-1), (a0-2), and (a0-3) in an amount of 0 to 10 mol %. In the formulas, R is a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, or a halogenated alkyl group having 1 to 5 carbon atoms, Va.sup.01 and Va.sup.03 are a divalent hydrocarbon group, n.sub.a01 and n.sub.a03 each are an integer of 0 to 2, Ra.sup.0 is a specific acid dissociable group, Va.sup.02 is a divalent linking group containing a hetero atom or a single bond, Ra.sup.07 is a monovalent organic group, n.sub.a021 is an integer of 0 to 3, and n.sub.a022 is an integer of 1 to 3.

##STR00001##

A polymerizable system includes a curable composition and one or more encapsulated initiator particles. The curable composition can include one or more 1,1-disubstituted alkene compounds and the encapsulated initiator particles can include one or more polymerization initiators encapsulated by a cured composition. The cured composition includes one or more 1,1-disubstituted alkene compounds.