A polymerizable liquid composition including semi-conductive nanoparticles for the manufacture of ophthalmic lenses. Specifically, polymerizable composition has at least one monomer or oligomer; at least one catalyst for initiating the polymerization of the monomer or oligomer; and semi-conductive nanoparticles, which are dispersed in the monomer or oligomer. The absorbance through a 2-millimeter-thick layer of the polymerizable composition is higher than 0.5 for each light wavelength ranging from 350 to λ.sub.cut, λ.sub.cut being in the visible range, preferably in the range from 400 nm to 480 nm.

A polymerizable liquid composition including semi-conductive nanoparticles for the manufacture of ophthalmic lenses. Specifically, polymerizable composition has at least one monomer or oligomer; at least one catalyst for initiating the polymerization of the monomer or oligomer; and semi-conductive nanoparticles, which are dispersed in the monomer or oligomer. The absorbance through a 2-millimeter-thick layer of the polymerizable composition is higher than 0.5 for each light wavelength ranging from 350 to λ.sub.cut, λ.sub.cut being in the visible range, preferably in the range from 400 nm to 480 nm.

A light filtering glass container including a glass container coated with a light filtering coating obtained by curing a polymerizable composition including semi-conductive nanoparticles. The absorbance through a 5-micrometer thick light filtering coating is greater than 0.5 for each light wavelength ranging from 350 nm to λ.sub.cut, λ.sub.cut being in the range from 420 nm to 480 nm, and the difference of lightness between the uncoated glass container and the glass container with the light filtering coating is lower than 5.

A polymerizable composition for an optical material includes: an allyl carbonate compound (A) including two or more allyloxycarbonyl groups at a terminal which is represented by General Formula (1); and a radical polymerization initiator (B). The radical polymerization initiator (B) includes at least one kind of radical polymerization initiator (B1) which is a peroxyester-based radical polymerization initiator, and a radical polymerization initiator (B2).

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A polymerizable composition for an optical material includes: an allyl carbonate compound (A) including two or more allyloxycarbonyl groups at a terminal which is represented by General Formula (1); and a radical polymerization initiator (B). The radical polymerization initiator (B) includes at least one kind of radical polymerization initiator (B1) which is a peroxyester-based radical polymerization initiator, and a radical polymerization initiator (B2).

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A polymerizable composition for an optical material includes: an allyl carbonate compound (A) including two or more allyloxycarbonyl groups at a terminal which is represented by General Formula (1); and a radical polymerization initiator (B). The radical polymerization initiator (B) includes at least one kind of radical polymerization initiator (B1) which is a peroxyester-based radical polymerization initiator, and a radical polymerization initiator (B2).

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An electrocaloric element for a heat transfer system includes an electrocaloric material of a copolymer of (i) vinylidene fluoride, and (ii) an addition polymerization monomer that is larger than vinylidene fluoride and includes a substituent more electronegative than chlorine. Electrodes are disposed on opposite surfaces of the electrocaloric material, and an electric power source is configured to provide voltage to the electrodes. The system also includes a first thermal flow path between the electrocaloric material and a heat sink, and a second thermal flow path between the electrocaloric material and a heat source.

An electrocaloric element for a heat transfer system includes an electrocaloric material of a copolymer of (i) vinylidene fluoride, and (ii) an addition polymerization monomer that is larger than vinylidene fluoride and includes a substituent more electronegative than chlorine. Electrodes are disposed on opposite surfaces of the electrocaloric material, and an electric power source is configured to provide voltage to the electrodes. The system also includes a first thermal flow path between the electrocaloric material and a heat sink, and a second thermal flow path between the electrocaloric material and a heat source.

The present invention is directed to a polymerizable composition comprising (A) a reaction product of: (a) diethyleneglycol bischloroformate, ethyleneglycol bischloroformate, or combinations thereof; (b) allyl alcohol; (c) optionally, a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups; and (B) an organic peroxide comprising at least three peroxide groups. A polymerizate and/or an optical article comprising the polymerizable compositions of the invention are also provided.

The present invention is directed to a polymerizable composition comprising (A) a reaction product of: (a) diethyleneglycol bischloroformate, ethyleneglycol bischloroformate, or combinations thereof; (b) allyl alcohol; (c) optionally, a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups; and (B) an organic peroxide comprising at least three peroxide groups. A polymerizate and/or an optical article comprising the polymerizable compositions of the invention are also provided.